Issue 92, 2021

Solid-state construction of zigzag periphery via intramolecular C–H insertion induced by alumina-mediated C–F activation

Abstract

Caryl–F bond activation has become an important and quickly developing method for construction of carbon-based materials. We report that alumina-mediated C–F bond activation (AmCFA) enables construction of PAHs with zigzag periphery. This method includes formal Csp3–H activation and opens an avenue for generation of carbon-based nanomagnets directly on technologically relevant surfaces.

Graphical abstract: Solid-state construction of zigzag periphery via intramolecular C–H insertion induced by alumina-mediated C–F activation

Supplementary files

Article information

Article type
Communication
Submitted
16 Sep 2021
Accepted
28 Oct 2021
First published
29 Oct 2021

Chem. Commun., 2021,57, 12325-12328

Solid-state construction of zigzag periphery via intramolecular C–H insertion induced by alumina-mediated C–F activation

M. Feofanov, A. Förtsch, K. Amsharov and V. Akhmetov, Chem. Commun., 2021, 57, 12325 DOI: 10.1039/D1CC05233K

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