Issue 3, 2019
From the journal:

Dalton Transactions

Recent developments in the chemistry of metal oxopolyazides

Ralf Haiges ORCID logo a  

a Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA
E-mail: haiges@usc.edu

Abstract

The recent acomplished syntheses of novel metal oxopolyazides VO(N3)3, NbO(N3)3, NbO(N3)3·2CH3CN, MoO(N3)3, MoO(N3)3·2CH3CN, WO(N3)4, WO(N3)4·CH3CN, MoO2(N3)2, MoO2(N3)2·2CH3CN, WO2(N3)2, WO2(N3)2·2CH3CN and UO2(N3)2·CH3CN by the author is reviewed. The conversion of the compounds into 2,2′-bipyridine donor adducts and oxaazido metallates is discribed. The properties and X-ray crystal structures of the metal oxopolyazides are compared and discussed.

Graphical abstract: Recent developments in the chemistry of metal oxopolyazides

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Article information

DOI
https://doi.org/10.1039/C8DT04258F
Article type
Frontier
Submitted
24 Oct 2018
Accepted
12 Dec 2018
First published
12 Dec 2018

Dalton Trans., 2019,48, 806-813

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Recent developments in the chemistry of metal oxopolyazides

R. Haiges, Dalton Trans., 2019, 48, 806 DOI: 10.1039/C8DT04258F

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