Issue 44, 2019

Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties

Abstract

Two cryptand-like, shape persistent [2+3] imine cages (1 and 2) derived from oligopyrrolic precursors (diformyl dipyrrylpyridine 3 and diformyl bipyrrole 4) were prepared. These cages contain open cavities as inferred from solid state structural analyses and act as selective CO2 gas adsorbing materials in the solid state.

Graphical abstract: Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties

Supplementary files

Article information

Article type
Communication
Submitted
30 Mar 2019
Accepted
08 Apr 2019
First published
13 May 2019

Chem. Commun., 2019,55, 6185-6188

Shape-persistent pyrrole-based covalent organic cages: synthesis, structure and selective gas adsorption properties

F. Wang, E. Sikma, Z. Duan, T. Sarma, C. Lei, Z. Zhang, S. M. Humphrey and J. L. Sessler, Chem. Commun., 2019, 55, 6185 DOI: 10.1039/C9CC02490E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements