Issue 16, 2019

Halogen bonding effects on the outcome of reactions at metal centres

Abstract

Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr–I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.

Graphical abstract: Halogen bonding effects on the outcome of reactions at metal centres

Supplementary files

Article information

Article type
Communication
Submitted
07 Nov 2018
Accepted
30 Jan 2019
First published
31 Jan 2019

Chem. Commun., 2019,55, 2380-2383

Halogen bonding effects on the outcome of reactions at metal centres

L. Carreras, J. Benet-Buchholz, A. Franconetti, A. Frontera, P. W. N. M. van Leeuwen and A. Vidal-Ferran, Chem. Commun., 2019, 55, 2380 DOI: 10.1039/C8CC08884E

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