Scalable and cost-effective Ag nanowires flexible transparent electrodes

Flexible transparent electrodes (TEs) are important for new electronic devices. This paper reports a scalable, cost effective Ag nanowires (AgNWs) TE, which is made of a SnO2·xH2O and AgNWs composite layer and a flexible polyethylene terephthalate (PET) bottom layer by a solution method at room temperature. The AgNWs/SnO2·xH2O composite TEs reveal a significant reduction of four orders in magnitude of sheet resistance, from 90 kΩ sq−1 to 12 Ω sq−1, while retaining transmittance of about 92% at 550 nm. This could be owing to the significant reduction of contact resistance for the weld-like junction of bound AgNWs. Compared with others, this method is characterized by filling gaps of the silver nanowire network with SnO2·xH2O. In addition, the adhesive forces between the AgNWs and the substrate are improved. This could be attributed to strong adhesion of SnO2·xH2O with the substrate. Moreover, this foldable transparent electrode is applicable for any non-planar surfaces and ultimately for future wearable optoelectronic devices.


Introduction
A transparent electrode (TE) is an essential component for a wide variety of electronic devices, such as liquid crystal displays, touch screens, organic light emitting diodes (OLEDs), organic photovoltaics (OPVs), microchips, transparent heaters, and smart windows, etc. [1][2][3][4][5][6][7] For electronic devices, indium tin oxide (ITO) with a market share of 93% is the most widely used TE. 8 However, further application and development of ITO are expected to be receded due to three issues: scarcity of supply, expensive, and fragile ceramic nature. For these reasons, search for alternatives to ITO is motivated. Obviously, the ultimate market opportunity for alternative TEs is in fully exible devices. To compete with ITO, the material for the alternatives should possess certain characteristics, for instance, outstanding performance (e.g. transmittance > 95% and sheet resistance < 100 U sq À1 ), exible, good thermal-cycling, chemically stability, solution-phase coating processes, and costeffective. Recently, carbon based TEs are the most promising alternatives, but still have problems of conductivity, mechanical properties and cost. In addition, metal TEs are also a candidate of the best alternatives. Metal nanowires electrodes can meet the requirements for the alternatives. The Ag nanowires (AgNWs) TE has performance even better than ITO, 9 and is acknowledged as the proverbial "low-hanging fruit" for potential alternative to ITO.
However, pure AgNWs TEs also have three serious problems: low electrical conductivity, intrinsic nonconductive gaps which are not conductive and detrimental to the collection of carriers for the device, and poor adhesion to the substrate.
Firstly, pure AgNWs TEs still have electrical problems because of low contact between the AgNWs. As shown by experimental results, contact resistance of AgNWs (R c ) is the main source of sheet resistance (R sh ). The traditional methods for reducing R c and improving conductivity are heating and pressing. Some of new methods are laser nano-welding, graphene coating, chemical annealing, plasmonic welding. However, all these methods only solve the problem of electrical conductivity but are helpless for addressing the other two issues. [10][11][12][13][14][15][16][17] Secondly, pure AgNWs TEs have large area of blank space which is not conductive in AgNWs networks. In fact, AgNWs cover only 20% of the substrate. However, electrodes must cover all over the active areas for efficient charge extraction/injection because of the typically small lateral conductivity of organic semiconductor for some types of devices like OPVs and OLEDs. So, the concept of composite electrode is put forward. There are many methods to form a composite electrode with a silver nanowire, for example poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) welding, graphene coating, double-layer structure, electrospun nanobers, deposition of MnO 2 , TiO 2 , ZnO, AZO particles. The composite electrode can easily solve the problem of electrical conductivity and ll the gap between nanowires. Whereas PEDOT:PSS severely limits the device lifetime, and most of the nanoparticles need high temperatures (140 C to 250 C). Zilberberg et al. use sSnO x solgel process to fabricate the TEs even at room temperature with the method of atomic layer deposition (ALD). 23 But ALD limits the roll-to-roll production. So, currently, it still cannot achieve a large scale of cost-effective production. 10,[15][16][17][18][19][20][21][22][23] Thirdly, AgNWs TEs are easily to fall off the substrate due to the poor adhesion, which limits both of its usage and mass production. The composite electrode is very helpful to improve adhesion. However, the current technology is not suitable for roll-to-roll production.
In this work, we report a solution method to fabricate AgNWs TEs on PET substrate at room temperature which is suitable to the roll-to-roll production. More importantly, the fabrication processes are scalable and cost effective. With this method, the R sh of the TEs can be reduced by four orders while maintaining high transmission. In addition, the gaps between the nanowires are successfully lled and the adhesion between the AgNWs and the substrate are improved. Moreover, this exible transparent electrode is applicable for any exible substrate and ultimately for future wearable optoelectronic devices. This will be of great signicance to the extension and application of the electrode.

Synthesis of AgNWs
The AgNWs were synthesised by salt-assisted polyol method (Fig. 1a). 30 mL ethylene glycol (EG) solution of 0.052 mol L À1 AgNO 3 and 0.067 mol L À1 PVP was thoroughly agitated. In addition, another 30 mL EG solution was prepared and heated at 130 C for 1 h. 2.5 mL EG solution of 6 Â 10 À4 mol L À1 FeCl 3 was dropped into the heated 30 mL EG. Aer 5-10 min, the mixed solution containing AgNO 3 and PVP was added with a dropping speed of 0.5 mL min À1 into the heated solution. Finally, post-reaction solution was cooled naturally and then ltered by qualied lter paper (intermediate speed). AgNWs were washed out of the lter paper with deionized water. AgNWs were obtained by centrifugation at speed of 2000 rpm. Then the precipitation was retained, and the solution was replaced by ethanol. The step of centrifuge separation was repeated for three times.

Fabricate of AgNWs TEs
AgNWs were ultrasonically dispersed in ethanol with the concentration of 0.35 mg mL À1 (Fig. 1b). The AgNWs TEs were fabricated by the doctor-blade on the substrate of PET ( Fig. 1c and d). And then the lms were immersed in aqueous solution of SnCl 4 $5H 2 O (6% w) for 10 s. Finally, the TEs were washed with deionized water and dried.

Conductivity
The R sh of the AgNWs TEs without any post-treatment are as high as 90 kU sq À1 . This is a problem that AgNWs TEs usually have, mainly because AgNWs are piled up on the substrates without any contact. Therefore, the improvement of contact is very important for good conductivity. Fortunately, we found a scalable, and cost-effective way to solve this problem. The AgNWs TEs were immersed into the solution of SnCl 4 $5H 2 O (6% w) for 10 s. The R sh of initial AgNWs TEs, SnO 2 $xH 2 O lm and AgNWs/SnO 2 $xH 2 O composite TEs is shown in Fig. 2. The conductivity of the initial TEs is very poor with the R sh over 90 kU (blue pillar). Similarly, the R sh of the only SnO 2 $xH 2 O (red pillar) is 6 kU which is also too high for TEs. Fortunately, the R sh of the AgNWs/SnO 2 $xH 2 O composite TEs (green pillar) is just 12 U sq À1 . The R sh of AgNWs TEs was reduced dramatically from 90 kU sq À1 to 12 U sq À1 by 99% or about 4 orders of magnitude.
To found the cause of the increase in conductivity, we analysed the solution. The solution of SnCl 4 $5H 2 O is not stable and easy to be hydrolysed. The reactions in the aqueous solution of SnCl 4 $5H 2 O can be expressed as: (1)   Firstly, SnO 2 $xH 2 O can make the nanowire in close contact and ll the gap of AgNWs TEs. The nanowires will be adsorbed on the substrate due to the strong adhesion of SnO 2 with substrate. And adhesion of SnO 2 with glass can even reach 20 MPa. SnO 2 $xH 2 O can help the nanowires adhere rmly to the surface of the substrate and contact closely to each other for better transmission of electrons. Moreover, the lling of the voids by SnO 2 $xH 2 O is very important for electronic devices. The lling of the nonconductive voids can improve the collection of carriers which will improve the performance of electronic devices.
Secondly, Cl À ions could help to bind the AgNWs together and form a weld-like junction which will further increase the conductivity of the lm. As discussed in previous studies, 21 silver atoms in AgNWs may be dissolved slowly in the presence of Cl À and dissolved oxygen in water. Due to redox reactions, it will produce solvated silver ions (Ag + ). The redox reaction can be written as: We need to pay attention to the atomic oxygen on the silver surface. It may block the re-deposition of silver ions onto the silver surface. And atomic oxygen on the silver surface comes from molecular oxygen which is adsorbed and dissociated to atomic oxygen between 200 K and 500 K. 24 However, concentration of dissolved oxygen in water is very limited so that Ag + ions could redeposit onto the relatively more active AgNWs surface and junction. The deposition of Ag at the junction will allow the two nanowires to be successfully welded together and will reduce R c , which is the main source of R sh . So, the Cl À in the solution can help improve the conductivity of TEs.
In Table 1, the electrical properties of different composite TEs are compared and analysed. The last row presents our results, whose perform is seen to be better than other types of electrodes. When the length of the nanowire is doubled, the resistance is reduced by an order of magnitude. In contrast, while the diameter varies at 50-100 nm, the transmittance is maintained at 90%, the longer the nanowires are, the better the electrical properties. And we also found that when the length is the same, the thinner the nanowire is, the better the electrical properties are.

Optical properties
Optical properties are also an important aspect of transparent electrodes. Fig. 3 shows the change of transmittance (T), scattering (S), and haze (H) properties of initial AgNWs TEs and AgNWs/SnO 2 $xH 2 O composite TEs. Haze is a percentage of the transmitted light intensity which is more than 2.5 degrees deviation from the incident light. And haze is equal to the percentage ratio of the scattered light ux (S) within large angles deviating from the incident direction by more than 2.5 to the transmitted luminous ux (T), i.e.
where H represents haze, and S represents the large-angle scattered light ux, and T represents transmitted luminous ux. The demand for haze is not the same for different applications. For display devices, haze should be as small as possible (usually <1%). Yet, for photovoltaic devices, haze can be as large as possible to increase optical path length in devices. As shown in Fig. 3, for the initial AgNW TEs (black line), fabricated by means of the doctor-blade coating method, the transmittance is over 92.9% (at 550 nm wavelength). But the R sh is too high for the pure AgNW TEs. Similarly, the only SnO 2 $xH 2 O lm (blue line) has a transmittance of 93% but its conductivity is not good enough yet. In contrast, for the composite TE, its transmittance is little changed and remained at 92.7%, but its conductivity is signicantly improved, also its haze and scattering are increased by about 1%. This means that the presence of the SnO 2 $xH 2 O layer has little effect on the transmittance but will enhance the scattering due perhaps to the change of refractive index. Fig. 4a and b are the diagram of structure of the initial AgNWs TEs. Fig. 4c and d are the SEM image corresponding to the schematic in Fig. 4a. From Fig. 4c, we can see that the length of AgNWs is about 10-20 mm, and the diameter is 50-100 nm. As shown in Fig. 4d, AgNWs do not lie at on the substrate, but tilt arbitrarily. The contact between AgNWs is poor, and some of the nanowires are even turned up. Accordingly, the large resistance of the initial AgNWs TEs probably comes from the poor contact. Therefore, to reduce R sh , we need to rst reduce the R c . Fig. 4b and e are the schematic and SEM image of the composite TEs, respectively. Fig. 4e shows that SnO 2 $xH 2 O lled the gaps between nanowires or even covered the surface of the nanowires. Fig. 4f is a SEM image of damaged composite TEs which was made on a exible substrate and pulled to split. As clearly seen through the tearing lm in Fig. 4f, the gaps in the nanowire are really lled by the material. Fig. 4e and f show that nanowires are all compacted on the substrate and some nanowires are in good contact in AgNWs/SnO 2 $xH 2 O composite TEs.

Morphology
The junction of the composite TEs is tested by TEM to conrm the contact of the nanowires. Fig. 5a and b show the TEM images of the crossing structure of initial TEs and the composite TEs. For initial AgNWs TEs (Fig. 5a), the connection between the crossed AgNWs is not welded. And the force between the nanowires is mainly van der Waals force. For the AgNWs/SnO 2 $xH 2 O composite TEs, the connection between the crossed AgNWs is welded. The force of the weld-like junction is intermolecular force. Therefore, the nanowires are rmly and stably welded together although exfoliated by the ultrasonic from the substrate. This means that the solution of SnO 2 $xH 2 O can help to improve contact of nanowires.

Chemical analysis
The chemical in the nanowire gap is characterized. Fig. 6a shows the TEM-image of the lm. Obviously, there is a layer of material, which might be amorphous, deposited onto the surface of the TE and AgNWs. Based on the analysis of the components of the hydrolysis solution, the amorphous substance on the lm surface are believed to be SnO 2 $xH 2 O.
The elemental composition is determined by Energy Dispersive Spectrometer (EDS). Fig. 6c shows the EDS spectrum of the amorphous, and reveals the presence of tin (Sn), oxygen (O), carbon (C), copper (Cu) and chlorine (Cl) elements in the sample. Carbon is the most abundant. This could be attributed to the amorphous carbon-coated copper grids, which is also the source of copper. The small amount of chlorine comes from the H 2 SnCl 6 in the solution. The most important thing is verifying the existence of tin and oxygen in the amorphous thought to be SnO 2 $xH 2 O. To further conrm our speculation, we need to remove the crystalline water from the amorphous to verify the existence of SnO 2 . When SnO 2 $xH 2 O is annealed at 400 C for 30 min, SnO 2 $xH 2 O will be turned into the crystallized SnO 2 . The crystallized SnO 2 is characterized by high resolution transmission electron microscopy (HRTEM). The HRTEM image shows a clear lattice spacing of 3.3 A in Fig. 6b, which exactly matches to the (110) plane of single crystal SnO 2 .   (301) reection planes of tetragonal SnO 2 , respectively. The diffraction peaks of the products can be well indexed to the known tetragonal rutile SnO 2 (JCPDS 41-1445), which conrms the presence of SnO 2 in the annealed products. So far, the amorphous material is determined to be SnO 2 $xH 2 O.

Thermal stability
The thermogravimetric analysis of SnO 2 $xH 2 O shows that SnO 2 $xH 2 O began to severe loss of water from 100 C (Fig. 7a). Nevertheless, crystallization temperature of SnO 2 is about 400 C. If SnO 2 $xH 2 O is heated at 100 C or 200 C, we will get the amorphous substance which removed some of the crystal water.
This simple heat treatment surprisingly gives us an unexpected benet that the adhesion of the lm is signicantly improved. As we all know, the thin lm of AgNWs can easily be erased when we touch it gently due to the poor adhesion of the initial AgNWs TEs. However, there's always a way out! The adhesion of the composite electrodes is improved signicantly just with a 100 C or 200 C heating treatment. This is attributed to the strong adhesive strength between SnO 2 and the substrate. When the non-heated composite electrodes were taped and torn down just for one time, the R sh increased from 12 to 60 U sq À1 which is increased by 5 times (black line in Fig. 7b). Nevertheless, the 100 C or 200 C heating treatment has only a little inuence on the conductivity of the composite TEs (Fig. 7b). The R sh increases only by 3 U sq À1 . In addition, the thermal stability of the heated composite electrode is quite good. The R sh of the lm changes little but maintains at about 12 U sq À1 during heating (Fig. 7c). In conclusion, the adhesion of the composite TEs can be improved by heat treatment, and the TEs can also tolerate adhesive tape test.
XPS spectra are used to characterize the initial composite TEs and the heated composite TEs at 200 C. We want to know whether the heat treatment has other effects on the electrode, in addition to the loss of crystalline water. Fig. 8 shows the X-ray photoelectron spectroscopy (XPS) of the composite TEs. The XPS survey spectrum (Fig. 8a) shows the peaks of Ag 3d doublet, Sn 3d doublet, Sn 4d and O 1s peaks. There are two peaks with binding energies of 368.3 eV for Ag 3d 5/2 and 374.3 eV for Ag 3d 3/2 in the regional spectrum (Fig. 8b) of Ag 3d. This is consistent with the standard binding energy of pure silver. The peaks at a binding energy of 486.6, 495.3 and 27.1 eV (Fig. 8c) can agree with the Sn 3d 5/2 , Sn    3/2 and Sn 4d 3/2 , respectively. Their standard combination can be very close to the previously reported results, indicating that the valence states of Ag and Sn are 0 and +4, respectively. This means that the heat treatment at 200 C does not cause a change in the valence of the composite electrode.

Conclusions
As reported previously, AgNWs transparent electrode usually has the problems of poor initial conductivity and intrinsic gap between nanowires. This paper demonstrated a simple solutionprocessed method for a scalable, cost effective and exible AgNWs TEs. Compared with others, this method is characterized by the gap of the silver nanowire network lled by SnO 2 $xH 2 O. The electrode forms a new kind of AgNWs/SnO 2 $xH 2 O composite structure just with 10 s immersion in solution of SnCl 4 $5H 2 O at room temperature. It is conrmed that aqueous solution of SnCl 4 $5H 2 O could help to reduce the R sh by four orders of magnitude, from 90 kU sq À1 to 12 U sq À1 , while keep transmittance of about 92% at 550 nm. In addition, the adhesive forces between the AgNWs and the substrate is improved. The optimization of the performance is attributed to the effects of SnCl 4 $5H 2 O solution which mainly contains Cl À and SnO 2 $xH 2 O because of hydrolysis. There are two main effects on AgNWs TEs. Firstly, Cl À can help to fuse the contact of nanowires which reduces R c of TEs. Secondly, SnO 2 $xH 2 O can help to ll the space of networks. The conductivity of the composite TEs is improved attributed to this important lling. At the same time, the coverage on the active areas can improve the efficiency of charge extraction/injection for devices. Surprisingly, the adhesion of AgNWs TEs can be signicantly improved with 100 or 200 C heating. What's more, the simple solution-method at room temperature makes it possible for the roll-to-roll production.

Conflicts of interest
There are no conicts to declare.