Issue 10, 2018
From the journal:

Inorganic Chemistry Frontiers

High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(ii) based on hybrid compounds†

Yan-Li Wei,a   Jing Jing,a   Chao Shi, ORCID logo b   Heng-Yun Ye,b   Zhong-Xia Wang ORCID logo a  and  Yi Zhang ORCID logo *ab  

* Corresponding authors

a Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, P. R. China
E-mail: yizhang1980@seu.edu.cn

b Chaotic Matter Science Research Center, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China

Abstract

Two novel tetrahedral manganese(II) complexes, (N-methylpiperidinium)MnCl4 (1) and (N-methylpyrrolidinium)MnCl4 (2), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37% and 2 emits unusual red emission at 611 nm.

Graphical abstract: High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(ii) based on hybrid compounds

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Article information

DOI
https://doi.org/10.1039/C8QI00793D
Article type
Research Article
Submitted
31 Jul 2018
Accepted
01 Sep 2018
First published
03 Sep 2018

Inorg. Chem. Front., 2018,5, 2615-2619

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High quantum yield and unusual photoluminescence behaviour in tetrahedral manganese(II) based on hybrid compounds

Y. Wei, J. Jing, C. Shi, H. Ye, Z. Wang and Y. Zhang, Inorg. Chem. Front., 2018, 5, 2615 DOI: 10.1039/C8QI00793D

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