Fluorinated Aryl Sulfonimide Tagged (FAST) salts: modular synthesis and structure– property relationships for battery applications

Solid-state electrolytes are attracting great interest for their applications in potentially safe and stable high-capacity energy storage technologies. Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) is widely used as a lithium ion source, especially in solid-state polymer electrolytes, due to its solubility and excellent chemical and electrochemical stability. Unfortunately, chemically inert LiTFSI cannot be easily modified to optimize its properties or allow for conjugation to other molecules, polymers, or substrates to prepare single-ion conducting polymer electrolytes. Chemical modifications of TFSI often erode its advantageous properties. Herein, we introduce Fluorinated Aryl Sulfonimide Tagged (FAST) salts, which are derived from successive nucleophilic aromatic substitution (S N Ar) reactions. Experimental studies and density functional theory calculations were used to assess the electrochemical oxidative stabilities, chemical stabilities, and degrees of ion dissociation of FAST salts as a function of their structures. FAST salts oﬀer a platform for accessing functional sulfonimides without sacrificing many of the advantageous properties of TFSI. with higher theoretical energy densities beyond lithium-ion batteries, such as lithium–air and lithium–sulfur batteries. LiTFSI is also the most studied lithium salt especially in solid-state polymer electrolytes, due to its desirable solubility and excellent stability. However, chemically inert LiTFSI cannot be easily modified to optimize its properties or for conjugation to other molecules, polymers, or substrates to prepare single-ion conducting polymer electrolytes. Herein, we report the synthesis, chemical and electrochemical stability, and conductivity study of a new family of modular salts, Fluorinated Aryl Sulfonimide Tagged (FAST) salts that are derived from successive nucleophilic aromatic substitution (S N Ar) reactions. The tunable chemical and electrochemical oxidative stability as well as Lewis basicity of FAST salts opens up new opportunities for the design and applications of polymer–FAST conjugates and single-ion conductors in solid-state electrolytes for safe and stable high-energy storage technologies.


Introduction
The high energy density, reliability, and low cost of rechargeable lithium-ion batteries (LIBs) have revolutionized the consumer market for portable electronic devices. 1,24][5] As LIBs approach the theoretical specific energies of cathode/anode materials, extensive studies have focused on finding new battery chemistries beyond LIBs. 61][12][13][14][15] For example, new electrolytes with high conductivity (410 À4 S cm À1 at room temperature), stability, and safety are needed. 7,13,14,16Most electrolyte materials that have been studied to date rely on mixtures of lithium salts such as lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) or lithium hexafluorophosphate (LiPF 6 ) and a suitable solvent and/or polymer. 16,17Comparing LiTFSI and LiPF 6 , LiTFSI offers a broad electrochemical stability window, 18 greater thermal stability, and higher resistance to hydrolysis, 19 which lead it to be preferred in Li-air and Li-S batteries. 19Additionally, due to its high solubility in water (421 M) and ability to form a passivation layer (mainly LiF), LiTFSI has been used in ''water-in-salt'' electrolytes enabling high-voltage aqueous lithium-ion batteries. 20,21Moreover, encouraging results have been reported on utilizing TFSI salts in sodium-air batteries 22 and multivalent energy storage systems such as magnesium batteries. 237][28] One strategy to improve the Li + (or Na + in sodium batteries) transference number involves anchoring the anions to a polymeric backbone, making the cation the only mobile ion (i.e., single-ion conducting polymer electrolytes). 29[36] TFSI derivatives where one or both trifluoromethyl groups are replaced with functional yet still electron withdrawing substituents, such that the beneficial properties of TFSI are not comprised, would be highly desirable.We identified perfluoroarylsulfonimides A, B, and C (Scheme 1) as potential starting points to achieve this goal.The installation of perfluoroaryl substituents in these compounds could maintain the electron deficient nature of the anion and open the possibility of chemical modification via nucleophilic aromatic substitution (S N Ar) reactions.Herein, we report our studies on the synthesis and characterization of this new class of sulfonimide salts, which we call ''Fluorinated Aryl Sulfonimide Tagged'' (FAST) salts.Successive S N Ar reactions between A, B, or C and oxygenand/or nitrogen-base nucleophiles enabled rational tuning of the electron density, electrochemical oxidative stability, chemical stability toward superoxide and peroxide anions, and Lewis basicity of FAST salts as assessed by both experimental studies and density functional theory (DFT) calculations.Our design led to several FAST salts that display electrochemical oxidative stability at 4.0 V Li , negligible chemical degradation, and reasonable ion conductivity in 1,2-dimethoxyethane (DME) and PEO.FAST salts offer a synthetically tunable platform for the identification of optimal anion structures that could replace TFSI in a variety of applications.

Results and discussion
The perfluoroarylsulfonimide sodium salts A and C were prepared starting from pentafluorobenzene sulfonyl chloride in good yield (482%), whereas salt B was prepared via condensation of 4-trifluoromethyl-2,3,5,6-tetrafluorobenzenesulfonyl bromide 37 and trifluoromethanesulfonamide in 72% yield.With these compounds in hand, we embarked on the synthesis of a library of FAST salts (Fig. 1) via S N Ar reactions between A, B, or C and a variety of nucleophiles selected to assess the impact of steric bulk and electronics on the salts' properties: phenoxide (OPh), Scheme 1 Synthesis of perfluoroarylsulfonimide anions A, B, and C and their subsequent functionalization via S N Ar reactions to generate FAST anions of the general formula P-Pip x OR y F z .Note: the cations used in this study, Na + and Li + , are not shown.

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Energy & Environmental Science alkoxides (OR: OMe, OEt, OiPr, and ONeop), and piperidine (Pip).Throughout this work, we use the general notation P-Pip x OR y F z to represent each FAST salt, where P is the parent salt (A, B, or C), and x, y, and z are the numbers of piperidine, alkoxide, and fluorine substituents, respectively.All FAST sodium salts were characterized by 1 H, 13 C, 19 F NMR, MS, and in some cases, single crystal X-ray crystallography.
We were able to exploit differences in the reactivity of the various nucleophiles in this system to control the substituent patterns in the resulting FAST salts.For example, selective S N Ar of the para fluorine atom of A with Pip could be achieved to provide A-PipF 4 ; subsequent S N Ar of the remaining ortho fluorine atoms with OPh, OMe, or OEt groups provided A-PipOPh 2 F 2 , A-PipOMe 2 F 2 and A-PipOEt 2 F 2 , respectively.The structures of the sodium salts of these compounds were confirmed by X-ray crystallography (Fig. 2).Notably, though these newly introduced N and O substituents are electron donating, this substitution pattern maintains the two electron-withdrawing meta fluorine substituents (Hammett parameters for fluorine: s meta = 0.34 versus s para = 0.06).As seen in Fig. 2, the sulfonimides in these structures are present as their free base; the sodium cations are not coordinated to the nitrogen but instead coordinate to the oxygen atoms from the sulfonimide groups, alkoxide groups, and/or adventitious water (Fig. 2b).When two piperidine groups are introduced onto the A scaffold the resulting FAST salts (e.g., A-Pip 2 F 3 and its derivatives A-Pip 2 ORF 2 ) are much less acidic (they are protonated during aqueous washing); the crystal structure of A-Pip 2 F 3 ÁH + (Fig. S1, ESI †) reveals that the proton is coordinated by the nitrogen atom of the ortho-Pip.Therefore, FAST salts containing two Pip substituents were deprotonated with sodium hydroxide prior to further investigations.

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The electrochemical oxidative stability and average partial charge of aromatic carbons, c + , obtained using Natural Population Analysis (NPA) 38,39 of select tri-substituted FAST salts as well as A, A-NeopF 4 , and A-Neop 2 F 3 depicted in Fig. 1 were evaluated using DFT calculations (Fig. 3) following the BANE framework we developed recently. 40We observed that higher computed electrochemical oxidation potential correlated well with higher average aromatic carbon charge, c + .More specifically, FAST salts with the greatest number of electron donating Pip groups (e.g., A-Pip 2 ORF 2 ) exhibit the lowest c + and electrochemical oxidative stability.FAST derivatives with one Pip group (e.g., A-PipOR 2 F 2 ) showed higher c + and electrochemical oxidative stability than A-Pip 2 ORF 2 .As expected, the trialkoxide derivatives A-OR 3 F 2 , in turn, exhibited higher c + and electrochemical oxidative stability than A-PipOR 2 F 2 .Finally, in the order of A-Neop 2 F 3 , A-NeopF 4 , and A, as the number of electron withdrawing F atoms increases, the computed c + and electrochemical oxidative stability increase almost linearly.
To further understand the electrochemical oxidative stability of our FAST salts, HOMO and LUMO maps for four representative salts, A-ONeop 3 F 2 , A-PipONeop 2 F 2 , A-o-PipONeop 2 F 2 , and A-Pip 2 ONeopF 2 were compared (Fig. 4).These salts show similar LUMOs but significantly different HOMOs: the HOMO of A-ONeop 3 F 2 is uniformly distributed on the aromatic ring with little density on the oxygen atoms of the alkoxide substituents.FAST salts with a Pip group featured HOMOs that were heavily localized on the Pip nitrogen atom.Surprisingly, the HOMO maps of A-PipONeop 2 F 2 and A-o-PipONeop 2 F 2 are drastically different.The HOMO of A-PipONeop 2 F 2 is distributed on both the benzene ring and the Pip nitrogen atom, while nearly all the HOMO is concentrated on the Pip nitrogen atom in the ortho position in both A-o-PipONeop 2 F 2 and A-Pip 2 ONeopF 2 .These observations may explain the observed basicity of A-o-PipONeop 2 F 2 and A-Pip 2 ONeopF 2 that was not observed for other salts.
We carried out experimental measurements to evaluate the electrochemical oxidative stability of several of these FAST salts under an oxygenated environment for comparison to the DFT computed trends obtained in implicit DMSO solvent.The electrochemical oxidative stability of our FAST salts was determined using potentiostatic measurements in an electrochemical cell (glass fiber separator impregnated with 0.02 M sulfonimide dissolved in propylene carbonate (PC) solution sandwiched between Li metal foil and stainless steel mesh current collector), which was pressurized with oxygen and held at potentials from 3.0 to 4.5 V Li for 3 h each.PC was chosen as the solvent due to its superior electrochemical stability, 17,18 although it should be noted that its vulnerability against nucleophilic substitution makes it unsuitable as electrolyte solvent for Li-O 2 battery. 43,44A relatively low concentration, 0.02 M, was employed to accommodate the low solubility of several FAST salts such as A-Pip 2 OEtF 2 in PC.In general, A-Pip 2 ORF 2 compounds have limited solubility in PC (o0.1 M) and 1,2-dimethoxyethane (DME, 0.1 M to 0.5 M).Nonetheless, other FAST salts shown in Fig. 1 display much higher solubility (41 M) in common solvents used in battery systems.For example, we tested the solubility of representative sodium salts of A, A-PipF 4 , and A-ONeop 3 F 2 .In a typical battery system, the concentration of salt is usually 1 M.Each of these three salts have solubility larger than 1 M in PC   41,42 Fig. 4 Computed LUMOs (top row) and HOMOs (bottom row) of four representative FAST anions.The HOMO/LUMO maps were generated using the optimized geometries obtained at B3LYP/6-31G(d,p).The HOMO/LUMO energy in eV were obtained at B3LYP/6-311++G(d,p) level of theory with geometries optimized using B3LYP/6-31G(d,p).Atom color code: grey -carbon, white -hydrogen, red -oxygen, aqua -fluorine, yellow -sulfur, and blue -nitrogen.

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Energy & Environmental Science (common solvent for aprotic LIBs) and DME (common solvent for Li-air batteries) at room temperature.The sodium salt of A has a solubility of 10 m in water.With more hydrophobic substitutions, the solubility in water would decrease.A-PipF 4 has solubility larger than 1 M in water, while A-ONeop 3 F 2 has solubility of 0.5 M in water.One key advantage of our approach is that by simple modification of the substituents, it is possible to tune solubility as needed.For example, if increased water solubility were desired, one could use hydrophilic nucleophiles in the S N Ar reaction.The current response, cumulative charge, and estimated percentage of salt oxidation at each potential step from 3.6 V Li to 4.5 V Li for select salts are shown in Fig. 5.
The percentage of electrochemically oxidized salt was calculated based on the assumption that the oxidation of one FAST salt molecule produces one electron.We note that deviation from this assumption and the presence of impurities can lead to overestimation of the electrochemical oxidation percentage, which can explain why several salts showed electrochemical oxidation percentages that are close to or even greater than 100%.In Fig. 5a  and c, the series of A, A-ONeopF 4 , A-ONeop 2 F 3 , A-ONeop 3 F 2 are compared.All four salts in this series, which feature 2 to 5 fluorine atoms and 0 to 3 ONeop substituents on the aromatic ring, were very stable towards oxidation with approximately 2% and 6% oxidized upon charging to 4.2 V Li and 4.5 V Li , respectively (Fig. 5c).Upon charging to 4.5 V, TFSI exhibited electrochemical oxidation roughly an order of magnitude lower than the four salts in this series.However, these fours salts are more stable than (phenylsulfonyl)(trifluoromethyl)sulfonimide (Ph-TFSI), a widely used TFSI alternative in battery applications. 25,45Next, the influence of the substitution pattern on the oxidative stability of triply substituted salts A-OR 3 F 2 was measured (Fig. 5b and c).These salts showed excellent oxidative stability at voltages o4.0 V Li with the exception of A-OMe 3 F 2 , which exhibited significant oxidative current at 3.8 V Li .Generally, the FAST salts with bulkier alkoxide groups (e.g., OiPr and ONeop) exhibited superior stability than those with smaller substituents such as OMe and OEt at high voltage (44.0 V Li ).The influence of Pip on the electrochemical stability was investigated by comparing  Energy & Environmental Science Paper charging to 4.2 V Li , respectively.This stability trend matches the DFT calculations presented in Fig. 3 . Finally, several A type FAST salts with one piperidine group A-PipOR 2 F 2 and B type FAST salts B-OR 4 were tested and compared in Fig. 5e and f.As shown by the cumulative charge and estimated oxidized percentage in Fig. 5f, A-PipOR 2 F 2 and B-OR 4 generally have higher charge accumulation and worse electrochemical oxidative stability than A-OR 3 F 2 at 44.0 V Li .Overall, most of the salts in Fig. 2 show electrochemical oxidative stability at 4.0 V Li and thus are promising candidates in diverse battery chemistries.Notably, A-ONeop 3 F 2 was extremely stable to electrochemical oxidation (up to 4.5 V Li with oxidative current less than 0.25 mA and oxidation percentage is less than 6%).Next, the chemical stability of various FAST salts was investigated under solution conditions designed to mimic the oxygen electrode of a typical aprotic Li-air battery. 40,46,47Each FAST salt was dissolved in DMF (20 mg mL À1 ) and mixed with 12.5 equivalents of Li 2 O 2 , KO 2 , and 1 equivalent of 4-methoxybiphenyl as internal standard (for quantitative NMR analysis); the mixture was stirred at 80 1C for 3 days.The supernatant of the mixture was characterized by 1 H, 19 F-NMR, and liquid chromatography-mass spectrometry (LC-MS).Generally, FAST salts with a greater number of aryl fluoride groups displayed lower chemical stability: for salts derived from A and C, only those with two meta fluorine atoms have negligible degradation, whereas in salts derived from B no aryl fluorides were tolerated due to the strong electron withdrawing effect of -CF 3 group (s para = 0.54).For tri-substituted salts derived from A (Scheme 1 and Fig. 1), the chemical stability was strongly affected by the identity and pattern of the substituents.Fig. 6 provides a comparison of the percentage of degradation (obtained by quantitative 1 H NMR) of each salt.For salts derived from A, we observed that bulkier -OR substituents improved the stability against chemical degradation.A-OMe 3 F 2 was observed to degrade almost completely (91%) while no degradation was detected for A-ONeop 3 F 2 .FAST salts with Pip groups exhibited greater chemical stability than those with -OR substitutions: the degraded percentage decreased from 65% in A-OPh 3 F 2 and 91% in A-OMe 3 F 2 to 16% in A-PipOPh 2 F 2 and 15% in A-PipOMe 2 F 2 .When two Pip groups were introduced (A-Pip 2 ORF 2 ), less than 4% degradation was observed regardless of the identity of R.These experimental results for chemical stability are inversely correlated with the calculated average carbon atomic charges on the aromatic ring: A-Pip 2 ORF 2 4 A-PipOR 2 F 2 4 A-OR 3 F 2 , which supports the expectation that more electron rich FAST salts should be less susceptible to nucleophilic attack.Furthermore, we computed the Gibbs free energy for nucleophilic substitution by superoxide, DG nuc , at select carbon sites (i.e., O-CH 3 ) in A-OMe 3 F 2 , A-PipOMe 2 F 2 , and A-Pip 2 OMeF 2 (Fig. S2, ESI † ) follows the trend in the chemical stability of these salts determined experimentally.Finally, we plotted the computed DG nuc against the increase in the NPA partial charge of the attacking oxygen in superoxide (partial charge of the oxygen after the substitution reaction minus its partial charge before the reaction; Fig. S2, ESI †).It is observed that a larger increase in the oxygen partial charge corresponds to a more favourable DG nuc ; this correlation was also observed in our recent study on the nucleophilic substitution of small organic molecules such as carbonates and ethers by superoxide. 40This trend suggests that a larger increase in the attacking oxygen partial charge indicates stronger electron-donating strength of superoxide at the carbon site, which gives rise to more favourable DG nuc .
Ion conductivity in liquid electrolytes depends upon two factors: charge carrier concentration and mobility.With the same concentration of salts, the extent to which the salt is dissociated determines the charge carrier concentration.9][50] The TFSI anion is well known for being an ''innocent'' anion with weak interactions with metal ions. 50To compare our FAST salts with TFSI and evaluate the extent of ion dissociation, the anion-cation interaction strengths for our FAST salts were determined by 23 Na NMR. 50,51The sodium salts were prepared as 0.1 M solutions in nitromethane with 0.25 M NaClO 4 in DMSO as the internal standard.The 23 Na chemical shifts of FAST salts relative to NaTFSI are shown in Fig. 7a.It is immediately obvious that the nature of the anion plays an important role in the resulting chemical shift.For example, A-OR 3 F 2 and A-PipOR 2 F 2 have 23 Na signals that are shifted downfield, indicating stronger anion-Na + interactions than the parent type A and B salts.A considerable amount of line broadening was also observed and can be attributed to the formation of more ion pairs. 51We propose that as the FAST salt anions become more electron rich (i.e., as the number of F atoms decreases), they become more Lewis basic, display stronger interactions with Na + , and produce more ion pairs.To validate this hypothesis and study the effect of different substitution groups on anion-Na + interaction and ion conductivity, we plotted the calculated Gibbs free energy of ion pair association,

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Energy & Environmental Science DG assoc , versus the relative 23 Na chemical shifts as well as the ion conductivities of DME solutions containing several FAST salts at 0.1 M experimentally obtained at 25 1C (Fig. 7b).Implicit diethylether solvent with dielectric constant set at 7.2 was used to mimic the solvent used for conductivity studies (DME).As expected, salts with more negative calculated DG assoc values (more favorable anion-Na + association) have more down-field shift in 23 Na NMR spectrum and displayed lower conductivity.More specifically, we observed that solutions containing type A and B salts have ion conductivities that are a factor of 2 and 1.5, respectively, lower than that of NaTFSI while A-ONeop 3 F 2 , A-PipF 4 and A-PipONeop 2 F 2 exhibit conductivities that are 4 to 7 times lower.The conductivities of solutions containing these salts are inversely related to the salt anion Lewis basicity and anion-cation interaction strength.Furthermore, 23 Na NMR chemical shift of other B type and C type salts were also measured shown in Fig. S3a (ESI †).Here acetonitrile was chosen as solvent due to low solubility of B and C type salts in nitromethane.Acetonitrile solvates Na + better than nitromethane and thus decreases the anion-Na + interaction strength difference. 51Nevertheless, we observed that salts with more S N Ar substitutions have 23 Na signal shift toward down field and line broadening comparing with B and C parent salts (Fig. S3a, ESI †); these salts also exhibit more favorable DG assoc for anion-Na + association and lower ion conductivity in DME solution (Fig. S3b, ESI †).Overall, salts with more S N Ar substitutions among all three types have greater Lewis basicity, which leads to stronger interaction with Na + and more negative DG assoc values.These results highlight the balance of factors that must be considered in the design of functional FAST salts.The Li FAST salts could be readily acquired by ion exchange of the Na salts.We prepared four Li salts from A, A-PipF 4 , A-ONeop 3 F 2 , and A-PipONeop 2 F 2 .The 7 Li and 23 Na NMR spectra show nearly complete replacement of Na + by Li + in A (Fig. S4, ESI †).The ionic conductivities of solid-state polymer electrolytes prepared by blending these Li salts with PEO (10 kDa; molar ratio of PEO repeat unit and Li + [EO] : [Li + ] = 15 : 1) are shown in Fig. 8a.These FAST-PEO blends exhibited a similar ionic conductivity trend to their corresponding sodium salts in liquid electrolytes: blends with Li salts A and A-PipF 4 have ionic conductivities that are 2 and 4 times lower, respectively, than that of LiTFSI.Polymer electrolytes containing Li salts of A-PipONeop 2 F 2 and A-ONeop 3 F 2 showed conductivities in the range from 60 1C to 80 1C that were approximately one order of magnitude lower than that of LiTFSI.As in liquid electrolyte, the lower ion conductivity of FAST-PEO blends can be attributed to higher Lewis basicity of these salts and the formation of more ion pairs (Fig. 8b), which leads to a lower concentration of charge carriers.Another reason for the observed lower ion conductivity could simply be size, as the mobility of larger FAST anions may be decreased, which would reduce overall ion conductivity.Nevertheless, in light of the all of the results discussed above, A-ONeop 3 F 2 shows chemical and oxidative stability on par with TFSI and reasonable conductivity, thus suggesting the potential use of this and other trisubstituted FAST salts as functional TFSI replacements.

Conclusions
In summary, we have developed a novel class of sulfonimide salts that are based on successive S N Ar reactions of fluorinated phenyl sulfonimides: Fluorinated Aryl Sulfonimide Tagged (FAST) salts.Using DFT calculations and experimental measurements, we demonstrated that the chemical and electrochemical oxidative stability of FAST salts are inversely correlated with each other as the number of fluorine atoms present on the aromatic ring is varied.FAST salts with strongly electron donating Pip substituents generally showed better chemical stability compared to those with ether substituents; however, the sterically hindered salt A-ONeop 3 F 2 was also highly resistant to chemical degradation.FAST salts with Pip groups were more vulnerable to electrochemical oxidation than those containing only ether substituents; here again, ONeop 3 F 2 displayed outstanding stability.Other properties like solubility, Lewis basicity, and conductivity could also be tuned by introducing different numbers and types of nucleophilic functional groups to the FAST salt scaffold.FAST salts provide a new anion design strategy, enabling alternatives to TFSI with properties that can be rationally varied in a highly modular fashion.In particular, the ability to readily control the pattern of functionalization on the FAST scaffold and predict the resulting chemical and  electrochemical oxidative stability as well as basicity opens up new opportunities for the design of polymer-FAST conjugates and single-ion conductors, meeting the growing interest of solidstate electrolytes as potentially safe and stable high-energy storage technologies.

Fig. 1
Fig. 1 Chemical structures of FAST anions synthesized in this work via S N Ar reactions between various nucleophiles and parent salts A, B, or C.

Fig. 3
Fig.3Electrochemical oxidative potentials of select FAST salts computed using B3LYP/6-311++G(d,p) with geometries fully optimized at the B3YLP/ 6-31G(d,p) level of theory in implicit DMSO solvent are plotted against the arithmetic average of the NPA partial charges of aromatic carbons obtained at the optimized geometries.The electrochemical oxidation potentials in experimentally measured scale versus Li/Li + , plotted on the right axis, were converted from the computed -G ox in eV by the subtraction of 1.4 V.41,42

Fig. 5
Fig.5The influence of S N Ar substitutions on the electrochemical oxidative stability of representative FAST salts in potentiostatic tests.The current response of A-OR y F z as functions of time show very low current up to 4.5 V Li (a).The current response of different types of alkoxide substitutions in A-OR 3 F 2 were also compared in (b).The cumulative charge and estimated oxidized percentage of A-OR y F z and A-OR 3 F 2 were calculated in (c).The current response of salts with different numbers of piperidine type substitutions, A-Pip x OR y F z , and those in the A-PipOR 2 F 2 series were recorded in (d) and (e), respectively; their cumulative charge and estimated oxidized percentage are shown in (f).Measurements were performed using an electrochemical cell pressurized with oxygen and consisting of a stainless steel mesh current collector, 90 mL 0.02 M FAST-PC solution, one glass fiber separator, and Li metal.

Fig. 6
Fig. 6 Chemical and electrochemical oxidative stability test results for FAST salts.The black circles indicate the degradation percentages of the sulfonimide salts after incubation with 12.5 equiv. of Li 2 O 2 and KO 2 in DMF for three days at 80 1C.Percent degradation was quantified by 1 H NMR using 4-methoxybiphenyl as a reference standard.The electrochemical oxidation percentages of the corresponding FAST salts in the potentiostatic tests at the end of the 4.2 V Li step are shown by the grey circles.

Fig. 7
Fig. 7 (a) The measured chemical shift of 23 Na NMR signal for representative FAST salts (the 23 Na signal from the inner standard, NaClO 4 , is set to 0 ppm).(b) The 23 Na NMR chemical shift (relative to NaTFSI) and ion conductivity of 0.1 M DME solution at 25 1C versus the computed anion-Na + association free energy, DG assoc , in implicit diethylether solvent with dielectric constant set at 7.2 for representative FAST salts.

Fig. 8
Fig. 8 (a) The ion conductivities of solid state FAST-PEO electrolytes prepared via blending representative LiFAST salts and PEO (molar ration of PEO repeat units and lithium ion [EO] : [Li + ] = 15 : 1) at various temperatures.(b) The conductivity of FAST-PEO electrolytes at 60 1C versus computed free energy of anion-Li + association, DG assoc , in implicit diethylether solvent with dielectric constant set at 7.2.