Issue 31, 2018
From the journal:

Dalton Transactions

Difuryl(supermesityl)borane: a versatile building block for extended π-conjugated materials†‡

Nicolas A. Riensch,§a   Lars Fritze,§a   Tobias Schindler,a   Marius Kremera  and  Holger Helten ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: holger.helten@ac.rwth-aachen.de

Abstract

Direct functionalization and Pd-catalyzed cross-coupling of difuryl(supermesityl)borane (1) led to highly emissive organoborane compounds 3 and 4. Photophysical and TD-DFT studies reveal an increase of the HOMO levels with higher hetarene content and stabilization of the HOMO and LUMO levels through B-doping, leading to very robust, air-stable electron-accepting materials.

Graphical abstract: Difuryl(supermesityl)borane: a versatile building block for extended π-conjugated materials

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Article information

DOI
https://doi.org/10.1039/C8DT01716F
Article type
Communication
Submitted
30 Apr 2018
Accepted
17 May 2018
First published
18 May 2018

Dalton Trans., 2018,47, 10399-10403

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Difuryl(supermesityl)borane: a versatile building block for extended π-conjugated materials

N. A. Riensch, L. Fritze, T. Schindler, M. Kremer and H. Helten, Dalton Trans., 2018, 47, 10399 DOI: 10.1039/C8DT01716F

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