Issue 50, 2018

Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

Abstract

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the corresponding phenanthrene analogues with boron and nitrogen in the 9- and 10-positions, respectively.

Graphical abstract: Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

Supplementary files

Article information

Article type
Communication
Submitted
23 Feb 2018
Accepted
09 Mar 2018
First published
09 Mar 2018

Chem. Commun., 2018,54, 6808-6811

Intermolecular insertion reactions of azides into 9-borafluorenes to generate 9,10-B,N-phenanthrenes

S. Yruegas, J. J. Martinez and C. D. Martin, Chem. Commun., 2018, 54, 6808 DOI: 10.1039/C8CC01529E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements