Selective hydrosilylation of olefins by a two-dimensional Rh(I) low-valent metal–organic framework

Dipendu Mandal; Madison R. Esposito; Samuel E. Griffin; Grant P. Domecus; Seth M. Cohen

doi:10.1039/D5CC02201K

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Selective hydrosilylation of olefins by a two-dimensional Rh(i) low-valent metal–organic framework†

Dipendu Mandal,

^a Madison R. Esposito,

^a Samuel E. Griffin,

^a Grant P. Domecus^a and Seth M. Cohen

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California, USA
E-mail: scohen@ucsd.edu

Abstract

Multitopic phosphine ligands combined with Rh(I) or Ir(I) nodes are shown to assemble into low-valent metal–organic frameworks (LVMOFs) with a two-dimensional (2D) topology. The 2D Rh(I) LVMOF exhibits catalytic activity for the hydrosilylation of olefins, functioning in a heterogeneous and selective manner.

This article is part of the themed collection: Emerging Trends in Advanced Functional Porous Materials

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DOI: https://doi.org/10.1039/D5CC02201K
Article type: Communication
Submitted: 20 Apr 2025
Accepted: 16 Jun 2025
First published: 19 Jun 2025

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Chem. Commun., 2025, Advance Article

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Selective hydrosilylation of olefins by a two-dimensional Rh(I) low-valent metal–organic framework

D. Mandal, M. R. Esposito, S. E. Griffin, G. P. Domecus and S. M. Cohen, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC02201K

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Chemical Communications

Selective hydrosilylation of olefins by a two-dimensional Rh(i) low-valent metal–organic framework†

Abstract

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Selective hydrosilylation of olefins by a two-dimensional Rh(I) low-valent metal–organic framework

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