Dandelion-shaped TiO2/multi-layer graphene composed of TiO2(B) fibrils and anatase TiO2 pappi utilizing triphase boundaries for lithium storage

A three-dimensional dandelion-shaped TiO2/multi-layer graphene compound (TiO2/MLG) composed of TiO2(B) fibrils and anatase pappus structures has been synthesized as a potential anode material for Li storage. Electron microscopy indicates that the composite contains triphase boundaries between anatase, TiO2(B) and graphene, which are responsible for the enhancement of energy storage and the decrease of electrode polarization. Cyclic voltammetric investigations indicate that both Li insertion and pseudocapacitance contribute to charge storage. Ultrahigh specific capacities of 243 and 182 mA h g 1 have been obtained at 0.1 and 1 A g , respectively. Moreover, the excellent capacity retention can reach 99.6% after 100 cycles with almost 100% coulombic efficiency at 0.1 A g . The importance of the triphase boundary in enhancing the storage of charge and transport of Li is demonstrated.


Introduction
As a consequence of an increasing demand for energy, improved energy storage is required to enable future power systems. Lithium-ion batteries offer high energy and power density and as a result are attracting great interest with a focus on designing electrodes that can enhance energy-storage performance. 1,2 Titanium dioxide (TiO 2 ), one of the most promising anode materials, has been intensively studied, not only due to its low cost, abundance and non-toxicity but also on account of the negligible volume deformation during the Li-ion insertion/de-insertion processes (intercalation is preferred to describe lithium storage in a laminar host structure) 3 and excellent gravimetric capacity. [3][4][5] The operational potential of TiO 2 is high (>1 V vs. Li + /Li), which can enhance battery safety by reducing the probability of the formation of lithium dendrites at the anode surface and avoiding the formation of a solid electrolyte interface (SEI). [6][7][8] To-date various polymorphs of TiO 2 including anatase (tetragonal), 9 rutile (tetragonal), 5 brookite (orthorhombic) 10 and bronze (TiO 2 -B, monoclinic) 11 have been extensively studied as anode materials in lithium-ion batteries. The other allotropes, which either are easily transformed to other types like ramsdellite (TiO 2 -R) 12 and hollandite (TiO 2 -H) 13 or need high-pressure and high-temperature synthesis conditions, such as a-PbO 2 -structured TiO 2 (II), 14 baddeleyite, 15 columbite, 16 cubic, 17 TiO 2 (OI) 18 and TiO 2 (OII), 19 have been rarely researched. Despite the numerous studies, TiO 2 has not been used extensively as a high rate anode material owing to its limited ability to store charge and poor conductivity.
An intrinsic drawback of TiO 2 is the material's poor electronic conductivity (10 À13 S cm À1 ) 5,20,21 and limited ionic conductivity. 22 Several solutions have been proposed to overcome this issue including: (i) addition of a conducting phase, e.g., carbon coating 23 or compositing with transition metal oxides, 24 (ii) reduction of the ionic diffusion length by fabricating nanoscale TiO 2 structures such as wires, 25 tubes, 26 cubes, 27 rods 28 and owers, 8 and (iii) doping through either the introduction of Ti 3+ or oxygen vacancies 5,29 or with heteroatoms B, 30 C, 6 N, 31 S, 32 Ni, 33 Zn 34 or Sn. 35 Charge stored in a Li + /heterophase anode system may be enhanced 36-39 through interfacial charge storage at both the solidliquid interface and internal solid-solid interfaces. Jamnik and Maier have demonstrated increased charge storage at TiO 2 -metal interfaces as a result of the metal acting as an electron sink and the TiO 2 storing excess Li + . In TiO 2 photochemical studies, it has been demonstrated that owing to the offset in the conduction band levels, photogenerated charge carriers can be stored at the junction between anatase and TiO 2 (B). [40][41][42] This band offset has been employed in TiO 2 engineering to yield a material in which Li + and electrons are separated across TiO 2 (B)/anatase TiO 2 interfaces within the anode leading to increased charge storage.
In the present work we have fabricated a new TiO 2 -graphene composite designed to enhance the prospects of this low cost, abundant, non-toxic material as an anode in a Li-battery. The TiO 2 is dandelion shaped with nanosized TiO 2 (B) brils capped with anatase TiO 2 pappi. The as-prepared structure has extensive solid-electrolyte and solid-solid junctions to maximize interfacial charge storage. Multilayered graphene (MLG) is added to the TiO 2 phases to yield a composite with enhanced conductivity and an increased number of solid-solid junctions.

Experimental
Materials preparation: dandelion-shaped TiO 2 /multi-layer graphene (TiO 2 /MLG) and the compared TiO 2 anode materials were synthesized by a solvent-thermal method. For TiO 2 /MLG preparation, 0.24 g polyvinylpyrrolidone (PVP, Sigma, average mole weight: 360 000) was dissolved in 40 mL acetic acid solution (Sinopharm Chemical Reagent Beijing Co. Ltd.) by strong stirring, followed by the addition of 0.05 g multi-layer graphene ($10 nm thickness, Hefei Weijing Material Technology Co. Ltd.) and continuous stirring for 20 min. Then, 1 mL tetrabutyl titanate (TBT, Sinopharm Chemical Reagent Beijing Co. Ltd.) was added dropwise to the above dark solution in 5 min, and the mixture was sealed to sonicate at a power of 99 W for 20 min at 50 C. The obtained suspension was transferred to a 60 mL Teon-lined stainless-steel autoclave, and maintained at 150 C for 24 h. Aer being cooled to room temperature, the precipitate was collected by centrifuge, washed with ethanol and water several times and dried at 60 C in an oven. The dried sample was then calcined in the tube furnace at 400 C for 4 h owing with an argon atmosphere, and the temperature rose from room temperature with an increase rate of 3 min À1 . Aer grinding, the TiO 2 /MLG powder was obtained. The compared TiO 2 sample was prepared using the same method but without the use of multi-layer graphene.
Characterization: the crystallographic structure of the asprepared materials was studied by X-ray powder diffraction (XRD) using a Bruker D8 diffractometer with monochromatic Cu Ka radiation (l ¼ 1.5406Å), and the diffraction data were recorded in the 2q range of 10-80 . The morphological structures of the anode materials were investigated by a FEI Quanta 200 scanning electron microscopy (SEM) and JEOL 2010F transmission electron microscopy (TEM). The thermogravimetric analysis/differential scanning calorimetry (TGA/DSC) of the samples was carried out on a Diamond TG thermoanalyzer.
Electrochemical tests: the anode was fabricated with the active material, acetylene black, and binder (polyvinylidene uoride, PVDF) in a weight ratio of 8 : 1 : 1 by using NMP as the solvent and copper foil as the current collector ($2.5 mg cm À2 ), followed by drying in vacuum at 110 C for 24 h. The R2016 coin cell was assembled in an argon-lled glove box using metallic lithium as the cathode and Celgard 2500 membrane as the separator. The electrolyte was 1 M LiPF 6 dissolved in a mixture of ethylene carbonate (EC), dimethyl carbonate (DMC), diethyl carbonate (DEC) (v/v/v, 1/1/1). Cyclic voltammetry (CV) and galvanostatic charge/discharge cycling tests were carried out in a setting voltage range by using an electrochemical workstation (CHI660C) and a CT2001A LAND battery tester, respectively. Electrochemical impedance spectroscopy (EIS) was studied using a Modulab (Solartron Analytical) with the amplitude of 5 mV in the frequency range from 1 MHz to 10 mHz. All electrochemical tests were carried out at room temperature.

Results and discussion
The X-ray diffraction (XRD) pattern of the as-prepared composite is shown in Fig. 1. The diffraction pattern can be indexed to the three constituent phases of the composite, namely graphite (P6 3 /mmc, JPCD no. 65-6212), anatase TiO 2 (I4 1 /amd, JPCD no. 65-5714) and TiO 2 (B) (C2/m, JPCD no. 46-1238). The observed graphite peak is evidence of the incorporation of the multi-layer graphene (MLG) which was used as a reagent during the preparation. The strong (002) diffraction peak at 26.5 illustrates that the MLG structure was maintained throughout the hydrothermal and calcination processes employed in fabrication. 43,44 TiO 2 (B) is formed from the thermal dehydration of layered hydrogen titanate, 45,46 resulting from the low-rate of hydrolysis of TBT in acetic acid. The slow hydrolysis of the TBT precursor with the help of the PVP dispersant is benecial for the self-assembly of anatase and TiO 2 (B). Rietveld renement of the diffraction pattern using a two-phase analysis model, see Fig. S1, † indicates that the phase content of anatase TiO 2 and TiO 2 (B) are 70.7% and 29.3%, respectively.
In order to estimate the amount of MLG in the composite sample, thermal analysis/differential scanning calorimetry (TGA/DSC) was carried out in air with a heating speed of 5 C min À1 (Fig. S2 †). The slight weight loss before 120 C is ascribed to the evaporation of adsorbed water molecules. As the complete decomposition temperature of graphene has been generally considered to be around 700 C, 47-50 the weight loss at this temperature has been assumed to correspond to the content of MLG in the TiO 2 /MLG composite, which is estimated to be 5.8%. In addition, the wide exothermic peaks of TiO 2 /MLG reects the oxidization of the carbon skeleton of MLG, which can be affected by the formed C-Ti bond and the distribution of TiO 2 creating localized spots to facilitate the oxidization reaction. [51][52][53] Besides MLG, the phase transformation of TiO 2 from TiO 2 (B) to anatase to rutile in the range of 350-600 C causes uctuations in the exothermic peaks. 54,55 The dandelion-shaped TiO 2 /MLG with TiO 2 (B) brils and anatase TiO 2 pappi was characterized by scanning electron microscopy (SEM) and transmission electron microscopy  Fig. 2d clearly demonstrates the crystal domains of the three phases in a nanoregion, and the boundary structures between anatase TiO 2 and TiO 2 (B). Within the triple phase region indicated by an ellipse in Fig. 2d, it is found that the lattice fringes of the (003) plane of TiO 2 (B) and the (004) plane of anatase TiO 2 are adjacent with a 125 angular mismatch, and there is a 5 angular mismatch between the (100) plane of graphene and the (003) plane of TiO 2 (B) and 120 between the (100) plane of graphene and the (004) plane of anatase TiO 2 . As depicted in Fig. 2e, the interface mismatch rate, d, between two mismatched phases can be calculated using eqn (1) where d reects the interface matching intensity or the possibility of interface match. 4 The schematically presented parameters d 1 and d 2 signify the projected lengths of mismatched planes and eqn (1) may be employed when d 1 $ d 2 . d is calculated to be 0.497, 0.032 and 0.539 for the interfaces between the (003) plane of TiO 2 (B) and the (004) plane of anatase, the (003) plane of TiO 2 (B) and (100) plane of graphene, the (004) plane of anatase and (100) plane of graphene, respectively. More abundant interfacial structure is present between graphene and anatase in this triphase composite than between anatase and TiO 2 (B). By employing Fast Fourier Transform (FFT) and inverse FFT, the magnied lattices of the corresponding darker parts in the HRTEM image displayed in Fig. 2f are assigned to TiO 2 (B), which demonstrates that the crystals of this phase form the brils whilst the lighter pappus parts are composed of anatase TiO 2 and the complementary analysis is shown in Fig. S4. † In addition, it is clearly observed from the FFT images in Fig. 2f that the lattice plane of (À604) displays a degree of disorder. Cyclic Voltammetry (CV) of TiO 2 /MLG was performed in a voltage range of 1-3 V vs. Li/Li + , and the CV curves are shown in Fig. 3a and b. The rst CV cycle, beginning from the open circuit voltage, shows different electrochemical behavior to the subsequent cycles, consistent with conditioning of the anode material during the rst round of Li insertion/de-insertion. The second and fourth cycles are consistent in shape illustrating excellent reversibility of the reactions for the as-prepared material. 4,7 The cathodic peak located at 1.37 V vs. Li/Li + in the rst cycle is found to disappear in the following, which has been explained as the irreversible reactions of some impurities. 4 Compared with the CV peaks of TiO 2 (B), 7 the cathodic peak at around 1.4 V in the rst cycle results from the open channel saturation of TiO 2 (B) by the inserted Li + ions. In the anodic scan of the second cycle there are three distinct peaks labeled A, B1 and B2 in Fig. 3a. At higher scan rates, Fig. 3b, peaks B1 and B2 are less well dened and eventually merge into a single entity labeled B. Analysis of peaks A and B as the scan rate is varied from 0.2 mV s À1 to 1.2 mV s À1 indicates that the peak current of the former is a linear function of the square root of the scan rate, Fig. 3(c), whilst the height of the latter is directly proportional to the scan rate, Fig. 3d. The as-prepared TiO 2 /MLG includes a mixture of anatase and TiO 2 (B) presenting diffusionand surface-controlled electrochemical reactions at different potentials. 3,4,7 The position of peak A, 1.68 V vs. Li/Li + , and the variation in peak height with scan rate are consistent with lithium insertion into anatase TiO 2 . 5 Peak B can be assigned to a pseudocapacitive process on the surface of TiO 2 (B). 56 A higher current associated with anatase TiO 2 is in agreement with the composition of the composite.
The galvanostatic charge/discharge proles in the voltage range of 1 to 3 V vs. Li/Li + of TiO 2 /MLG and TiO 2 prepared using the same synthetic method but without MLG are shown in Fig. 4a. The discharge curves of TiO 2 /MLG and TiO 2 can be divided into three regions. 36,57 The rst region (Region 1) with a steep decrease in potential is ascribed to the homogeneous Li + insertion into bulk TiO 2 until the solid-solution limit of Li + ions   in TiO 2 , such behavior is indicative of a nano-sized titania material. 58 Region 2 is characteristic of the lithiation of anatase. It can be seen that the average voltage plateau of TiO 2 /MLG (1.75 V) is 20 mV higher than that of TiO 2 (1.73 V), from which it can be deduced that the boundary structures between TiO 2 and graphene have the potential to lower the electrode polarization resulting from the good electronic and ionic conductivity 44 in the biphase TiO 2 (Li-rich and Li-poor) co-existence plateau. 36 The contributed capacities of 126 and 106 mA h g À1 for TiO 2 / MLG and TiO 2 in the two regions result from the random insertion of Li + into over half the available interstitial octahedral sites of anatase. 4,57 Region 3, at low potentials, corresponds to the loss of pseudocapacitive charges from the interfaces in the system. The TiO 2 /MLG composite anode and the TiO 2 anode have very similar behavior in regions 1 and 2 of the discharge curve indicating that the degree of lithiation of the nanoparticles is independent of the amount of MLG. In region 3 the TiO 2 /MLG composite displays a higher specic capacity at all potentials. In the second and third cycles, region 3 of the TiO 2 / MLG composite can be divided into two slopes of different gradients whilst for the TiO 2 anode a single gradient is observed, as shown in Fig. S5. † The columbic efficiency of TiO 2 / MLG in the rst cycle is 80.4%, slightly higher than the 78.8% observed for the TiO 2 anode. Fig. 4b shows the discharge capacities of TiO 2 /MLG at current densities of 0.05, 0.1, 0.2, 0.5, 1, 2, 3 and 5 A g À1 to be 266, 243, 221, 200, 182, 161, 140 and 115 mA h g À1 . For the higher discharge rates of 5.5, 6, 7, 8, and 10 A g À1 the capacities of TiO 2 /MLG are 84, 69, 48, 43 and 35 mA h g À1 , as indicated in Fig. 4c. For comparison, the specic discharge capacities of TiO 2 displayed in Fig. 4d are 198, 183, 159, 128, 119, 113, 100 and 86 mA h g À1 for current densities of 0.05, 0.1, 0.2, 0.5, 0.8, 1, 1.4 and 2 A g À1 , respectively. It is found that the specic capacity of TiO 2 /MLG at 1 A g À1 retains 75% of the value at 0.1 A g À1 , while TiO 2 keeps 62%. The cyclic performances of TiO 2 /MLG in Fig. 4e was investigated to evaluate the electrode stability. Only a slight loss of capacity was observed aer 100 cycles at a current density of 0.1 A g À1 . The corresponding capacity retention of TiO 2 /MLG is 99.6% with high coulombic efficiency almost approaching 100%, even for high current rates of 5 and 10 A g À1 as illustrated in Fig. S6. † The coulombic efficiencies of the 1200 cycles of TiO 2 /MLG are extremely coincident when compared with that of the reference TiO 2 (Fig. S7 †), which conrms the high electrode stability of TiO 2 /MLG during cycling. With reference to the conclusions from Wu et al., 4 the high electrochemical stability of the electrode is attributed to the threedimensional dandelion-shaped microsphere structure which provides short diffusion distance for ion transport, high contact area between the electrolyte and electrode and the boundaries of TiO 2 /MLG which are capable of accommodating strain during cycling, leading to high Li + diffusion kinetics as well as stable electrochemical reactions.
Electrochemical impedance spectroscopy (EIS) was used to explore the variation of impedance of TiO 2 /MLG during electrochemical cycling. Fig. 5(a) and (b) show the Nyquist plots for the electrodes cycled 0 and 1000 times with corresponding calculated plots which are obtained from the equivalent circuit model in the inset, respectively. For the components in the equivalent circuit, the values, with errors, that were calculated to yield the best ts to the experimental data are listed in Table  S1 and S2. † In the equivalent circuit of both, R1 represents the internal resistance of the cell that arises from both the electrode and electrolyte. CPE2 (constant phase element) in Fig. 5a represents the pseudocapacitance that is generated on the complicated surface of internal triphase boundaries 4 plus electrodes. R2 represents the charge transfer and possible ion diffusion, and CPE1 is the capacitor in the bulk associated with Li + ion insertion. In Fig. 5b, two new components are introduced namely CPE3 and R3. CPE3 is dened as the Warburg resistance with the factor, n ¼ 0.5 (Table S2 †) and correspondingly, CPE1 becomes a pure capacitor with n ¼ 1. The Warburg resistance results from the solid-state ion diffusion in the electrode channels. The presence of R3 points to the development of a surface resistance during cycling, which can be attributed to the open interfacial structure in the electrode or SEI lm on the electrode surface. 4 According to Tables S1 and S2, † the resistances, R1 and R2 have decreased but the capacitance of CPE1 and CPE2 have increased aer multiple electrochemical cycles when compared with those of the fresh cell. The impedance data indicate that the structural rearrangement of the TiO 2 /MLG electrode during cycling promotes the boundary storage to be predominant over bulk storage for Li + ions. The interfacial structure provides more open channels for ion diffusion with cycling. Fig. 6 is a schematic representation of the TiO 2 /MLG composite. The as-prepared material has an abundance of triphase boundaries between anatase TiO 2 , TiO 2 (B) and graphene. Wang et al. 42 have demonstrated that charge storage at the anatase TiO 2 -TiO 2 (B) junction can enhance Li + storage in anode materials. The high specic capacities observed for the biphasic TiO 2 material prepared in the absence of MLG points to a synergistic interfacial effect improving charge storage. The specic capacitance of the dandelion structured TiO 2 is further enhanced when MLG is introduced into the composite. The interfaces within nanosized materials can offer more sites for Li + storage 36 and the boundaries between MLG and TiO 2 phases also provide sites for Li storage. The MLG itself with nearly 30 layers will only contribute negligible capacity in the voltage range of 1-3 V vs. Li/Li + . 59 There are abundant phase boundaries arising from the polycrystal in the TiO 2 /MLG dandelion structure, contributing to large extent of lattice mismatch, as well as extra sites for Li + ion and electron storage and some disordered planes probably provide more active sites for Li + ion storage and transfer. 4,11 The TiO 2 /MLG composite is able to store charge through both Li + insertion and a pseudocapacitive mechanism, as evidenced by the i-V curves obtained when the potential is cycled. We postulate that the improved rate performance of the TiO 2 /MLG composite relative to the TiO 2 material results from the fact that the edge-abundant interfaces of graphene can promote Li + ion diffusion and electron transport along the triphase boundaries, as schematically presented in Fig. 6.

Conclusions
Dandelion-shaped TiO 2 /MLG composed of TiO 2 (B) brils and anatase pappi was synthesized as a promising anode material for Li storage. Both the material characterization and cyclic voltammetry presenting diffusion-and surface-controlled electrochemical reaction at different potentials, evidenced the anatase/TiO 2 (B) heterophase in TiO 2 /MLG, and the open channel saturation of TiO 2 (B) by inserted Li + ions at around 1.4 V was used to explain the irreversible cathodic peak. A mismatch rate, d, between two adjacent phases with mingled boundaries, was introduced to describe the interplanar mismatch degree. The edge-abundant interfaces of graphene involved in the triphase boundaries were reported to enhance the electrochemical storage properties of TiO 2 /MLG and lower the electrode polarization by the improvement of Li + diffusion and electron transport. The discharge capacities of TiO 2 /MLG at current densities of 0.05, 0.1, 0.2, 0.5, 1, 2, 3 and 5 A g À1 are 266, 243, 221, 200, 182, 161, 140 and 115 mA h g À1 , and the capacity retention is 99.6% with high coulombic efficiency almost approaching 100% aer 100 cycles at the current density of 0.1 A g À1 . The resistances of TiO 2 /MLG decreased with cycling and more boundaries were opened to enhance ionic and electron conductivity.