Iron–polypyrrole electrocatalyst with remarkable activity and stability for ORR in both alkaline and acidic conditions: a comprehensive assessment of catalyst preparation sequence

A new facile template-free method is presented to synthesize Fe-treated N-doped carbon (Fe/N–C) catalysts for oxygen reduction reaction (ORR) by employing a synthesis protocol of pyrolysis–leaching– stabilization (PLS) sequence of polypyrrole in the presence of ferric source, which serves dual purposes of an oxidant for pyrrole polymerization and an iron source. Each step in the PLS sequence is assessed in detail in terms of the related structural properties of the resulting carbon catalysts, and their effects on ORR activities are elaborated to confirm the validity of the current synthesis protocol. It is found that the as-prepared carbon catalyst exhibits outstanding high catalytic activity in both alkaline and acidic conditions. The carbon catalyst prepared at a pyrolysis temperature of 900 C (FePPyC-900) shows remarkably high ORR activity with onset potential of 0.96 V (vs. RHE), which is similar to that of Pt/C, whereas the half-wave potential (E1/2) of FePPyC-900 is 0.877 V, more positive than that of Pt/C at the same catalyst loading amount under alkaline conditions. Furthermore, the FePPyC-900 catalyst also illustrates exceptionally high activity under acidic conditions with onset and half-wave potentials of 0.814 and 0.740 V, respectively, which are almost comparable to those (0.817 and 0.709 V) of the state-ofthe-art Pt/C catalyst, which is rarely observed for non-Pt-based carbon catalysts. In addition, the FePPyC-900 catalyst displays much better stability and methanol tolerance than the Pt/C and exhibits a four electron transfer pathway under both alkaline and acidic conditions. Such extraordinary high ORR activity and stability of the FePPyC-samples can be attributed to the implementation of extra stabilization step in addition to conventional sample preparation steps of pyrolysis and subsequent leaching in current PLS synthesis protocol as well as to the use of highly conducting PPy as a single precursor of carbon and nitrogen in the presence of Fe.


Introduction
With the increasing concern over environmental safety and depletion of fossil fuels, fuel cell (FC) is considered as a promising source of alternative green power because of its high energy density, high efficiency, and negligible emission of harmful gases. 1,2 The proton exchange membrane fuel cell (PEMFC) and alkaline polymer electrolyte fuel cell (APEFC) have attracted global research interest because of their low operation temperature, high efficiency and long life span. 3 Platinum (Pt) and Pt-based alloy materials are widely used as electrocatalysts for both hydrogen oxidation reaction and oxygen reduction reaction (ORR) in PEMFC, 4,5 although Pt is expensive and naturally less abundant. Furthermore, the sluggish ORR kinetics at the cathode necessitates large usage of noble Pt to accelerate the ORR at the cathode, which greatly increases the cost of fuel cells and thus makes widespread commercialization of the fuel cell technology unlikely. 6,7 Therefore, the development of precious metal-free catalyst with both high activity and stability to substitute the Pt-based catalysts has been regarded as a more probable alternative to signicantly reduce the cost and realize commercialization of fuel cells.
In the past few decades, a range of alternative non-noble metal catalysts (NNMCs), such as metal-free or transition metaltreated heteroatom-doped carbon, [8][9][10][11][12][13][14] transition metal oxide/ carbides/nitrides, [15][16][17] perovskite oxides, 18,19 transition metalcoordinated macrocyclic compounds, [20][21][22] and MOF-derived catalyst, have been investigated as alternatives to costly Pt catalyst. 23 In particular, transition metal-treated N-doped carbon catalysts (M/N-Cs) have attracted attention as electrocatalysts for the ORR due to high catalytic activity, durability and wide availability along with economical merits. To date, iron (Fe) and/or cobalt (Co)-treated composites with N or P doping have demonstrated good catalytic activities and durability towards ORR in an acidic medium. [24][25][26] There are many types of nitrogen precursors for N-doped carbon, including ammonia (NH 3 ), 27 polyacrylonitrile ((C 3 H 3 N) n ), 28 polyaniline ((C 6 H 5 NH) n ), 24 ethylenediamine (C 2 H 4 (NH 2 ) 2 ), 29 cyanamide (CH 2 N 2 ), 30 urea, and phthalocyanine. 20 In addition, polypyrrole ((C 4 H 5 N) n ) (PPy) is an excellent carbon source with N moiety since it is a conducting polymer and can also be employed as a matrix for incorporating metallic catalysts. 31 Furthermore, the aromaticity of the pyrrole ring is favourable to form graphitic carbon structures aer carbonization, which can improve ORR activity signicantly. Yuasa et al. 32 in 2005 rst reported on Co-PPy as an electrochemical cathode catalyst, which kindled worldwide focus on transition metal and N-doped carbon research. 33 There have also been several studies reporting Fetreated N-doped carbon derived from Fe-incorporated PPy for ORR applications. 15,[34][35][36][37][38][39] However, almost all these papers have shown the ORR activity only under alkaline conditions, except for one study by M. Sevilla et al., which presented the ORR activity of Fe-PPy under both alkaline and acidic conditions. 39 The ORR activity of their Fe-PPy catalyst under acidic conditions was found to be quite lower than that of the Pt-based catalyst. In general, the activity of transition metal-treated N-doped carbon is reported to be still much lower than that of the Pt-based catalyst under acidic conditions. Furthermore, the synthesis process is very important for fabricating good electrocatalysts. Recently, the synthesis sequence of 1 st heat treatment-acid etching-2 nd heat treatment has been used for the synthesis of transitional metal-incorporated N-doped carbon. 30,[40][41][42][43] Typically, this process includes rst heating the mixture of N, C and transitional metal sources, and then etching the unstable species with an acid, and aerward the second heating process is carried out. M. Ferrandon et al. reported that acid etching can remove the iron species adjacent to the active sites to expose them for the ORR reaction, and the second heat treatment increases the stability of the nal Fe/N-C catalyst material. 43 However, each of the synthesis steps has not been fully investigated for better understanding the effectiveness of the synthesis procedure. On the other hand, most studies have shown the changes in the surface area, electronic conductivity and active site content in different synthesis procedures, mostly without the inclusion of the nal stabilization step, which can greatly inuence the electrocatalytic activity of Fe/N-C catalysts. 44 In this study, Fe-treated N-doped carbon (Fe/N-C) electrocatalysts were prepared from a simple template-free synthesis protocol of a pyrolysis-leaching-stabilization (PLS) sequence for polypyrrole (PPy) and ferric chloride (FeCl 3 ) as C, N, and Fe precursors. Each step in the PLS sequence was assessed in detail in terms of the related structural properties of the resulting carbon catalysts, and their effects on the ORR activities were elaborated to conrm the validity of the current synthesis protocol. PPy was chosen as a single precursor for C and N since it is an excellent conducting polymer and thus can yield an extended graphitic carbon framework with high electrical conductivity upon carbonization. We nd that FePPyC-900 prepared by the PLS sequence of the Fe-PPy precursor at 900 C exhibits excellent ORR performance with near 4-electron transfer and low H 2 O 2 yield, which is comparable to that of commercial E-TEK 20 wt% Pt/C catalyst under both alkaline and acid conditions along with much better long term stability and high methanol tolerance. In particular, the exceptionally high ORR activity comparable to that of the state-of-the-art Pt/C was observed even in an acidic medium, which has been rarely reported before. The results clearly indicate that the PLS sequence is very effective for catalyst preparation and the as-prepared FePPyC catalyst represents a viable alternative to precious Pt catalyst in fuel cells.

Material preparation
FePPyC catalysts were prepared by a new synthesis protocol consisting of a series of pyrolysis-leaching-stabilization (PLS) sequence for Fe-PPy precursors. First, 3.00 ml of monomer pyrrole was dissolved in 60.0 ml of 0.5 M HCl solution and allowed to stir for 15 min at room temperature, and 10 ml FeCl 3 (0.74 mol l À1 ) solution was then added slowly into the abovementioned mixture as an oxidant for pyrrole polymerization and further stirred for 12 h. The mixture containing the polymer and transition metal was ltered by a vacuum lter. The product was dried at 80 C for 12 h, and the dried precursor was heated to 800, 900, and 1000 C for 1 h at a heating rate of 10 C min À1 in an argon atmosphere for carbonization and graphitization, and the sample was then cooled naturally to room temperature at the same atmosphere. To remove redundant phases, mainly unstable metallic iron and iron compounds, the pyrolyzed product was leached in 0.5 M H 2 SO 4 at 80 C for 8 h. Aer thorough washing several times with deionized water and absolute ethanol, the product was dried at 80 C for 12 h. The leached product was pyrolyzed again at the same temperature for 1 h for stabilization (structural integration), as mentioned above, to obtain the FePPyC-T (T ¼ 800, 900, and 1000 as pyrolysis temperature) samples. For comparison, a Fe-free N-doped carbon catalyst was also synthesized from pure pyrrole monomer using hydrogen peroxide as an oxidant for polymerization (denoted as PPyC) instead of FeCl 3 . The same PLS method of pyrolysis, acid leaching and further stabilization was applied to obtain Fe-free PPyC-T.

Material characterization
The X-ray diffraction (XRD) patterns were measured using a Rigaku Smartlab diffractometer with CuKa radiation using a Ni b-lter at a scan rate of 4 /min. The X-ray source was obtained at 40 kV and 30 mA. Raman spectroscopy measurements (Renishaw) were recorded using an Ar ion laser (l ¼ 514.5 nm). The scanning electron microscopy (SEM) images were obtained using a Hitachi S-4700 microscope operated at an acceleration voltage of 10 kV. The transmission electron microscope (TEM) was measured on EM 912 Omega at 120 kV. The nitrogen adsorption-desorption isotherms were operated at À196 C using a Micromeritics ASAP 2020 system. The specic surface areas of the samples were determined from nitrogen adsorption data in the relative pressure range from 0.05 to 0.2 using the Brunauer-Emmett-Teller (BET) equation. The total pore volume was obtained from the amount of gas adsorbed at the relative pressure of 0.99. Pore-size distribution was calculated using Micromeritics soware based on the Barrett-Joyner-Halenda (BJH) Method. X-ray photoelectron spectroscopy (XPS) analyses were operated with an AXIS-NOVA (Kratos) X-ray photoelectron spectrometer using a monochromated Al Ka X-ray source (hn ¼ 1486.6 eV) operated at 150 W under a base pressure of 2.6 Â 10 À9 Torr. The XPS spectra were deconvoluted using the curve tting program, XPSpeak 4.1. This soware was used for all XPS data processing. A special cell with a four-probe conguration was designed and constructed by our group for measurements of the electrical conductivity of materials under controlled pressure. The electrical conductivity is rst measured using four probes under a xed pressure using a Keithley model 6220 and 2182A as the DC current source and voltmeter and then converted to the conductivity as described earlier. 45 The sample volume was calculated from measured sample thickness and cross section area of the pressure chamber.

Electrochemical characterization
Electrochemical experiments were carried out at room temperature in a three-electrode cell using a rotating disk electrode (RDE) or rotating ring-disk electrode (RRDE) connected to an electrochemical analyzer (Biologic VMP3). The RRDE measurements were conducted using an electrode with a tted glassy carbon disk and a platinum ring in an oxygen-saturated 0.1 M KOH or 0.5 M H 2 SO 4 . The prepared catalysts or commercial E-TEK 20 wt% Pt/C catalyst (5.0 mg) were dispersed in 1.0 ml of a mixture solution of water and 5 wt% Naon (water : Naon ¼ 9 : 1). The as-prepared 10 mL catalyst ink was then dropped onto the glassy carbon disk (4 mm) of the RRDE or RDE (0.4 mg cm À2 ) and dried at 50 C to prepare the working electrode. An Ag/AgCl with saturated KCl and a Pt wire were used as a reference and a counter electrode, respectively. The potentials of the Ag/AgCl reference electrode were calibrated to the reversible hydrogen electrode (RHE). The potential presented in this study refers to the RHE potential. The potential difference between Ag/AgCl and RHE electrode was calculated using eqn (1).
where E Ag/AgCl is the experimentally measured potential vs. Ag/ AgCl reference. The potential differences between Ag/AgCl and RHE in alkaline and acidic electrolyte are found to be 0.96 and 0.22 V, respectively. 46 The cyclic voltammetry (CV) experiments were conducted for the ORR at the scan rate of 50 mV s À1 in the potential range from +1. 26 The electron transfer number (n) was determined from the RRDE measurements using the following eqn (3).
where I D is the disk current density, I R is the ring current density, and N is the current collection efficiency of the employed Pt ring (N ¼ 0.424).  Fig. 1 illustrates the PLS synthesis process of the FePPyC-T catalyst. In brief, pyrrole monomer was dispersed in an HCl solution, to which an iron(III) chloride solution was added for the polymerization of pyrrole. The mixture was then ltered to obtain the solid phase, followed by drying in an oven until the sample weight did not change, usually for $12 h at 80 C. The Step-2: acid leaching for removing unstable Fe species.

Results and discussion
Step-3: second pyrolysis for structural integration and stability.
rst heat treatment was carried out at 800, 900, and 1000 C, respectively, under the argon atmosphere for 1 h for carbonization and graphitization. The heat-treated product was than leached in 0.5 M H 2 SO 4 at 80 C for 8 h to remove any unstable phases. The second heat treatment was carried out to make a loose carbon matrix, formed during acid leaching, further graphitized and stabilized under the same condition, as mentioned above in the rst heat treatment step of the synthesis, to obtain the nal FePPyC-T. For comparison, a Fefree PPyC-T was also prepared using the identical PLS process with hydrogen peroxide as an oxidant for polymerization instead of FeCl 3 , as mentioned in the Experimental section.
The ORR activity of the Fe-treated N-doped carbon catalysts is inuenced by pyrolysis temperature. 26 Pyrolysis at relatively a low temperature from 500 to 700 C may lead to Fe-N 4 conguration as ORR active sites, whereas heat treatment at higher temperatures can increase the electrical conductivity of the carbon material and form Fe-N 4Àx centers with a lower N content, which are reported to form new active sites. 43 Thus, there may be a trade-off between the N content and electrical conductivity, which is decided mainly by the reaction temperature. 11,26 In general, pyrolysis at temperatures higher than 700 C is considered to be more desirable for better ORR performance despite some loss of the N content in the carbon framework. To nd an optimal pyrolysis temperature, the Fe-PPy mixture precursor was pyrolyzed at various temperatures, ranging from 800 to 1000 C in this study.
First, the effect of carbonization on the morphology of the prepared catalyst was evaluated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Fig. 2a and e show the SEM and TEM images of the Fefree PPyC-900 carbon material. It can be seen that PPyC-900 shows a dense bulky structure, and no porous structure is observed. Fig. 2b-d are SEM images of FePPyC-800, FePPyC-900, and FePPyC-1000, respectively, which show the formation of aggregated small carbon particles interconnected together, which are likely to form a porous structure between the carbon particles. Fig. 2f-h show TEM images of FePPyC-800, FePPyC-900, and FePPyC-1000, respectively, which also show the formation of aggregated small carbon particles interconnected together. We surmise that the formation of this type of interconnected structure can lead to interconnected open pores for efficient mass transfer during ORR and eventually help increase the catalytic activity of the catalyst. 17 In this study, FePPyC-T catalysts were prepared by the PLS synthesis sequence. The effect of each step in the PLS sequence on structural properties of the resulting carbon catalysts is elaborated to conrm the validity of the current synthesis protocol. Fig. S1 of (ESI) † shows the TEM and HR-TEM images of FePPyC-900bf obtained before acid leaching. A particle with a size of around 35 nm (Fig. S1a of ESI †) is clearly seen. A high resolution (HR)-TEM image of the selected region of the particle in Fig. S1b of ESI † presents a lattice fringe of d ¼ 2.05Å, which corresponds to plane spacing of Fe(110) plane. In addition, Fig. S2 of ESI † illustrates a typical TEM image and elemental mapping of FePPyC-900bf, which indicate the uniform distribution of Fe nanoparticles (NPs) and N in carbon. Furthermore, TEM image and element mapping images for FePPyC-900af obtained aer acid leaching are shown in Fig. S3 of ESI. † Aer acid leaching, all the large Fe particles are leached out from FePPy-900af, but Fe is still found to be well dispersed in the N-doped FePPy-900af carbon matrix.
XRD patterns of all the samples prepared at difference pyrolysis temperatures reveal a broad peak at around 2q ¼ 25 indexed to the (002) plane and a small peak at 44 corresponding to (100) plane of graphitic carbon, which are typical of a turbostratic carbon structure, as shown in Fig. 3a. 49 In particular, the intensity of the (002) peak is becoming stronger and narrower with increasing temperature. This clearly indicates that on increasing the carbonization temperature, the graphitic nature of the catalysts is also increasing. 44,45 A comparison of the XRD patterns of PPyC-900 and FePPyC-900 suggests that FePPyC-900 possesses more graphitic structures, which can be ascribed to the catalytic property of Fe. The XRD pattern of FePPyC-900bf shows the existence of iron phase ( Fig. S4a of ESI †), which is consistent with the TEM images seen in Fig. S1 and S2 of ESI. † However, no XRD signals for iron species are found in the sample aer acid leaching (FePPyC-900af) and the 2nd pyrolysis (FePPyC-900), which indicates that the acid leaching process removes almost all the iron metal or  oxide species from the sample. The remaining iron species are dispersed in the catalyst mainly as mononuclear Fe species with co-existing Fe 2+ and Fe 3+ , which can be further conrmed by XPS. 50 Raman spectra of all the samples are shown in Fig. 3b. All the samples displayed two broad bands at 1340 and 1575 cm À1 , which can be assigned to the D band and G band, respectively. D band is related to the breaking of symmetry caused by structural disorders and defects, whereas the G band represents the inplane tangential stretching vibration mode (E 2g ) of the graphite sheet. 51 The positions of both peaks are similar for all samples, showing that the structures of all the carbon samples are similar. The ratio of the D and G band intensities (I D /I G ) oen indicates the disordered nature of the prepared carbon frameworks and was observed to be 1.12, 1.07, 1.01, and 1.00 for FePPyC-800, PPyC-900, FePPyC-900, and FePPyC-1000, respectively. The decrease in the I D /I G ratios suggests that the carbon structure becomes more ordered and graphitic upon increasing the pyrolysis temperature, which is in agreement with the XRD results. In addition, similar to our XRD results, from a comparison of the I D /I G values between FePPyC-900 and PPyC-900, it can be noted that the treatment of Fe increases structural order and crystallinity in the carbon framework. The increase in crystallinity or graphitic nature can denitely help in improving the electrical conductivity of the samples. As shown in Fig. S4b of ESI, † for the different synthesis steps, the I D /I G ratios of FePPyC-900bf, FePPyC-900af, and FePPyC-900 are found to be 0.88, 1.02 and 1.01, respectively. Higher I D /I G ratio of FePPyC-900af and FePPyC-900 than that of FePPyC-900bf suggests that disorder and defective sites increase in the FePPyC-900af and FePPyC-900 framework, from which Fe species were leached out. 52 Electrical conductivity is an essential property required in electroactive materials for efficient ORR. Hence, the effect of Fe and carbonization temperature on the conductivity of the prepared catalysts was investigated using a cell with a fourprobe conguration (see ESI † for details). 45 Fig. 3c shows an assessment of each step of the PLS sequence in terms of the electrical conductivity. As the pressure increases, the conductivity increases for all the samples. FePPyC-900af was found to show higher conductivity than FePPyC-900bf due to acid leaching of the unstable or nonconductive iron oxide species (Fig. 3c). Aer the second pyrolysis treatment, FePPyC-900 reveals higher conductivity than FePPyC-900af. Fig. 3d illustrates that the conductivity of FePPyC-T samples also increases with increasing pyrolysis temperature. This can be understood by the fact that the increasing pyrolysis temperature certainly improves the graphitization. 8,45 In addition, FePPyC-900 exhibits higher conductivity than Fe-free PPyC-900, suggesting that iron treatment plays an important role of increasing the graphiticity of the carbon framework, as proven by XRD and Raman spectra in Fig. 3, 26,40 eventually improving the overall conductivity. 26,41,44,47 The surface properties of the prepared samples were determined by nitrogen isotherms, as shown in Fig. S5a of ESI. † N 2 isotherms for PPyC-900 exhibit type I isotherms typical of microporous materials, whereas the FePPyC-T samples show type IV isotherms characteristics for microporous and mesoporous materials. 53 The Brunauer-Emmet-Teller (BET) surface areas of PPyC-900, FePPyC-800, FePPyC-900bf, FePPyC-900af, FePPyC-900, and FePPyC-1000 were determined to be 565.8, 355.6, 425.6, 504.8, 592.2, and 726.1 m 2 g À1 , respectively. Table  S1 of ESI † summarizes the BET surface area, pore volume, and pore diameter of all the prepared samples. FePPyC-900af (504.8 m 2 g À1 ) shows a higher surface area than FePPyC-900bf (425.6 m 2 g À1 ), and the surface area increases further aer the second pyrolysis process (592.2 m 2 g À1 ). As observed in Table S1 of ESI, † a similar trend was observed for the total pore volume, suggesting that removing the iron species by acid leaching increases the total surface area and pore volume. In addition, the surface area was found to increase for the Fe-treated samples with increasing temperature. Interestingly, Fe-free PPyC-900 sample reveals a high micropore volume percentage near 95% of the total pore volume, whereas FePPyC-800, FeP-PyC-900, and FePPyC-1000 present decreased micropore volume percentage of 68.4%, 62.2% and 75.8%, respectively, as shown in Table S1, † which indicate an increased mesoporous volume in the FePPyC-T samples. The pore size distributions of these samples are shown in Fig. S5b, † and it can be seen that the pore sizes of the FePPyC-T samples are larger than that of the Fe-free PPyC-900. The average pore size of PPyC-900, FePPyC-800, FePPyC-900, and FePPyC-1000 is in the range of 3.0-6.6 nm. Such increased mesopore volume and average pore size in the FePPyC-T samples can be attributed to Fe removal from the carbon framework during acid washing, which results in large pores in the carbon framework. These mesopore structures are expected to be helpful for improving the ORR activity.
The elemental compositions of all the samples were monitored by X-ray photoelectron spectroscopy (XPS). Fig. 4a shows XPS survey scans of PPyC-900 and FePPyC-T samples, which indicate the presence of carbon C 1s, oxygen O 1s, nitrogen N 1s, and iron Fe 2p. In particular, heteroatoms, such as N, S, P, and B, doped into the carbon framework are believed to be responsible for the improved activity towards various electrochemical reactions. 9,11,45,54,55 Among them, electronegative N is most extensively investigated as a dopant and found to inuence the physicochemical properties of carbon. Moreover, it is also commonly accepted that the presence of Fe can convert the carbon framework into carbon with a more graphitized structure. 24,44,47 In Table 1, FePPyC-900af shows a lower iron content than FePPyC-900bf, indicating that acid washing removes the unstable iron metal. 43 Furthermore, the carbon content increases from 89.4% to 92.8% with increasing pyrolysis temperature, whereas the nitrogen content decreases from 6.1% to 2.6%. The iron content seems to be decreasing with increasing reaction temperature, which may be due to the shielding effect of the carbon layer, towards the XPS incident beam, formed on the Fe particle at higher temperatures.
As can be seen in Fig. 4b and S6 of ESI, † the major carbon (C 1 s) species detected by XPS are sp 2 C at 284.6 eV and sp 3 C at 285.3 eV, and a minor signal at 286.5 eV ascribing to different bonding of carbon with nitrogen or oxygen was also observed in all the samples. 56,57 The relative percentage of the different carbon species for C 1 s in all the samples are summarized in Table S2 of ESI. † As expected, sp 2 C increases with the presence of Fe and increasing carbonization temperature in the prepared samples. This can be understood by the fact that the increasing pyrolysis temperature and presence of Fe certainly improves the graphitization along with increase in sp 2 hybridization and thus increases the electrical conductivity, as proven in Fig. 3d. 44,47 Fig. 4c, S7 and S8 of ESI † show that the N1s is deconvoluted into four different peaks such as pyridinic nitrogen N1 ($398.6 eV), pyrrolic nitrogen N2 ($400 eV), graphitic nitrogen N3 ($401.1 eV), and oxidized nitrogen N4 ($402.3 eV). 48,58,59 The relative amount of N bonding congurations signicantly changes with increasing pyrolysis temperature. As shown in Fig. S9a of ESI, † FePPyC-900af and FePPyC-900 show similar relative intensity of pyridinic-N, but reveal higher intensity than FePPyC-900bf, whereas FePPyC-900af shows higher pyrrolic-N intensity than FePPyC-900 and FePPyC-900bf. Moreover, FeP-PyC-900bf and FePPyC-900 show quite similar graphitic-N intensity, but much higher intensity than FePPyC-900af. This can be attributed to the acid washing aer rst pyrolysis, which exposes edge-sited N species such as pyridinic-N and pyrrolic-N. During the second pyrolysis process, some of the pyrrolic-N converts to graphitic-N without much change in pyridinic-N. The increase in the graphitic-N amount aer the second pyrolysis may contribute to enhanced electrical conductivity of FePPyC-900 compared to FePPyC-900af, as evidenced in Fig. 3c. In particular, the pyridinic-N and pyrrolic-N decrease with increasing temperature, as shown in Fig. S9b of ESI, † implying that these N species are less stable at higher temperatures. On the contrary, amount of graphitic-N increases signicantly with increasing pyrolysis temperature. The graphitic-N species is found to be relatively more stable and becomes predominant at temperatures higher than 900 C. In general, pyridinic-N and graphitic-N are reported to be active for the ORR. 55 Oxidized-N, known to be catalytically inactive for the ORR, also increases steadily from 800 C to 1000 C. Interestingly, upon a comparison of PPyC-900 and FePPyC-900, it can be seen that the pyrrolic-N species decrease, whereas pyridinic-N increases in FePPyC-900, and graphitic-N is not changed much, implying that Fe may help generate more edge pyridinic N-species, which can eventually help to enhance the ORR performance of FeP-PyC-900. 47,60 Fig . 4d shows the Fe 2p spectrum of FePPyC-900 catalyst, and the signal intensity is very weak. According to previous reports, 25,26,61 the Fe 2p peak is deconvoluted into ve peaks at 710.7, 715.0, 718.6, 724.3, and 726.4 eV. The photoelectron peaks at 710.7 and 715.0 eV correspond to binding energy of 2p 3/2 orbitals of Fe(II) and Fe(III) ion, respectively. The peaks at 724.3 and 726.4 eV can be assigned to 2p 1/2 binding energy of Fe(II) and Fe(III), respectively. The peak at 718.6 eV corresponds to a satellite peak. This indicates that both Fe(II) and Fe(III) coexist in the catalyst. It can be seen that the total area of the deconvoluted peaks corresponding to Fe 3+ is higher than that of Fe 2+ , indicating a higher atomic percentage of Fe(III), which may be due to the use of Fe(III) chloride as an iron precursor.
The electrocatalytic ORR activity is determined for the samples prepared in different synthesis steps of the PLS sequence. Herein, each step of the PLS sequence was assessed in terms of the ORR activity. For FePPyC-900af (aer acid leaching but before second pyrolysis), the onset potential and limiting current density are improved from those of FePPyC-900bf (aer the rst pyrolysis, but before acid leaching) as shown in Fig. S10a and b of ESI. † Best of all, FePPyC-900 shows the most positive onset potential along with a much higher current density under both alkaline and acidic conditions aer second pyrolysis, indicating the importance of the second pyrolysis aer acid leaching. 62 The ORR activity of the catalyst was signicantly enhanced aer acid leaching and additional pyrolysis, which can help to make the loose carbon matrix, formed during acid leaching, stabilized and further graphitized. N species doped into the carbon framework can also contribute to the enhancement of the ORR activity. According to the report by Lai et al., 63 both pyridinic-N and graphitic-N species, in particular, pyridinic-N plays a more important role as an active center for the ORR. Fig. 5 shows the interdependence of the ORR activity (onset potential) on the specic surface area, electrical conductivity, and amount of both pyridinic-and graphitic-N species of FePPyC-900bf, FePPyC-900af, and FeP-PyC-900 samples. Interestingly, each step of a series of pyrolysis-leaching-stabilization (PLS) sequences brings out the different structural properties of the resulting carbon samples, and their effects on the ORR activity are illustrated in Fig. 5. FePPyC-900 has much higher pyridinic-and graphitic-N species than FePPyC-900bf and FePPyC-900af. Moreover, FePPyC-900 shows much higher BET surface area and electrical conductivity than FePPyC-900bf and FePPyC-900af. Therefore, the synergistic contribution of all these properties improved the ORR performance of FePPyC-900. Electrocatalytic ORR activity is measured using cyclic voltammetry (CV) and rotating ring disk electrode (RRDE) techniques. The CV curve of FePPyC-900 catalyst in the N 2 -saturated 0.1 M KOH solution displays a featureless curve. When oxygen gas is purged in the solution, the CV curve exhibits a noticeable ORR peak at 0.85 V, as shown in Fig. S11a of ESI. † In Fig. S11b of ESI, † the CV curve of FePPyC-900 in N 2 -saturated 0.5 M H 2 SO 4 shows a pair of symmetric peaks at around 0.54 V and 0.66 V, which may be due to the redox reaction of quinone/hydroquinone or Fe(II)/Fe(III). 64,65 With an O 2 -saturated acidic solution, a CV curve with different peak shape, marked by a strong reduction peak at 0.62 V occurs. These results suggest that FePPyC-900 shows signicantly high ORR activity in both acid and alkaline electrolytes.
The CV curves of the PPyC-900 and FePPyC-T samples are presented in Fig. S11c and d of ESI. † It can be seen that the FePPyC-T samples show nearly rectangular CV curves, which indicates less electrode polarization in FePPyC-T than in Fe-free PPyC-900 under both alkaline and acidic conditions. This result clearly indicates that Fe plays a crucial role in enhancement of the electrochemical activity in the FePPyC-T samples by increasing the electrical conductivity (see Fig. 3d). Moreover, from the areas in the CV curves, FePPyC-T samples were found to show a higher electrochemical surface area than Fe-free PPyC-900, suggesting that the FePPyC-T samples prepared in the presence of Fe have much more active sites than the PPyC-900 ( Fig. S11c and d of ESI †). In particular, the FePPyC-900 (0.847 V vs. RHE) has a more positively-shied ORR peak potential than FePPyC-800 (0.623 V) and FePPy-1000 (0.801 V) under alkaline conditions, indicating the highest ORR activity in FePPyC-900 among the FePPyC-T samples prepared at different carbonization temperatures. Interestingly, the ORR peak potential of 0.847 V for FePPyC-900 is one of the most positively shied values reported so far to the best of our knowledge. Table S3 of ESI † compares the ORR peak potentials for different electrocatalysts prepared in this work under alkaline conditions.
The ORR activity of FePPyC-900 in both alkaline and acidic electrolytes was further conrmed by the CV curves at a slow scan rate of 10 mV s À1 , as shown in Fig. S12 of ESI. † The voltammogram of FePPyC-900 in N 2 -saturated 0.1 M KOH and 0.5 M H 2 SO 4 shows quasi-rectangular patterns without obvious redox peaks, whereas well-dened ORR peaks are seen at 0.87 V and 0.69 V (vs. RHE) for CV in 0.1 M KOH and 0.5 M H 2 SO 4 electrolyte, respectively, when O 2 was introduced, suggesting efficient electrocatalytic activity of FePPyC-900 for ORR in both alkaline and acidic media. Fig. 6 shows the ORR activities of the PPyC-900 and FePPyC-T samples prepared at different pyrolysis temperatures in alkaline and acidic conditions. The ORR activity performance data of all samples are summarized in Table 2. The electrochemical measurements of all the samples show that FePPyC-900 sample has the best ORR activity under both alkaline and acidic conditions. FePPyC-900 shows an onset potential of $0.960 V vs. RHE, almost identical to that of 20 wt% Pt/C, and a half wave potential (E 1/2 ) of 0.877 V vs. RHE, which is more positively shied than 0.844 V of the Pt/C under alkaline conditions. Under acidic conditions, it can be seen that FePPyC-900 shows an onset potential of 0.814 V, only 3 mV less positive compared with that of 20 wt% Pt/C (0.817 V), and a half wave potential of 0.740 V, which is more positive than 0.709 V of 20 wt% Pt/C. FePPyC-900 reveals current density of 6.40 mA cm À2 , which is slightly higher than 6.33 mA cm À2 for the 20 wt% Pt/C in KOH solution. In H 2 SO 4 solution, FePPyC-900 shows a current density of 5.70 mA cm À2 , which is higher than that of Pt/C (5.40 mA cm À2 ). This represents extraordinary activity, which is among the best ever reported for metal-treated doped carbon catalysts, and is comparable to the state-of-the-art commercial  Pt/C catalyst, even in an acidic medium. In general, the activity of transition metal-treated N-doped carbon is reported to be lower than or comparable to that of Pt/C catalyst under alkaline conditions, but still much lower than that of the Pt-based catalyst under acidic conditions. 41,66,67 Therefore, such remarkable ORR activity of the FePPyC-900 sample, particularly under acidic conditions, has not been reported before to the best of our knowledge. Fig. 7 illustrates the variation of the N content, specic surface area and electrical conductivity along with their effects on the ORR activity (onset potential) in the resulting carbon samples as a function of the carbonization temperature in the presence and absence of a Fe precursor. There exists an interesting trade-off between the N content, surface area, and electrical conductivity. As the carbonization temperature increases, the N content decreases, which is unfavourable for the ORR, but at the same time, the surface area and conductivity increases, which are benecial for the ORR. This trade-off should be optimized for the best performance. FePPy-900 possesses high electrical conductivity and an appropriate N content as well as a high surface area with a mesopore structure, and thus outperforms the other samples.
Interestingly, despite the higher surface area and electrical conductivity, FePPyC-1000 shows a slightly lower ORR activity than FePPyC-900. This is probably because FePPyC-1000 has a lower N content, which clearly indicates that N is a part of the catalytically active center. Interestingly, FePPyC-800 shows poor ORR activity despite the higher N content most probably because of the low electrical conductivity and surface area, strongly indicating that carbonization temperature should be higher than 800 C for the efficient development of graphiticity as well as surface area in the resulting carbon. Therefore, the carbonization temperature for the optimal ORR performance must be near 900 C in the current system. Individual N species may also be an important factor affecting the enhanced ORR activity. As shown in Fig. 4c and S9b of ESI, † FePPyC-900 exhibits a relatively higher percentage of pyridinic-and graphitic-N compared with FePPyC-800 and FePPyC-1000. The high content of pyridinic-and graphitic-N can also contribute to the improved ORR activity of FePPyC-900 catalyst.
The LSV curves of the FePPyC-900 at different rotation rates with a scan rate of 10 mV s À1 are shown in Fig. S13a and c of ESI † for O 2 -saturated 0.1 M KOH and 0.5 M H 2 SO 4 conditions, respectively. The ORR behaviour of FePPyC-900 at low overpotential (above 0.9 V for alkaline and 0.75 V for acidic conditions) is independent of the rotation rate, suggesting that this potential range corresponds to an electrochemical kinetics process. 68 As observed in Fig. S13b and d of ESI, † the Kotechky-Levich plots of FePPyC-900 at different potential are linear and nearly parallel, and the insets of Fig. S13b and d † show the calculated electron transfer number varying (n) from 3.5 to 4.0, which indicates a four electron ORR pathway under both alkaline and acidic conditions. Furthermore, electron transfer number and hydroxide yield of FePPyC-900 catalyst were also measured using the RRDE measurement at 10 mV s À1 with a rotation speed of 1600 rpm. The H 2 O 2 yield and the electron transfer number n were calculated from eqn (2) and (3) based on the RRDE data, as described in the Experimental section. Fig. S14a and c of ESI † show the ring and disk current density curves of the FePPyC-900 sample in 0.1 M KOH and 0.5 M H 2 SO 4 , respectively. The onset potentials of the ring current curves are lower than the counterparts of disk current curves under both alkaline and acidic conditions, which is similar to the behaviour of Pt/C catalysts in previous reports. 69,70 The peroxide yield for FePPyC-900 under alkaline conditions increases from 1.1% to 7.2% over the potential range from 0.76 to 0.0 V, and the average n is around 3.89, as shown in Fig. S14b of ESI. † For an acidic electrolyte, the peroxide yield decreases gradually from 1.4% to 0.6% from 0.67 to 0.02 V vs. RHE (Fig. S14d of ESI †), and the average n is $3.96, indicating Table 2 Onset potentials (E onset ), half-wave potentials (E 1/2 ), and limiting current densities (LCD) at 0.16 V in an alkaline medium and at 0.02 V in an acidic medium for different catalysts at 1600 rpm

Sample
Alkaline Acidic  a favourable 4 electron reduction process. The electron transfer number calculated from RRDE method is in good agreement with that based on the Koutecky-Levich plots calculation, indicating the four electron pathway of the ORR process for the FePPyC-900 catalyst in both alkaline and acidic media. FePPyC-900 in an acidic electrolyte exhibits lower ORR activity (0.814 V onset potential) than that (0.960 V onset potential) in an alkaline electrolyte. Furthermore, the onset potential of hydrogen peroxide oxidation, which is determined by the onset potential of ring current curve, is much more negative than that of ORR under alkaline conditions compared to observation under acidic conditions, as seen in Fig. S14a and c of ESI, † suggesting a somewhat different ORR mechanism in alkaline and acidic media. This also indicates that the formation of hydrogen peroxide is more favourable at a more negative potential under alkaline conditions as shown in high yield of hydrogen peroxide in alkaline electrolyte compared to that in an acidic electrolyte, as observed in Fig. S14 of ESI. † The gap of the electrochemical performance between alkaline and acidic media may be explained by the inner-sphere and outer-sphere electron transfer mechanism between the oxygen molecule and active site on the electrode surface. 71 It is acknowledged that N doping into the carbon framework generates charge delocalization and a slightly positive charge at the adjacent carbon atoms, and these charged carbon become active sites for the adsorption of oxygen molecules during the ORR. 72 Typically, the oxygen molecule is rst adsorbed at the active site (*) in an acidic electrolyte, and then the adsorbed O 2 receives an electron from the electrode and a proton to form *-(OOH) ads . This process is called the inner-sphere electron transfer (ISET). Other two protons interact with two oxygen atoms to break the O-OH bond to generate water and -OH species, and the additional proton then reacts with the remaining -OH ads to form water, as shown in eqn (4)-(6).
* + O 2 + H + + e À / *-(OOH) ads (4) *-(OOH) ads + 2H + + 2e À / *-(OH) ads + H 2 O *-(OH) ads + H + + e À / * + H 2 O Furthermore, hydrogen peroxide can be formed when a proton react with *-(OOH) ads in eqn (4) to generate H 2 O 2 , which can also re-adsorb to the active site to receive 2e À and 2H + to generate water. 73 In addition, protonation at the nitrogen atom (as an Lewis base site) in N-doped carbon can have a strong inuence on the lone-pair electrons of N atoms, decreasing the charge delocalization of adjacent carbon atoms, which leads to decreased catalytic activity in an acidic electrolyte. 74 In an alkaline electrolyte, there are two possible pathways. The rst is the chemisorption of an oxygen molecule onto the active site followed by receiving electrons and capturing protons from water until the OH À anion is generated without the desorption of a peroxide species (HO 2 À ) intermediate, as shown in eqn (7)- (9), which is analogous to the ISET in an acidic electrolyte. 71 *-(OO) ads + H 2 O + 2e À / *-(OOH) ads + OH À (8) *-(OOH) ads + H 2 O + 2e À / 3OH À The second is the outer-sphere electron transfer mechanism (OSET), in which the solvated oxygen molecule adsorbs on the active site through hydrogen bonding of *-(OH) ads species and received the rst electron from the electrode by the tunnelling effect to form oxygenated radical species [O 2 c À $(H 2 O) n ] aq , as shown in eqn (10). 71,75 At a more negative potential, the solvated [O 2 c À $(H 2 O) n ] aq species can be fully stripped off water shell and adsorbed to the active site followed by protonation to generate hydroperoxyl radical (HO 2 c), as shown in eqn (11) and (12). An additional electron was then captured by (HO 2 c) to form a hydrogen peroxide ion (HO 2 À ), as shown in eqn (13). 71 This illustrates the more negative potential for hydrogen peroxide generation compared to the ORR potential in the RRDE measurement, as shown in Fig. S14a of ESI. † In addition, the high hydrogen peroxide yield in the alkaline electrolyte compared to that in the acidic electrolyte at low potential could be due to the stable existence of a superoxide radical in alkaline media, which may stay in the outer-Helmholtz plane.
(HO 2 c) ads + e À / (HO 2 À ) ads / (HO 2 À ) aq (13) The ORR kinetics on the FePPyC À900 catalyst can be evaluated by Tafel analysis. In Fig. S15a of ESI, † the Tafel slopes of FePPyC-900 and Pt/C at low over potential were found to be 95 mV dec À1 and 106 mV dec À1 under alkaline conditions, respectively. In Fig. S15b of ESI, † the Tafel slope values of FePPyC-900 and Pt/C under acidic conditions were determined to be 78 mV dec À1 and 79 mV dec À1 , respectively. Interestingly, under both alkaline and acidic conditions, the FePPyC-900 catalyst shows a lower Tafel slope than those of the state-of-theart Pt/C. The lower Tafel slope value is desirable for the ORR activity, indicating that FePPyC-900 is more effective than Pt/C for the ORR under both alkaline and acid conditions. The exchange current density can be obtained by extrapolation of the horizontal axis. The lower Tafel slope would generate a higher exchange current density, whereas a higher Tafel slope would give a lower exchange current density. 76 Hence, the FeP-PyC-900 sample has a higher exchange current density than the Pt/C catalyst, indicating higher ORR activity.
In addition, the ORR performance of our catalyst was evaluated by the current-time response. The typical dynamic current response of all samples was measured at various potentials from 0.96 to 0.06 V (vs. RHE) at a rotation rate of 1600 rpm, as shown in Fig. S16. † The FePPyC-900 catalyst shows a much higher current compared to the other samples in different synthesis steps (Fig. S16a †). In addition, with different pyrolysis temperatures, FePPyC-900 also exhibits the best ORR performance with a higher current compared to the other FePPyC-T samples when increasing the negative applied potential, as observed in Fig. S16b. † These results are in good agreement with the LSV curves in Fig. S10a of ESI † and 6a.
In earlier reports, 24,77,78 carbon black (Vulcan XC-72) was used as a supporting carbon for N-doped carbon, and the catalyst consisting of N-doped carbon along with Vulcan carbon showed high ORR activity performance. Herein, we also added a certain amount of Vulcan carbon (XC-72) into our catalyst in the initial step of the synthesis process while keeping the remaining synthesis protocol identical and tested the ORR activity of the resulting FePPyC-900/VC under alkaline and acidic conditions (Fig. S17 of ESI †). Unlike the earlier study, the Vulcan carbon did not increase the ORR activity of the FePPyC-900 catalyst in the current experimental conditions under both alkaline and acidic conditions. It has been also demonstrated that the Fe and Co dualcontaining N-C compositions are considered to be the most promising systems for the development of high-performance ORR electrocatalysts. 3,41,79 Thus, according to the current synthesis method of FePPyC-900, FeCoPPyC-900 was synthesized using the identical PLS protocol with both Fe and Co metal precursors. A certain amount of cobalt nitrate (Co(NO 3 ) 2 ) was mixed with a FeCl 3 solution to have a mole ratio of Fe : Co ¼ 1 : 1, and the mixture was then added to the pyrrole solution. The full synthesis procedure followed the same processes as those of FePPyC-900. The LSV curves in Fig. S18 of ESI † illustrate the electrocatalyst performance of FeCoPPyC-900 under both alkaline and acidic conditions. Under alkaline conditions, the onset potential of FeCoPPyC-900 is similar to those of the commercial Pt/C and FePPyC-900. The half-wave potential and limiting current of FeCoPPy-900 are also similar to those of FePPyC-900 and slightly higher than those of Pt/C, suggesting high electrocatalyst activity of the FeCoPPyC-900 catalyst under alkaline conditions, as reported earlier. 3,41,79 Under acidic conditions, however, the onset potential and half-wave potential of FeCoPPyC-900 are much lower than those of FePPyC-900 and Pt/C, even though the limiting current of FeCoPPy-900 is better than those of FePPyC-900 and Pt/C. These extra experimental results indicate that the activity of FePPyC-900/VC and FeCoPPyC-900 is not good in an acidic electrolyte compared to that of the benchmark Pt/C, whereas the FePPyC-900 catalyst exhibits excellent ORR performance under both the alkaline and acidic conditions. Both the tolerance against the methanol crossover and stability of the catalyst material are also important parameters for an evaluation of practical fuel cell applications. 80 The methanol tolerance was evaluated by the current-time response at 0.85 V vs. RHE under alkaline conditions. It is shown in Fig. 8a that the ORR current of Pt/C drastically decreases aer the addition of 3.0 M methanol, which can be attributed to methanol oxidation instead of oxygen reduction by Pt/C under the current experimental conditions. On the other hand, except for a slight initial decrease, the ORR current of FePPyC-900 is almost unaffected, demonstrating that FePPyC-900 catalyst illustrates signicant methanol tolerance unparalleled to Pt/C. 56 In addition, the FePPyC-900 catalyst also exhibits excellent longterm stability compared to the commercial Pt/C catalyst for oxygen reduction under 0.1 M KOH conditions (Fig. 8b) and 0.5 M H 2 SO 4 condition (Fig. S19 of ESI †).
The stability of FePPyC-900 was evaluated further using the accelerated durability test (ADT) by potential cycling within a range of 0.6-1.1 V for O 2 -saturated 0.1 M KOH and 0.5-1.0 V (vs. RHE) for O 2 -saturated 0.5 M H 2 SO 4 . As shown in Fig. S20a and b of ESI, † the E 1/2 of FePPyC-900 decreases to 23 and 35 mV aer 2000 and 5000 potential cycles, respectively, whereas the E 1/2 of the Pt/C decreases to 37 mV aer 2000 cycles and further decreases to 50 mV aer 5000 cycles under alkaline conditions. In Fig. S20c and d of ESI, † the E 1/2 of FePPyC-900 in O 2 -saturated 0.5 M H 2 SO 4 negatively shied with 34 and 44 mV aer 2000 and 5000 potential cycles, respectively, which are much lower than the 53 mV and 74 mV negative shi observed for the Pt/C catalyst. This also supports the excellent durability of FePPyC-900 under both alkaline and acidic conditions.
As shown in Fig. S19 and S20 of ESI, † it was observed that even aer the long term cycling and accelerated durability test (ADT), the prepared catalyst shows only a minute decrease in the activity. This drop in activity can be attributed to the carbon corrosion and/or deactivation of N species as N-doped carbon lattice is a main active center for the ORR. TEM and SEM analyses of FePPyC-900 were performed before and aer ADT, as shown in Fig. S21. † It was found that the carbon surface, which was smooth and well interconnected before ADT still maintained a similar morphology and interconnectivity even aer ADT, even though the carbon surface may be coated with a naon binder. This may be the reason for only a minute decrease in the activity aer ADT. Although it is very difficult to estimate the extent of carbon corrosion only by the TEM image, it is expected that some carbon corrosion takes place and thus decreases the ORR activity aer ADT. As reported previously, carbon corrosion can be attributed to the decay of activity during the ORR performance. [81][82][83] In addition, the slow deactivation of N species may be also a reason because the protonation at the N atom in N-doped carbon can have a strong inuence on the lone-pair electrons of the N atoms, decreasing the charge delocalization of the adjacent carbon atoms, which leads to decreased catalytic activity.
Aer all, the FePPyC-900 demonstrates much better methanol tolerance and long-term stability than state-of-the-art Pt/C under both alkaline and acidic conditions. Electrocatalytic activities of as-prepared FePPyC-900 electrocatalyst and other related Fe-treated N-doped carbon catalysts in earlier works are summarized in Tables S4 and S5 (ESI †) under alkaline and acid conditions, respectively. FePPyC-900 represents remarkable activity, which is among the best activity ever reported for Fetreated N-doped carbon catalysts, and thus illustrates a viable alternative to a costly Pt/C catalyst in terms of synthesis procedure and economical point as well as ORR activity and stability under both alkaline and acid conditions.

Conclusions
A highly efficient noble metal-free electrocatalyst for ORR was developed by novel synthesis protocol of pyrolysis-leachingstabilization (PLS) sequence at different pyrolysis temperatures using polypyrrole as a single precursor for N and carbon, and ferric chloride as an oxidant and iron source. PPy was chosen as a single precursor for C and N because it is an excellent conducting polymer and can yield an extended graphitic carbon framework with high electrical conductivity upon carbonization. Each step of the PLS sequence was assessed in detail in terms of various physical properties of the resulting catalysts to validate the efficacy of the synthesis protocol. The full PLS sequence was found to be very effective for the preparation of an efficient Fe-treated N-doped carbon electrocatalyst. In particular, the additional stabilizing pyrolysis step aer acid leaching exhibits remarkable effect for better ORR activity as elaborated when a PLS sample (FePPyC-900) is compared with the corresponding rst pyrolysis sample (FePPyC-900bf) and subsequent acid-leached sample (FePPyC-900af). The catalyst prepared at 900 C (FePPyC-900) displayed highest catalytic activity towards oxygen reduction, which is comparable to that of state-of-the-art commercial 20 wt% Pt/C under both alkaline and acidic conditions. In particular, it was found that the ORR activity of the FePPyC-900 catalyst is almost comparable to that of Pt/C even in an acidic medium, which has rarely been reported as a non-Pt electrocatalyst to the best of our knowledge. This high ORR performance of FePPyC-900 can be attributed to the high degree of graphiticity, high electrical conductivity, high surface area, and high density of the active pyridinic-and graphitic-N species facilitated by the new synthesis protocol. Furthermore, FePPyC-900 exhibits better stability and methanol tolerance than the commercial Pt/C for ORR under both alkaline and acidic conditions with a four electron transfer pathway, suggesting the complete reduction of oxygen to water. Further modication such as additional carbon support and addition of Co as another metal to help in the current system was not found to be benecial. As a result, our as-prepared FePPyC electrocatalyst can become a viable alternative catalyst to precious Pt/C catalyst in PEMFCs with high ORR performance and long term stability.