Visible light compatible infrared stealth capability based on phase change materials

Abstract

This paper utilizes thermochromic phase change materials VO2 and GST to design micro-nano structures with temperature-tunable thermal emission characteristics, further controlling their stealth effects in both visible light and infrared backgrounds. Initially, an infrared stealth structure based on GST is proposed. By exploring its crystalline (aGST) and amorphous (cGST) states, the optimal thickness of GST is determined to be 250 nm. The structures corresponding to aGST and cGST exhibit emissions of 0.24 and 0.24 respectively at the atmospheric window of 3-5 μm, and 0.03 and 0.15 at 8-14 μm. These low emission capabilities aid in achieving infrared stealth. In the non-atmospheric window of 5-8 μm, the emissions are 0.06 and 0.76, which can help reduce heat loss at low temperatures and radiate energy at high temperatures, thus optimizing the stealth effect. Subsequently, a ZnS layer is added on top to regulate structural color. By scanning the thickness of ZnS under different states of GST, we investigate the chromaticity coordinates of the structure in amorphous, crystalline, and mixed states with varying crystal proportions. From the perspective of infrared emissivity, the feasibility of visible light stealth is studied. A ZnS layer thickness of 150 nm is selected as the optimal parameter, determining the infrared emissivity for both states. The structures corresponding to aGST and cGST exhibit emissions of 0.17 and 0.22 at the atmospheric window of 3-5 μm, and 0.03 and 0.20 at 8-14 μm. The low emission capabilities help achieve infrared stealth, while the emissions within the non-atmospheric window of 5-8 μm are 0.10 and 0.77. Resonance absorption reasons are explained by calculating normalized electric field and energy dissipation intensity. Finally, a VO2 layer is added. Due to the reversible nature of the VO2 phase change, two phase change materials at different temperatures result in four states. The thickness of the VO2 layer is varied to explore the infrared emissivity under different states. This paper primarily focuses on designing dynamically tunable micro-nano structures by combining phase change materials, achieving precise control over reflection and emission characteristics in both visible light and infrared bands, thus providing more possibilities for stealth technology.

Transparent peer review

To support increased transparency, we offer authors the option to publish the peer review history alongside their article.

View this article’s peer review history

Article information

Article type
Paper
Submitted
08 Feb 2025
Accepted
24 Mar 2025
First published
26 Mar 2025

Dalton Trans., 2025, Accepted Manuscript

Visible light compatible infrared stealth capability based on phase change materials

Z. Ai, H. Zhang, S. Cheng, Z. Yi and Q. Song, Dalton Trans., 2025, Accepted Manuscript , DOI: 10.1039/D5DT00311C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements