Issue 78, 2016, Issue in Progress
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RSC Advances

Role of flexible bulky groups and weak interactions involving halogens in the vapoluminescence of a metal-free dye†

Y. Akune,a   R. Hirosawa,a   H. Takahashi,b   M. Shiroc  and  S. Matsumoto*a  

* Corresponding authors

a Graduate School of Environmental and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
E-mail: smatsu@ynu.ac.jp
Fax: +81-45-339-3345
Tel: +81-45-339-3366

b System Instruments Co., Ltd., 776-2 Komiya, Hachioji, Tokyo 192-0031, Japan

c X-Ray Research Laboratory, Rigaku Corporation, 3-9-12 Matsubaracho, Akishima, Tokyo 196-8666, Japan

Abstract

A metal-free pyrazine dye exhibited vapoluminescence when exposed to benzene vapour. Single-crystal X-ray analysis revealed that its flexible bulky groups and weak interactions involving halogens play an essential role in the occurrence of the observed vapoluminescence.

Graphical abstract: Role of flexible bulky groups and weak interactions involving halogens in the vapoluminescence of a metal-free dye

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Article information

DOI
https://doi.org/10.1039/C6RA15966D
Article type
Communication
Submitted
20 Jun 2016
Accepted
29 Jul 2016
First published
01 Aug 2016

RSC Adv., 2016,6, 74506-74509

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Role of flexible bulky groups and weak interactions involving halogens in the vapoluminescence of a metal-free dye

Y. Akune, R. Hirosawa, H. Takahashi, M. Shiro and S. Matsumoto, RSC Adv., 2016, 6, 74506 DOI: 10.1039/C6RA15966D

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