Issue 31, 2016
From the journal:

RSC Advances

A radical coupling reaction of DMSO with sodium arylsulfinates in air : mild utilization of DMSO as C1 resource for the synthesis of arylsulfonyl dibromomethane†

Jie Shi,‡a   Xiao-Dong Tang,‡b   Yan-Cheng Wu,a   Jie-Fang Fang,a   Liang Cao,a   Xiao-Yun Chen*c  and  Zhao-Yang Wang*a  

* Corresponding authors

a School of Chemistry and Environment, South China Normal University, Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou 510006, P. R. China
E-mail: wangzy@scnu.edu.cn
Fax: +86-020-3931-0187
Tel: +86-020-3931-0187

b School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

c School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, P. R. China
E-mail: xiaoyun_chen12@163.com

Abstract

A radical coupling reaction of DMSO with sodium arylsulfinates under air atmosphere to afford arylsulfonyl dibromomethane is described. This transformation provides a novel approach for the utilization of DMSO as a C1 resource with mild temperature without the need for an anaerobic atmosphere.

Graphical abstract: A radical coupling reaction of DMSO with sodium arylsulfinates in air : mild utilization of DMSO as C1 resource for the synthesis of arylsulfonyl dibromomethane

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Article information

DOI
https://doi.org/10.1039/C6RA01393G
Article type
Communication
Submitted
16 Jan 2016
Accepted
01 Mar 2016
First published
02 Mar 2016

RSC Adv., 2016,6, 25651-25655

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A radical coupling reaction of DMSO with sodium arylsulfinates in air : mild utilization of DMSO as C1 resource for the synthesis of arylsulfonyl dibromomethane

J. Shi, X. Tang, Y. Wu, J. Fang, L. Cao, X. Chen and Z. Wang, RSC Adv., 2016, 6, 25651 DOI: 10.1039/C6RA01393G

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