Issue 13, 2014
From the journal:

Chemical Communications

Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple ‘pseudo-fluid’ model for a ball milling reaction†

Xiaohe Ma,a   Wenbing Yuan,b   Steven E. J. Bell*a  and  Stuart L. James*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, Northern Ireland, UK
E-mail: s.james@qub.ac.uk, s.bell@qub.ac.uk
Web: www.ch.qub.ac.uk/staff/james/, www.ch.qub.ac.uk/staff/bell/

b Key Laboratory of Tropical Biological Resources of the Ministry of Education, Hainan University, Haikou, China

Abstract

Quantitative monitoring of a mechanochemical reaction by Raman spectroscopy leads to a surprisingly straightforward second-order kinetic model in which the rate is determined simply by the frequency of reactive collisions between reactant particles.

Graphical abstract: Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple ‘pseudo-fluid’ model for a ball milling reaction

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Article information

DOI
https://doi.org/10.1039/C3CC47898J
Article type
Communication
Submitted
14 Oct 2013
Accepted
17 Dec 2013
First published
02 Jan 2014

Chem. Commun., 2014,50, 1585-1587

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Better understanding of mechanochemical reactions: Raman monitoring reveals surprisingly simple ‘pseudo-fluid’ model for a ball milling reaction

X. Ma, W. Yuan, S. E. J. Bell and S. L. James, Chem. Commun., 2014, 50, 1585 DOI: 10.1039/C3CC47898J

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