Antireflective gradient-refractive-index material-distributed microstructures with high haze and superhydrophilicity for silicon-based optoelectronic applications

We fabricate gradient-index (n) material-based microstructures, i.e., magnesium fluoride (MgF2, n ∼ 1.37) film-coated SU8 ultraviolet curable polymer (n ∼ 1.59) microcones (MCs) with tapered architectures, on silicon (Si, n ∼ 3.9) substrates using a soft imprint lithography method for high-performance Si-based optoelectronic applications. The effects of various geometry parameters (i.e., height, filling ratio, and period) of conical MCs on the SU8 film/Si structure including different thicknesses of MgF2 films on the reflectance properties are investigated by a theoretical analysis using a rigorous coupled-wave analysis simulation. For the fabricated samples, their optical characteristics and surface wetting behaviors are also explored. The MgF2 film-coated SU8 MCs on Si substrates (i.e., MgF2/SU8 MCs/Si) exhibit a superhydrophilic surface with very low water contact angles of <10° and reduce the surface reflection of the bare Si over a wide wavelength of 350–1100 nm, showing the lower average reflectance (Ravg) and solar weighted reflectance (Rsw) values of ∼14% and ∼12.1%, respectively, (i.e., Ravg ∼ 15.1% and Rsw ∼ 13% for the SU8 MCs/Si and Ravg ∼ 38.5% and Rsw ∼ 38% for the bare Si). Furthermore, the MgF2/SU8 MCs on glasses also show strong light scattering in transmissions at wavelengths of 350–1100 nm, which indicates an average haze ratio of ∼89.8%, while maintaining high total transmissions. Both the measured and calculated reflectance spectra showed similar results.


Introduction
2][3][4] However, the surface reflection of the Si is higher than 30% due to its high refractive index (high-n), which degrades the performance of Si-based optoelectronic devices.Thus, it is important to employ efficient antireflection coatings (ARCs) which can suppress unwanted Fresnel surface reflection losses.][10][11][12][13][14][15][16][17][18][19] However, for a realization of micro or nanostructures, high-cost, low-throughput, and complex nanolithography techniques, i.e., laser interference 14,15 , electron (e)-beam 16 , and nanoimprint 17 lithography methods and thermal 18 and electro-chemical 19 treatments, together with a dry etching are usually required.6][27][28] These polymers are suitable for ARCs on the surface of the Si due to relatively low refractive indices of ~ 1.4-1.7.4][35] Meanwhile, the superhydrophilicity makes water droplets to spread out evenly like a thin film on the surface.When a water droplet flows on the hydrophilic surface, it can squeeze into the space between the dusts and the surface, and then take the dusts away, i.e., self-cleaning. 18,19,36lso, it has many functions such as anti-fog, quick dry, and elimination of light scattering caused by the water droplets.
This hydrophilicity can be enhanced if the roughness is sufficiently large. 37,38Our group has previously reported the antireflective GRIN material-distributed microstructures with a strong light scattering effect, together with an optical analysis. 31he micrograting structures were fabricated on the surface of transparent sapphires by conventional photo lithography patterning and subsequent dry etching processes.As mentioned earlier, however, the realization of directly-patterned structures on the Si surface using these pattering and etching processes leads to the increase of the complexity and cost in the fabrication process.To avoid this problem, here, we proposed a novel architectural approach consisting of GRIN materialdistributed microcone arrays, which effectively reduces the surface reflectivity of Si and enhances the light scattering in the Si, fabricated by the soft imprint lithography using the micrograting structured sapphires as a master mold and PDMS stamps.Although the master molds with microstructures are also prepared by the lithography patterning and etching processes, once master molds and replica polymer stamps are made, they can be repeatedly employed for pattern transfers into secondary substrates.Furthermore, the large-scale fabrication techniques (i.e., roll-to-roll and roll-to-plate processes) of master molds and stamps have been developed in the soft imprint lithography, 39,40 which would facilitate the mass-production for industry applications.In addition, it is difficult to optimize experimentally efficient antireflective GRIN material-distributed microstructures with a strong light scattering effect on the Si surface due to high cost and timeconsumption.To verify their optical properties with optimizing the structure, it is also necessary to perform numerical modeling and optical calculations.Therefore, it is very meaningful to analyze the optical properties and wetting behaviors of the GRIN material-based microstructures on the Si surface.In this work, we reported the optical design, fabrication, and characterization (i.e., optical properties and surface wettability) of magnesium fluoride (MgF 2 )-coated SU8 polymer microstructures on the Si surface via the soft imprint lithography and subsequent e-beam evaporation.For optical analyses, numerical modeling and simulations were carried out using the rigorous coupled-wave analysis (RCWA) and finitedifference time-domain (FDTD) methods.

Effect of geometry parameters on reflectance properties
Firstly, the effects of various geometry parameters, such as height, filling ratio, and period, of conical MCs on the SU8 film/Si substrate on reflectance properties were investigated by the RCWA method using a commercial software (DiffractMOD, Rsoft Design Group).For the MgF 2 film-coated SU8 MCs/Si structure (i.e., MgF 2 /SU8 MCs/Si), the reflection calculations were also performed as a function of MgF 2 film thickness.Fig. 1 shows the (a) contour plots of variations of calculated reflectance spectra of the SU8 MCs/Si structure for different geometry parameters of (i) height, (ii) filling ratio, and (iii) period including the (iv) MgF 2 film thickness of the MgF 2 /SU8 MCs/Si structure and (b) average reflectance (R avg ) values for the corresponding geometry parameters at wavelengths of 350-1100 nm.The fixed values for geometry parameters and three-dimensional (3D) scale-modified corresponding simulation models with 2D periodic hexagonal pattern arrays used in these calculations are also shown in the inset of Figs.1(a) and 1(b), respectively.To design the numerical model, the geometry of the conical MCs was roughly represented in the Cartesian coordinate system by a scalarvalued function of three variables, f(x,y,z), for simplicity.The shape of conical MCs can be roughly defined by the following equations: ( ) x y r where r is the radius of the circle in x-y plane, and H MCs , R MCs , and O T are the height, the bottom radius, and the order of taper of MCs, respectively.For all the calculations, it was assumed that the O T was set to be 1.5 and thicknesses of SU8 film and Si substrate were kept at 1 and 500 µm, respectively.As shown in Fig. 1, the SU8 MCs considerably reduce the surface reflection of the bare Si due to the GRIN profiles in terms of structure (i.e., tapered cone shape) and constituent materials (i.e., air/SU8/Si).However, their reflection property is strongly dependent on the height and filling ratio (i.e., ratio of the bottom diameter of MCs to the period between MCs; R BDP ) of MCs as well as the MgF 2 film thickness while there is relatively no significant variation for the period.As shown in Fig. 1(a), furthermore, the strong oscillations in calculation reflectance spectra of SU8 MCs/Si structure are observed over a wide wavelength range of 350-1100 nm due to the constructive or destructive interference caused by multiple reflections of the light at interfaces of the air/SU8 and SU8/Si.For the height in the (i) of Fig. 1(b), the R avg value is gradually decreased from 15.7 to 12.3% with increasing the height of MCs from 0.5 to 5 µm.This is attributed to the longer optical path length and more GRIN profile between air and the SU8 film via the MCs at larger heights. 8,15,41For the filling ratio (R BDP ), the high reflection region (i.e., red part in the (ii) of Fig. 1(a)) of > 21% is reduced with increasing the R BDP value, exhibiting the R avg values of 19.7% at R BDP = 0.1 and 13.8% at R BDP = 1, as shown in the (ii) in Fig. 1(b).This means that even if the MCs are formed there is a lower effect on reflectance properties at lower filling ratios. 14,42Thus, to effectively suppress the reflection, the closely-packed MCs are required.On the other hand, for a period range of 2-5 µm in the (iii) of Fig.  interference caused by a UV-light diffraction in the short period mask patterns during the exposure process, and lower PR thicknesses on the formation of 2D hexagonal dotted PR pattern arrays with sub-2 µm periods on substrates. 43,44The MCs with sub-2 µm periods can be fabricated by other patterning techniques including laser interference 14,15 , e-beam 16 , or imprint 17 lithography, colloidal formation 45,46 , and thermallydewetted metal particles 47,48 .But, fabrication cost, simple approach, throughput, and process time of master molds as well as deformation and distortion of stamps and replicas patterntransferred from the master molds with sub-2 µm scale features in the soft imprint lithography process should be considered for industrial applications.Lastly, the GRIN-material structure can further suppress the surface reflection.As can be seen in the (iv) of Fig. 1, the coating of MgF 2 film with a lower n onto the SU8 MCs/Si further decreases the reflection, showing lower R avg values.Particularly, at a thickness of 500 nm, the GRIN MgF 2 /SU8 MCs/Si structure has a R avg value of 13.8% which is lower than that (i.e., R avg = 14.8%) of SU8 MCs/Si without the MgF 2 film.Thus, we deposited the MgF 2 film with 500 nm of thickness on the SU8 MCs/Si with geometry parameters including height of 1.4 µm, R BDP of 0.9, and period of 2.9 µm in experiments.

Angle-dependent reflectance properties
The conical micrograting structure can further suppress the surface reflection for the obliquely incident light due to its relatively omnidirectional shape. 12 Meanwhile, the MgF 2 /SU8 MCs/Si structure shows superior antireflective properties compared to the SU8 MCs/Si at θ i values of < 40 o while it exhibits slightly higher R avg values at some θ i values of ≥ 40 o .This may be attributed to the variation of effective optical path lengths, which is related to the interferences in diffracted and rebounded lights at the interfaces of air/MgF 2 film, MgF 2 film/SU8 MCs, and SU8 film/Si, caused by the change in the optical thickness of MgF 2 film on the SU8 MCs/Si structure for larger oblique incident lights. 49evertheless, its R avg value of ~ 12.4% for the entire θ i range of 0-80 o is lower than those of both the bare Si (i.e., R avg ~ 36.6%) and the SU8 MCs/Si (i.e., R avg ~ 12.8%) samples.From these results, the conical microstructured polymer films can significantly suppress the surface reflection of Si over a wide range of wavelengths and incident angles.Moreover, the coating of materials with a lower n on the SU8 MCs/Si can further reduce the reflection.The surface and cross-sectional morphologies of the samples were characterized by using a SEM (LEO SUPRA 55, Carl Zeiss) system.The reflectance and transmittance properties were characterized by using a UV-vis-NIR spectrophotometer (Cary 5000, Varian) with an integrating sphere.The contact angles of water droplets were taken by using a contact angle measurement system (Phoenix-300, SEO Co., Ltd.) and averaged for three different positions on the surface of samples.4(a), it can be observed that the conical MCs on SU8 film/Si substrates were well transferred from sapphire master molds via the PDMS stamps without any large deformation and distortion over a broad area.The MgF 2 film with a thickness of 500 nm was also well deposited on the surface of SU8 MCs/Si samples.For the SU8 MCs, the average period and average height were also estimated to be ~ 2.9±0.1 and 1.4±0.1 µm, respectively.The filling ratio of MCs was about R BDP ~ 0.9.The surface wetting properties strongly depend on the structures and materials. 37,50As shown in Fig. 4(b), the bare Si exhibited a hydrophilic surface with a water contact angle (θ C ) of ~ 42 o .However, for the SU8 MCs, the θ C value of ~ 92 o was obtained.This θ C value is higher than that (i.e., θ C ~ 74 o ) 26 of flat SU8 films without any patterns due to the increased roughness on the surface of SU8 films caused by the MCs, which can be explained by the Cassie-Baxter model. 51On the other hand, the MgF 2 film-coated SU8 MCs/Si samples had very low θ C values of < 10 o , indicating a superhydrophilic surface.This is due to the hydrophilic MgF 2 film on the roughened MCs as proposed by the Wenzel's model. 37For the superhydrophilic surface, a water droplet can rapidly spread out and form a liquid film after falling onto the surface, and under the effect of gravity, the liquid film is easy to flow along the surface and takes dust particles or contaminants away. 18,19,36herefore, these MgF 2 /SU8 MCs/Si structures with a superhydrophilic surface may self-clean the pollutants and This journal is © The Royal Society of Chemistry 2014 quickly dry the rainwater on the surface of Si-based optoelectronic devices in real outdoor environments. 36,52

Optical properties
Measured reflectance spectra and 50 o -titled oblique-view photographs of the bare Si, the SU8 MCs/Si, and the MgF 2 /SU8 MCs/Si samples are shown in Figs.5(a) and 5(b), respectively.The refractive index profile (left) of MgF 2 /SU8 MCs/Si structure and calculated reflectance spectra (right) of the corresponding structures are also shown in the inset of Fig. 5(a).At wavelengths above 1030 nm, the abrupt increase in reflectance spectra is attributed to the backscattered lights from the back surface of the Si substrate because Si is transparent below its energy bandgap. 53As shown in Fig. 5(a), the SU8 MCs considerably reduce the reflection, exhibiting a much lower R avg value of ~15.1% than that of the bare Si (i.e., R avg ~ 38.5%).However, as confirmed in the calculated reflectance results in Fig. 1(d), the 500 nm-thick MgF 2 film-coated SU8 MCs/Si can lower further the reflectance compared to the SU8 MCs/Si over a wide wavelength of 350-1100 nm, showing the R avg value of ~ 14%.4,55 In fact, the MgF 2 /SU8 MCs/Si with the R avg ~ 14% exhibits a relatively poor antireflection performance compared to other nanostructures or thin films as ARCs for reducing the surface reflectivity of the Si.7][58][59] The thin film-based ARCs such as single layer (i.e., SiN) 60 or double layers (i.e., SiO 2 /TiO 2 ) 61 coated on the Si also showed R avg values below than 10%.However, most of nanostructures for ARCs have been usually realized by expensive and complicated fabrication processes including colloidal-sphere 56,57 , nanoimprint 58 , and laser interference 59 lithography techniques as well as thermallydewetted metal nanoparticles 47 with subsequent dry or chemical etching processes.On the other hand, the conventional ARCs consisting of a stack of thin-film dielectric layers can be fabricated by a relatively simple deposition or coating processes.But, they also have some drawbacks such as poor or reduced substrate adhesion on certain materials due to the thermal expansion mismatch, sensitivity to thickness variations, and material selection as well as narrow low reflection band for incident wavelengths and angles, [5][6][7] which may not be suitable in practical harsh environments.1][22][23][24] Master molds and stamps are also reusable.Additionally, mass production is possible by large-scale fabrication techniques for polymer stamps. 39,40Moreover, this pattern transfer technique can be also employed on various substrates including semiconductors, metals, and transparent materials.For photovoltaic device applications, it is necessary to investigate the solar weighted reflectance (R sw ), which is defined by the ratio of the usable photons reflected to the total useable photons, of samples.The R sw can be estimated by normalizing the reflectance and the terrestrial air mass 1.5 global spectra integrated over a wavelength range of 350-1100 nm. 3 For the MgF 2 /SU8 MCs/Si sample, the relatively lower R sw value of ~ 12.1% was obtained compared to the SU8 MCs/Si (i.e., R sw ~ 13%) as well as the bare Si (i.e., R sw ~ 38%).In the inset of Fig. 5(a), the reflectance spectra calculated by the RCWA method roughly show a similar trend with the measured data in Fig. 5(a).Also, their antireflective properties can be observed from the photograph in Fig. 5(b).The characters in the LCD monitor were strongly reflected by the surface of the bare Si.On the contrary, both the SU8 MCs/Si samples with and without the MgF 2 film almost had a black surface due to their low reflectivity at visible wavelengths, as can be seen in Fig. 5(a).Also, rainbow (i.e., green or red)-like colors on their surfaces were shown due to the strong light diffraction property.
To investigate the diffuse light scattering of SU8 MCs, the corresponding structures were also prepared on the surface of glasses.Measured total and diffuse transmittance spectra of the bare glass, the SU8 MCs/glass, and the MgF 2 /SU8 MCs/glass samples are shown in Figs.5(c) and 5(d), respectively.As shown in Fig. 5(c), both the SU8 MCs/glass and MgF 2 /SU8 MCs/glass samples exhibited higher total transmission spectra than that of the bare soda lime glass, which shows the similar optical behavior reported in the previously-published litheratures 28,62 , in the wide wavelength range of 350-1100 nm, indicating larger average transmittance (T avg ) and solar weighted transmittance (T sw ) values of ~ 92.4% and 93% for the SU8 MCs/glass and ~ 93.4% and ~ 93.9% for the MgF 2 /SU8 MCs/glass, respectively, (i.e., T avg ~ 88.3% and T sw ~ 89.1% for the bare glass).Besides, for a periodic grating structure, when light enters into the grating with a period of Λ at normal incidence, the angle of the transmitted diffraction waves, θ t,m , in the m-th diffraction order is given by the wellknown grating equation: 63 where λ is the incident wavelength of light and n is the refractive index of the incident medium.From this, the grating structure with periods larger than incident wavelengths generates higher order diffracted lights in transmission.54,55 As shown in Fig. 5(d), the SU8 MCs/glass and MgF 2 /SU8 MCs/glass samples had very high diffuse transmittance spectra over a wide wavelength region of 350-1100 nm while there exist almost no diffracted lights for the bare glass.Furthermore, the diffuse transmittance of MgF 2 /SU8 MCs/glass was slightly enhanced compared to the SU8 MCs/glass because of the MgF 2 film with a lower n. 29,31he haze ratio (H), which is defined by the ratio of the diffuse (T d ) to the total (T t ) transmission, i.e., H(%)= T d /T t ×100, is often used to characterize the light scattering properties of a sample.For both the SU8 MCs/glass and MgF 2 /SU8 MCs/glass, the average H (H avg ) values were estimated to be ~ 88.4 and 89.8%, respectively, at wavelengths of 350-1100 nm (i.e., H avg ~ 3.8% for the bare glass).In the transmission, these high diffraction behaviors (i.e., light scattering) can be confirmed from the FDTD simulations.The contour plots of FDTD-calculated electric field (E y ) distributions for the incident light propagating from air to the bare glass and the MgF 2 /SU8 MCs/glass samples at λ= 620 nm are shown in the inset of Fig. 5(d).In FDTD simulations, the E y , i.e., amplitude of y-polarized electric field, was calculated for the incident plane wave with a slab mode beam profile which is normalized at λ= 620 nm.The simulation results indicate that the SU8 MCs with a period of 2.9 µm exhibit strong light interference patterns with a wide angular spread and help the light propagation across the interface between air and the SU8 while there are no scattering lights for the flat bare glass. 3,31From these results, the MgF 2 film-coated SU8 MCs can effectively reduce the surface reflection of Si and they can lead to the strong light scattering inside the bulk Si, which can be useful to enhance the optical performance in optical and optoelectronic devices.

Conclusions
The MgF 2 /SU8 MCs/Si consisting of GRIN-material structures were fabricated by the soft imprint lithography using sapphire master molds with 2D periodic hexagonal conical micrograting pattern arrays.In comparison with both the SU8 MCs/Si and bare Si, their antireflective properties were experimentally and theoretically investigated, including their surface wetting behaviours.The coating of MgF 2 film on the SU8 MCs/Si structure led to the reduction of reflection as well as the enhancement of diffused lights in transmissions.Additionally, it showed strong light diffraction with a H avg value of ~ 89.8% over a wide wavelength region of 350-1100 nm.These results can provide a better insight into the broadband wide-angle antireflection microstrutures, which can be easily preapred by the simple and inexpensive soft lithography, with a self-cleaning functioned superhydrophilic and large diffuse light scattering properties for the fabrication of high-performance Si-based optoelectronic devices.

Fig. 1
Fig.1(a) Contour plots of variations of calculated reflectance spectra of the SU8 MCs/Si structure for different geometry parameters of (i) height, (ii) filling ratio, and (iii) period including the (iv) MgF2 film thickness of the MgF2/SU8 MCs/Si structure and (b) average reflectance (Ravg) for corresponding geometry parameters at wavelengths of 350-1100 nm.The fixed values for geometry parameters and three-dimensional (3D) scale-modified corresponding simulation models with 2D periodic hexagonal pattern arrays used in these calculations are also shown in the inset of (a) and (b), respectively.

Fig. 2
Fig. 2 (a) Contour plots of variations of calculated reflectance spectra of (i) bare Si, (ii) SU8 MCs/Si, and (iii) MgF2/SU8 MCs/Si for different incident angles (θi) of 0-80 o and (b) Ravg of corresponding structures as a function of incident angle for non-polarized light.

Fig. 2
shows the (a) contour plots of variations of calculated reflectance spectra of (i) the bare Si, (ii) the SU8 MCs/Si, and (iii) the MgF 2 /SU8 MCs/Si for different incident angles (θ i ) of 0-80 o and (b) R avg values of the corresponding structures as a function of incident angle for non-polarized light.In Fig.2, the incorporation of conical SU8 MCs into the surface of Si results in considerable reduced reflection in wide ranges of wavelengths and incident angles.The SU8 MCs/Si structure has a much lower R avg value of ~ 12.8% for θ i values of 0-80 o (i.e., R avg ~ 36.6% for the bare Si).

Fig. 3
Fig. 3 Schematic diagram of process steps for the fabrication of MgF2 film-coated SU8 MCs on Si substrates via soft lithography and e-beam evaporation.The SEM images of (i) sapphire master molds and (ii) PDMS stamps are also shown, respectively.

Fig. 3
Fig.3shows the schematic diagram of process steps for the fabrication of MgF 2 film-coated SU8 MCs on Si substrates via the soft lithography and electron (e)-beam evaporation.The scanning electron microscope (SEM) images of (i) sapphire master molds and (ii) PDMS stamps are also shown in Fig.3.To form the MCs on SU8 polymer films, the patterned sapphire substrate, which was purchased from AND Corporation, consisting of conical MCs with 2D periodic hexagonal patterns were used as a master mold, having average height and period of ~ 1.5±0.1 and ~ 2.9±0.1 µm, as shown in the (i) SEM image of Fig.3.In order to transfer MC patterns from the master mold into the Si substrate, Sylgard 184 (Dow Corning Co.) PDMS solution at a ratio of 10:1 (base:agent) was poured on master molds and then cured at a temperature of 75 o C for 2 h.After that, the PDMS stamps were carefully separated from the molds, thus creating the negative conical MC patterned PDMS stamps, as shown in the (ii) SEM image of Fig.3.The SU8 (Micro Chem Corp.) negative photoresist which is one of UV curable polymers was spin-coated on Si substrates with a size of ~ 20 mm × 20 mm, which were ultrasonically cleaned in acetone, methanol, and de-ionized water for 10 min, respectively, and cured provisionally by pressing (3.0 kgf) the PDMS stamps.After UV exposure for 20 min, the MCs on the surface of SU8 film/Si substrates were formed by peeling off the PDMS stamps.The MgF 2 film was deposited on SU8 MCs/Si samples by using an e-beam evaporation system at room temperature with a rotation speed of 10 rpm.The deposition rate was kept at 2 Å/s using a quartz crystal sensor for thickness monitoring and rate control.The MgF 2 filmcoated SU8 MCs were also prepared on the soda lime float glass substrates (Microscope slides, Sail brand, Cat.No. 7101, manufactured by Yancheng Huida medical instruments Co., China).The surface and cross-sectional morphologies of the samples were characterized by using a SEM (LEO SUPRA 55, Carl Zeiss) system.The reflectance and transmittance properties were characterized by using a UV-vis-NIR spectrophotometer (Cary 5000, Varian) with an integrating sphere.The contact

Fig. 4
Fig. 4 (a) 40 o -tilted oblique-and side-view SEM images of the MgF2/SU8 MCs/Si sample and (b) photographs of a water droplet on the surface of bare Si, SU8 MCs/Si, and MgF2/SU8 MCs/Si samples.

Fig. 4
Fig. 4 shows (a) the 40 o -tilted oblique-and side-view SEM images of the MgF 2 /SU8 MCs/Si sample and (b) the photographs of a water droplet on the surface of the bare Si, the SU8 MCs/Si, and the MgF 2 /SU8 MCs/Si samples.From the SEM images of Fig.4(a), it can be observed that the conical MCs on SU8 film/Si substrates were well transferred from sapphire master molds via the PDMS stamps without any large deformation and distortion over a broad area.The MgF 2 film with a thickness of 500 nm was also well deposited on the surface of SU8 MCs/Si samples.For the SU8 MCs, the average period and average height were also estimated to be ~ 2.9±0.1 and 1.4±0.1 µm, respectively.The filling ratio of MCs was about R BDP ~ 0.9.The surface wetting properties strongly depend on the structures and materials.37,50As shown in Fig.4(b), the bare Si exhibited a hydrophilic surface with a water contact angle (θ C ) of ~ 42 o .However, for the SU8 MCs, the θ C value of ~ 92 o was obtained.This θ C value is higher than that (i.e., θ C ~ 74 o )26 of flat SU8 films without any patterns due to the increased roughness on the surface of SU8 films caused by the MCs, which can be explained by the Cassie-Baxter model.51On the other hand, the MgF 2 film-coated SU8 MCs/Si samples had very low θ C values of < 10 o , indicating a superhydrophilic surface.This is due to the hydrophilic MgF 2 film on the roughened MCs as proposed by the Wenzel's model.37For the superhydrophilic surface, a water droplet can rapidly spread out and form a liquid film after falling onto the surface, and under the effect of gravity, the liquid film is easy to flow along the surface and takes dust particles or contaminants away.18,19,36Therefore, these MgF 2 /SU8 MCs/Si structures with a superhydrophilic surface may self-clean the pollutants and

Fig. 5
Fig. 5 (a) Measured reflectance spectra and (b) 50 o -titled oblique-view photograph of bare Si, SU8 MCs/Si, and MgF2/SU8 MCs/Si samples.Measured (c) total and (d) diffuse transmittance spectra of bare glass, SU8 MCs/glass, and MgF2/SU8 MCs/glass samples.The refractive index profile (left) of MgF2/SU8 MCs/Si structure and calculated reflectance spectra (right) of corresponding structures are also shown in the inset of (a).Contour plots of FDTD-calculated electric field (Ey) distributions for the incident light propagating from air to the bare glass and MgF2/SU8 MCs/glass samples at λ= 620 nm are shown in the inset of (d).
1(b), the R avg values are maintained at similar values of 14.5±0.4%.At the period of 2 µm, the SU8 MCs/Si has the lowest R avg value of 14.1%.Unfortunately, for the realization of MCs with low-scale (i.e., sub-2 µm), there are limitations in the conventional photo lithography process such as the increase of fabrication cost and complexity on making soda lime or quartz mask substrates with sub-2 µm periods dotted metal (i.e., chrome) pattern arrays as well as the shorter photoresist (PR) development times, deformation/distortion of exposed PR patterns due to a This journal is © The Royal Society of Chemistry 2014 The MgF 2 /SU8 MCs/Si sample had a superhydrophilic surface (i.e., θ C values of < 10 o ) and exhibited lower R avg and R sw values of ~ 14% and ~ 12.1%, respectively, at wavelengths of 350-1100 nm This journal is © The Royal Society of Chemistry 2014 (i.e., R avg ~ 15.1% and R sw ~ 13% for the SU8 MCs/Si and R avg ~ 38.5% and R sw ~ 38% for the bare Si, respectively).