Issue 12, 2015

K2S2O8-mediated metal-free direct C–H functionalization of quinones using arylboronic acids

Abstract

Direct C–H functionalization of quinones with arylboronic acids is achieved using K2S2O8 as the sole and efficient green catalytic system. This method provides a straightforward and sustainable way to construct arylquinones via a radical pathway in moderate to good yields under metal-free conditions.

Graphical abstract: K2S2O8-mediated metal-free direct C–H functionalization of quinones using arylboronic acids

Supplementary files

Article information

Article type
Research Article
Submitted
04 Aug 2015
Accepted
15 Oct 2015
First published
15 Oct 2015

Org. Chem. Front., 2015,2, 1616-1620

Author version available

K2S2O8-mediated metal-free direct C–H functionalization of quinones using arylboronic acids

A. Ilangovan, A. Polu and G. Satish, Org. Chem. Front., 2015, 2, 1616 DOI: 10.1039/C5QO00246J

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