Issue 41, 2015

Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions

Abstract

A conjugated microporous polymer was synthesized via a modified Sonogashira–Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol–yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.

Graphical abstract: Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions

Supplementary files

Article information

Article type
Communication
Submitted
22 May 2015
Accepted
27 May 2015
First published
02 Jun 2015

Polym. Chem., 2015,6, 7251-7255

Author version available

Facile synthesis of a conjugated microporous polymeric monolith via copper-free Sonogashira–Hagihara cross-coupling in water under aerobic conditions

J. Liu, J. M. Tobin, Z. Xu and F. Vilela, Polym. Chem., 2015, 6, 7251 DOI: 10.1039/C5PY00772K

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