A novel carbon nanotubes reinforced superhydrophobic and superoleophilic polyurethane sponge for selective oil–water separation through a chemical fabrication

Abstract

Oil spillage and industrial oily wastewater have caused severe environmental concerns. A super absorbent material capable of separating oil–water mixtures, especially with a high absorption capacity and mechanical strength, is urgently desired. Here, a common and feasible approach to fabricate carbon nanotubes (CNTs) reinforced polyurethane (PU) sponge is presented that shows superhydrophobic and superoleophilic properties. The method involves the oxidative self-polymerization of dopamine and the reaction of hydrophilic polydopamine (PDA) with hydrophobic octadecylamine (ODA). The superhydrophobic stability of the as-prepared sponge with temperatures and in corrosive solutions of different pH is investigated. The as-prepared sponge could quickly and selectively absorb various kinds of oils up to 34.9 times of its own weight, and the absorbed oils can be collected by a simple squeezing process. More interestingly, the mechanical strength of the as-prepared sponge is improved due to the structural reinforcement of CNTs anchored on the sponge skeleton. Furthermore, the recovered sponge could be reused to separate oil–water mixture 150 times while maintaining its high absorption capacity. This promising multifunctional sponge exhibits significant potential as an efficient absorbent in large-scale oil–water separation applications.