The annulative coupling of donor–acceptor cyclopropanes with cyclic secondary amines is reported using the combination of Ni(OTf)2 and visible light assisted eosin Y catalysis for tandem C–N and C–C bond formation. The reaction sequence provides a potential synthetic tool for the construction of pyrrolotetrahydroisoquinolines.
P. Karjee, M. Mishra, B. Debnath and T. Punniyamurthy, Chem. Commun., 2022, 58, 8670 DOI: 10.1039/D2CC02941C
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