A robust route to a diverse set of 6-aminophenanthridines via palladium-catalyzed C–H activation of N-sulfonyl-2-aminobiaryl and isocyanide insertion is reported. This transformation could also provide an important approach for building core frameworks of conjugated organic polymer materials.
H. Jiang, H. Gao, B. Liu and W. Wu, RSC Adv., 2014, 4, 17222 DOI: 10.1039/C4RA02381A
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