Issue 5, 2014

Palladium-catalyzed direct C–H allylation of arenes without directing groups

Abstract

A palladium-catalyzed direct C–H allylation of simple arenes without directing groups was developed for allyl arene synthesis. The use of bidentate monoanionic nitrogen ligands enabled the progress of initial C–H activation of arenes, as well as the subsequent insertion and β-OAc elimination.

Graphical abstract: Palladium-catalyzed direct C–H allylation of arenes without directing groups

Supplementary files

Article information

Article type
Research Article
Submitted
29 Mar 2014
Accepted
27 Apr 2014
First published
28 Apr 2014

Org. Chem. Front., 2014,1, 546-550

Palladium-catalyzed direct C–H allylation of arenes without directing groups

C. Ying and W. Duan, Org. Chem. Front., 2014, 1, 546 DOI: 10.1039/C4QO00097H

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