Issue 22, 2014

1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(i)/Cu(ii): Cu2I2 building block, anion influence and guest inclusions

Abstract

The reactions of a flexible bidentate ligand 1,3-phenylene diisonicotinate (L) with Cu(I/II) salts afforded coordination polymers with varied dimensionalities and guest inclusion capabilities. Complexation of L with CuI resulted in a 2D-network with (4,4) topology and inclusion of guest molecules such as CHCl3, bromobenzene, nitrobenzene and benzonitrile. The treatment of L with Cu(PF6)2 and Cu(ClO4)2 resulted in a one-dimensional network containing M2L2 macrocycles and a 4-fold interpenetrated three dimensional network having quartz topology, respectively. The 1D-networks included CHCl3 as guests and the interpenetrated 3D-network includes tetrahedral water clusters.

Graphical abstract: 1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(i)/Cu(ii): Cu2I2 building block, anion influence and guest inclusions

Supplementary files

Article information

Article type
Communication
Submitted
17 Jan 2014
Accepted
05 Feb 2014
First published
05 Feb 2014

CrystEngComm, 2014,16, 4701-4705

Author version available

1D, 2D and 3D coordination polymers of 1,3-phenylene diisonicotinate with Cu(I)/Cu(II): Cu2I2 building block, anion influence and guest inclusions

G. Mukherjee and K. Biradha, CrystEngComm, 2014, 16, 4701 DOI: 10.1039/C4CE00123K

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