An aqueous one-pot self-templating synthesis method to prepare highly uniform ZIF-67 hollow spheres (ZIF-67-HS) and their transition metal-doped derivatives (M/ZIF-67-HS, M = Cu and/or Zn) was developed. Extension of this approach to another important class of MOFs (metal carboxylates; e.g., HKUST-1) and facile design of derived nanostructures with complex architectures were also achieved.
Y. Chuan Tan and H. Chun Zeng, Chem. Commun., 2016, 52, 11591 DOI: 10.1039/C6CC05699G
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