Bis(Carbazolyl) Derivatives of Pyrene and Tetrahydropyrene: Synthesis, Structures, Optical Properties, Electrochemistry, and Electroluminescence

Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon NanoTecCenter Weiz Forschungsgesellschaft mbH, Franz-Pichler-Straße 32, A-8160 Weiz, Austria Department of Biology &Chemistry, New Mexico Highlands University, Las-Vegas, NM 87701, USA Department of Natural Sciences, Lebanese American University, Byblos, Lebanon School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, Georgia 30332 Institut für Festkörperphysik, Technische Universität Graz, Petersgasse 16, A-8010 Graz, Austria


Introduction
5][6][7] Efficient charge injection from electrodes into the adjacent organic layers, balanced charge transport, connement of hole-electron recombination and the resultant excitons in the desired emissive layer, and high quantum efficiencies of luminescence are all important factors in achieving efficient devices, which should ideally exhibit low drive voltages and high current and power efficiencies. 8Efficient blue-emitting devices are challenging to fabricate because the large optical and transport gap required for the emitter means that efficient hole and/or electron injection can be hard to achieve at moderate drive voltages, while care also has to be taken to avoid the possibility of exciton energy transfer from the emissive layer to neighboring materials.Blue OLEDs can be obtained by using either uorescent or phosphorescent materials.Although the latter approach can potentially result in much higher quantum efficiency, successful implementation typically involves blending of a heavy-metal phosphorescent "guest" into an organic "host", both the singlet and triplet excited-state energy of which must be larger than that of the "guest", while triplet energy transfer to neighboring layers must be prevented, thus leading to even more challenging issues regarding injection and exciton connement.
Polyaromatic molecules, such as diphenylanthracene, 9 have been studied as potential uorescent blue emitters.Pyrene has a remarkably long uorescence lifetime, 10 yet also exhibits high photoluminescence (PL) efficiency.In addition, it has a strong tendency to form excimers, 11,12 while pyrene excitation spectra are sensitive to microenvironment changes. 13Although pyrene has high charge-carrier mobility and a lower ionization potential than many other efficient blue emitters, for example polyuorenes, facilitating hole injection, pyrene itself is generally unsuitable for use in OLEDs due to its tendency to crystallize. 5Accordingly, a number of functionalized pyrenes have been developed as blue emitters. 14][17] Carbazole-based materials have been widely used as donors in a variety of organic electronic devices and, in general, exhibit hole-transport properties, although hybrids with various acceptor moieties such as oxadiazoles, [18][19][20] and even 4,4 0di(carbazol-9-yl)biphenyl 21 (CBP, compound 2a in Fig. 1), are ambipolar to varying extents.8][29] Although carbazoles typically exhibit irreversible electrochemistry due to dimerization and polymerization of the corresponding radical cations at their 3,6-positions, [30][31][32] blocking of those positions can suppress these reactions; moreover, 3,6-di(tert-butyl) substitution of the carbazole moieties of CBP (to give 2b, Fig. 1) has also been reported to result in a signicantly higher glass-transition temperature. 9iven the uorescent properties of pyrene and the transport properties of carbazoles, combining these two motifs in a single molecule may offer an interesting combination of physical properties and, perhaps, a route to new electroluminescent materials.4][35][36][37] Here, we report the synthesis, characterization, and electroluminescent properties of molecules in which two carbazole or 3,6-di-tert-butylcarbazole moieties are attached through the nitrogen atom to the 2,7 positions of pyrene (4a and 4b, Fig. 1), which, in contrast to previously reported carbazole-pyrene materials, show blue uorescence.We compare the structures, optical and electrochemical properties, orbital structure, and reorganization energies of 4a,b to those of analogous compounds in which the pyrene is replaced with tetrahydropyrene (3a,b), biphenyl (2a,b), or benzene (1a,b).

Photophysical studies
The photophysical studies of compounds 1-4 were performed using 1-5 mM solutions of each compound prepared in different solvents.The procedure involved the measurement of 1-2 mg of each compound in a vial for the preparation of a stock solution (1 mM) in DCM.Dilutions were done in another vial to obtain 100 mM solutions from which 40-200 mL were taken, placed in different vials, and le to dry.Different solvents were then added to each vial (4 mL) to obtain 1-5 mM solutions.A JASCO V-570 UV-NIR spectrophotometer was used for measurements of the absorption spectra, and the uorescence measurements were done using a Jobin-Yvon-Horiba Fluorolog III spectrouorimeter.The excitation source was a 100 W xenon lamp and the slit width was xed at 5 nm for all measurements, while the excitations were done at 330 or 320 nm.In order to nd the uorescence lifetime of compounds (1-4), a Jobin-Yvon-Horiba FluorologIII spectrouorimeter was used with a pulsed diode laser (282 nm).The decay data were analyzed using Data Analysis soware to t decays to single or double exponential with c 2 < 3.

X-Ray structure determination
X-ray diffraction experiments were carried out with a Bruker SMART APEX II CCD diffractometer, using Mo Ka radiation (l ¼ 0.71073 Å) at 100 K; details of the solution and renement and given in Table S1 (ESI †), while cif les are available from the Cambridge Crystallographic Data Center where the crystal structures of 1a, 2b, 3a, and 4b have been deposited and allocated the deposition numbers CCDC 899423, 899424, 899425, and 899426, respectively.The raw data frames were integrated with the SAINT+ program using narrow-frame algorithm. 45bsorption corrections were applied using the semi-empirical method of the SADABS program. 46The structures were solved by direct methods and rened using the Bruker SHELXTL programs suite 47 by full-matrix least-squares methods on F 2 with SHELXL-97 in anisotropic approximation for all nonhydrogen atoms.Compound 1a was found to crystallize in the orthorhombic space group Pbca, with an entire molecule in the asymmetric unit, whereas crystals of 2b, 3a, and 4b belong to the monoclinic space group P2 1 /c with half of the molecule in the asymmetric unit.In 2b disorder was modeled for the bridging six-membered ring over two positions with partial occupancies of 0.53(3) and 0.47 (3).In 3a disorder was modeled for the C sp 3 atoms in the tetrahydropyrene core over two positions with partial occupancies of 0.63(8) and 0.37 (8).All H atoms were placed in idealized positions and rened with constrained C-H distances and U iso (H) values set to 1.2U eq or 1.5U eq (for methyl group) of the attached C atom.

Organic light-emitting devices and electroluminescencemeasurements
Devices were fabricated using a standard sandwich assembly to investigate these new materials as the active layer in OLEDs: indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene)-polystyrenesulfonic acid (Baytron P VPAI 4083) (PEDOT:PSS)/3a, 3b, 4a, 4b/1,3,5-tris(1-phenyl-1H-2-benzimidazole) (TPBi)/Ca/Al.ITO-covered glass substrates were mechanically cleaned by the use of acetone and isopropyl alcohol.Aerwards the substrates were subjected to various supersonic treatments in deionized water, toluene, and isopropanol.A dry cleaning step in oxygen plasma nished the cleaning procedure.On top of the ITOsubstrates a layer of PEDOT:PSS was applied via spin-coating under ambient conditions and dried under dynamic vacuum according to the specications.Layers of 3a and 4a with a thickness of 80 nm were evaporated at an evaporation rate of 0.5 Å s À1 from a resistively heated crucible under dynamic vacuum in an evaporation chamber having an initial base pressure <1.0 Â 10 À6 mbar.Film thicknesses were monitored using a quartz-crystal microbalance.Compounds 3b and 4b were spin-coated from 5 mg mL À1 THF solutions in inert atmosphere and dried at 80 C for 2 h in vacuum.The resulting layer thickness amounted to 75 nm.The cathode materials (TPBi, Ca, Al) were deposited in an evaporation chamber under high vacuum (p < 1.0 Â 10 À6 mbar).TPBi (10 nm) was evaporated uniformly onto the substrate as an electron transport layer, Ca (10 nm) and Al (100 nm) were deposited through a shadow mask thus forming multiple devices with a device-area of 9 mm 2 on a single substrate.Electroluminescence (EL) spectra were acquired using an ORIEL spectrometer with an attached calibrated charge-coupled device (CCD) camera.Current-luminance-voltage (I-L-V) characteristics were recorded in a customized setup using a Keithley 2612A source measure unit for recording the I-V characteristics while the luminance was measured by a Keithley 6485 Picoammeter using a photodiode calibrated by a Konica-Minolta LS-100 Luminancemeter.

Quantum-chemical studies
The ground states and radical-cation states of 1b-4b were calculated at the density functional theory (DFT) level by employing the global hybrid B3LYP functional [48][49][50][51] in conjunction with a 6-31G(d,p) basis set. 52,53The low-lying singlet excited states were evaluated using the neutral ground-state geometries via time-dependent density functional theory (TDDFT) with the B3LYP functional and the same basis set.All calculations were performed using the Gaussian09 (Revision A.02) soware suite. 54
The Ullmann approach requires stoichiometric quantities of copper reagent and, typically, high temperatures (>200 C) and long reaction times, and oen gives only moderate yields; an alternative is the Buchwald-Hartwig palladium-catalyzed C-N coupling reaction. 58,59We obtained 3 and 4 in moderate to good yield from reaction of the appropriate dibromopyrene and carbazole derivatives (Scheme 2), using the tris(dibenzylideneacetone)dipalladium(0)/tri-tert-butylphosphine catalyst system, as described for N-arylation of carbazole in ref. 60, but using microwave irradiation to accelerate the reaction (with a maximum temperature of 125 C, run time of 2 min, hold time of 60 min, pressure of 120 psi, and power of 180 W).
In the "gas-phase" DFT calculations, the biphenyl unit of 2b is characterized by a twist angle of 37 , the CH 2 CH 2 "bridges" of 3b lead to a lower twist of 17 , while only in the pyrene derivative 4b do the "CH]CH" bridges lead to complete planarization of the biphenyl portion of the bridge.Molecules of 2b, 3a, and 4b are located on crystallographic inversion centers in their crystals, meaning that the biphenyl portions of the bridging moieties are apparently planar, as is the case in the previously reported structure of 2a, 61 although this is likely an artifact of disorder, as in the case of biphenyl itself, 62 precluding a meaningful comparison of experimental and DFT bridge geometries.In both the crystallographically determined and DFT structures, the carbazole moieties are signicantly twisted from coplanarity with the adjacent bridging group, consistent with the expected effects of steric interactions and with other structures of N-aryl carbazole derivatives; however, in the calculated structures, the angles between these two planes are all close to 53 , while there is considerable variation in the angles found in the crystal structures (see Table S2 †).4][65][66] These geometric differences may indicate relatively shallow potential energy surfaces with respect to these distortions so that minor crystal packing effects can lead to variations.
On the other hand, there is good general agreement between crystallographically determined and calculated bond lengths, suggesting that DFT describes the electronic structure of these molecules well (see below).For example, the bridging N(carbazole)-C(aryl bridge) bonds are in the range of 1.422(4)-1.428(4)Å (1.417-1.4194][65][66][67] The C-C bond lengths of the DFT and X-ray structures follow similar patterns.Notably, the calculations indicate that the central C-C bond of the biphenyl portion of the bridge shortens from biphenyl (1.483 Å) to tetrahydropyrene (1.473 Å) to pyrene (1.424 Å), consistent (allowing for the low precision of the 2b structure) with the trends in the corresponding crystallographic bond lengths (1.489(2), 1.464( 12), 1.470(4), and 1.422(3) Å for 2a, 61 2b, 3a, and 4b, respectively).While the small difference in the C-C bond lengths of the tetrahydropyrene and biphenyl bridges likely reects constraints imposed by the CH 2 CH 2 groups, the much shorter central bond in the pyrene system indicates that there is a signicant change in electronic structure of the bridge (see below for a discussion of the molecular orbitals) and that the simplistic representation of pyrene as a biphenyl moiety planarized by CH]CH groups is inadequate.

Absorption and uorescence studies
Fig. 3a and b show the absorption and uorescence spectra respectively of the carbazole and 3,6-di-tert-butylcarbazole derivatives (1-4) in DMF (see ESI † for spectra acquired in different solvents).In all cases, the absorption spectra showed a common sharp peak at around 295 nm and broader weaker features in the range 310-340 nm.In the case of 2a, these have been described as carbazole-localized transitions and transitions between more extensively delocalized p and p* orbitals, respectively 68 although carbazole itself also shows a weak transition at ca. 330 nm in addition to a strong absorption at ca. 290 nm. 69The absorption maxima, emission maxima, and Stokes shi of each compound are summarized in Table 1.3,6tert-Butyl substitution of the carbazole moieties results in small red-shis in absorption (ca.0-80 meV) and uorescence (ca.70-135 meV) maxima compared to their unsubstituted analogues, consistent with a previous comparison of 2a and 2b. 9 The pyrene derivatives have the lowest energy emission maxima (429 Fig. 2 ORTEP plots of 1a (a), 2b (b), 3a (c), and 4b (d) with the numbering scheme in projection on the best plane.In the cases of 2b and 3a, where conformational disorder was found, only the major conformation is shown.Thermal ellipsoids are shown with 50% probability level.Hydrogen atoms are drawn as circles of arbitrary small radii for clarity.and 450 nm for 4a and 4b, respectively) and exhibit the greatest Stokes shis (between the lowest energy observed absorption maximum and the uorescence maximum) of any of the compounds examined, although another weaker emission feature is present at ca. 380-390 nm; as discussed below, this is consistent with the lowest energy absorption maximum not corresponding to S 0 / S 1 in the pyrene compounds.
Table 2 provides the vertical transition energies (and wavelengths), transition dipoles, and electronic congurations of the lowest-lying excited states with appreciable oscillator strength as determined at the TDDFT B3LYP/6-31G(d,p) level of theory.The calculated maxima, though slightly red-shied with respect to experiment, 70 agree well with the empirical trends.For 1b through 3b, the rst vertical transition with appreciable oscillator strength is the S 0 / S 1 transition; in each case these are well-described as HOMO / LUMO excitations (although in 1b, the HOMO / LUMO+2 excitation also contributes to the transition).Depictions of the molecular orbitals involved in the transitions are located in the ESI; † in the case of 1b, the HOMO and LUMO are fully delocalized across both carbazole units and the central phenylene bridge.In the case of 2b and 3b, the HOMO has a similar delocalized character, while the LUMO is mainly localized on the central biphenyl portion with only modest extension on the carbazole (consistent with previous reports of the frontier orbitals of 2a and 2b 9 ).Thus, the lowestlying transitions are indeed well-described as p-p* transitions, as previously suggested for 2a, 68 although they have signicant carbazole-to-bridge charge-transfer character.
The picture differs for 4b, where the S 0 / S 1 transition, which largely corresponds to excitation from a carbazole-localized HOMO to a pyrene-localized LUMO (Fig. 4), has negligible transition dipole.This pyrene-localized LUMO has very little wavefunction distribution, as expected, on the 2-and 7-positions that connect the carbazole end groups to the pyrene center in direct contrast with the phenyl (1b) and biphenyl(-like) bridges (2b and 3b) of the other systemstherefore limiting the wavefunction overlap of the ground and excited states.Consistent with the small transition dipole moments linking these states, the uorescence lifetimes of 4a and 4b are longer than those observed for the other compounds in most solvents (see Table 2 and ESI †).Two higher-lying transitions (S 0 / S 5 and S 0 / S 7 ) with mixed HOMO / LUMO+1 and HOMO-4 / LUMO character are the rst transitions with any appreciable transition dipole; they presumably correspond to the lowestenergy experimentally observed absorption maximum.Assuming the main observed emission peak to be the S 0 / S 1 emission, the large Stokes shis seen for 4a and 4b are,   therefore, easily understood (the small emission peak at ca. 370-380 nm perhaps occurring from one of the higher lying states with more signicant coupling to the ground state).The LUMO+1 is mainly pyrene-localized, closely resembling the LUMO+1 of an isolated pyrene, 56,71-80 while the HOMO-4 is located on the pyrene unit and corresponds with the HOMO of pyrene itself (see Fig. 4).The most important contributor to S 0 / S 5 is the HOMO / LUMO+1 excitation, indicating that this transition has signicant quadrupolar carbazole-to-pyrene charge-transfer character and some similarity to S 0 / S 1 for the other compounds.The HOMO-4 / LUMO excitation is the most important contributor to the S 0 / S 7 transition; this transition is primarily a pyrene-localized transition, closely corresponding to the S 0 / S 2 transition of pyrene. 56luorescence quantum yields of 1-4 were determined in different solvents (Table S5 †).It was observed that solvent polarity affected the overall uorescence quantum yield.In general, higher uorescence quantum yields were observed in non-polar solvents (i.e.cyclohexane and hexane) and mediumpolarity solvents (i.e.DCM and THF), while lower uorescence quantum yields were recorded in polar solvents such as acetonitrile, methanol and ethanol.Solvent dependence was also manifested in the uorescence lifetime (s f ). 81Data for the eight carbazole derivatives were t to mono-or biexponential decays.Generally, there was no clear trend among the lifetime values in different solvents.However, the lowest lifetime (s 1 or s avg ) was obtained in hexane for compounds 1a, 2a, 2b, 3a, 3b, 4a, 4b, while 1b was an exception with the lowest s avg value being found in ethanol (see ESI †).Importantly, the recorded lifetimes for compounds 1(a,b), 2(a,b), 3(a,b) were less than 10 ns, while the pyrene-based compounds (4a and 4b) exhibited higher lifetimes in most solvents with values up to 22 ns.Nonetheless, these lifetimes fall considerably short of those found for pyrene itself (ca.400 ns). 82It should be noted that despite the small calculated S 0 / S 1 transition dipoles and the long uorescence lifetimes for 4a and 4b, the solution uorescence quantum yields are still moderately large (up to 56%, see Table S5 †) and comparable to those found for 1-3.The observed biexponential decays for some compounds (1a only in methanol, 1b (except in acetonitrile), 3b and 4b in all the solvents) may be attributed to various origins of the radiative transitions such as intramolecular twisting in the excited state or charge transfer states. 83The radiative (k r ) and non-radiative (k nr ) rate constants of 1-4 in various solvents are summarized in Table S6.†

Redox properties
The solution electrochemistry of 1a-4a and 1b-4b was investigated using cyclic voltammetry (CV) using 0.1 M n Bu 4 NPF 6 in dichloromethane as electrolyte.1][32] In contrast, 1b-4b all undergo two sequential reversible oxidation processes indicating that these coupling reactions are effectively suppressed; this qualitative difference is shown for the example of 4a vs. 4b in Fig. 5, while the other CVs are shown in the ESI.† Although irreversible oxidations are observed for many carbazoles with useful solidstate hole-transport properties, such as PVK 84 and 2a, 61 reversible electrochemistry might be expected to lead to more stable device behavior due to fewer decomposition reactions of the charge-carrying species.
The rst oxidation potentials, E +/0 1/2 , of the reversibly oxidized tert-butyl derivatives 1b-4b materials vary by only ca.0.1 V within the series; DFT-calculated values of ionization potential (IP) also show relatively minor variation.For 2b, 3b, and 4b, the minor variations in the DFT DSCF estimates of gas-phase vertical and adiabatic IPs, or of the IPs according to Koopmans' theorem, correlate very well with those in E +/0 1/2 ; the correlation is  less good for 1b; as in the previously reported (more pronounced) discrepancy between trends in gas-phase IP values and electrochemical potentials for bis(dimethylamino)benzene, biphenyl, and tolane derivatives, this is likely to be due to a greater solvation effect on the electrochemical potentials for the species with the smaller bridge. 85The similarity of redox potentials and calculated IPs within the series is consistent with the largely carbazole-localized nature of the HOMO in all cases, while some of the variation can be attributed to the varying bridge contributions; in particular, 4b is signicantly less readily ionized than 3b owing to the destabilizing interaction of the carbazole and bridge-based orbitals in the latter system, while there is barely any pyrene contribution to the HOMO of 4b.
In the case of the reversibly oxidized 3,6-di(tert-butyl)carbazole derivatives, 1b-4b, differential pulse voltammetry (DPV) 86 was also used to better separate the two oxidation features and better determine the separation DE 1/2 ¼ E 2+/+ 1/2 À E +/0 1/2 .As shown in Fig. 6 and Table 3, there is considerable variation in the separation between the two oxidations.The largest separation is seen for 1b; this is expected given the shorter bridge between the two carbazole redox centers (for example, greater values of DE 1/2 are seen for bis(di-p-anisylamino)benzene and bis(dimethylamino)benzene than for their respective biphenyl-bridged analogues), 85,87 which gives rise to increased delocalization, and, in the case of a class-II monocation, increased electrostatic interactions, stabilizing the monocation.The variation between the remaining compounds shows no clear trend; however, values of DE 1/2 are known to depend on a number of additional factors, 88 some of which are perhaps in competition with one another in the present series.
The solid-state IPs of the compounds were estimated to be in the range 5.4-5.6 eV according to the empirically established approximate relation, IP s ¼ eE +/0 1/2 + 4.8 eV, where e is the electronic charge and where the potential is relative to ferrocenium/ ferrocene.The value of 5.5 eV estimated for 2b is close to a value of 5.7 eV directly measured by UV photoelectron spectroscopy for 2b (and also for 2a). 9,89Estimates of the electron affinity (EA) in the solid state, obtained using the crude approximation, EA s ¼ IP s À E opt g , where E opt g is an estimate of the energy of the rst singlet excited state, are also given in Table 3.In general, this approach will lead to overestimates of EA s due to the effects of exciton binding energy.Moreover, as discussed in the previous section, the onset of strong absorption correspond to the S 0 / S 1 transition for 1b-3b, but S 0 / S 5 for 4b, meaning that this approach is unlikely to even afford meaningful trends in EA s in the present series.Indeed the estimated EA s values are all similar, while the DFT estimate of the EA obtained from Koopmans' theorem for 4b is much larger than that of 2b or 3b (Table 3).The trends in EA KT reect the fact that the p-system of the bridge increases in size from 1b to 2b/3b and then, again, to 4b; in addition, the LUMO in 4b is strongly pyrene localized and less destabilized by contributions from the carbazole portions of the molecule than that of 1b-3b.
The DFT geometries of 1b_ + -4b_ + were examined to gain further insight into the redox properties of these species.In principle, cations such as these might be either class-II (unsymmetrical with charge largely localized around one of the nitrogen atoms) or III (delocalized) mixed-valence species. 90Electron self-interaction errors in DFT oen leads to articially delocalized solutions; 91 therefore, while delocalized class-III structures are obtained from the DFT calculations and this result is similar to Table 3 Oxidation potentials of 3,6-di-tert-butylcarbazole derivatives vs. ferrocenium/ferrocene in CH 2 Cl 2 -0.1 M n Bu 4 NPF 6 , electrochemically based estimates of ionization potentials and electron affinities, and computational estimates of the gas phase ionization potentials and electron affinities at the B3LYP/6-31G(d,p) level of theory

Cpd
Experiment Theory what is experimentally established for bis(diarylamino)biphenyl radical cations, 92 it is possible that some or all of these radical cations may in fact exhibit localized structures, in which case adiabatic IPs, geometric changes, and reorganization energies will differ somewhat from those given in Table S4.† The largest geometric changes occur in the vicinity of the carbazole-bridge linkages.The N(carbazole)-C(aryl bridge) bonds shorten by 0.01-0.02Å, with the bond length change being largest for the smallest example, 1b.The induced strain of the alkyl linkage in the bridge of 3b induces a slightly larger change to the N-C bond versus the unconstrained biphenyl bridge of 2b, while the N-C bond change is smallest for 4b, where there is relatively little N-C(bridge) antibonding character in the HOMO.A considerable reduction in the torsion angle between the carbazole units and the neighboring aryl rings of the bridge also occurs on oxidation, again with the largest change occurring for 1b (11 reduction), an intermediate change for 3b (9 ), and the smallest for 2b and 4b (ca.6 ).The twist angle between the two benzene rings of the biphenyl ring of 2b also decreases (by 7 ) on oxidation, but does not signicantly change in the case of 3b (where the constraints of the alkyl bridges lead to a lower twist in the neutral geometry, as discussed above).The planarization of the biphenyl bridge of 2b_ + is reminiscent of previously reported computational and crystallographic studies of bis(diarylamino)biphenyl derivatives and their radical cations. 92,93he varying degrees of geometric modications on oxidation lead to notable differences in the neutral/radical cation intramolecular reorganization energy, which, according to Marcus theory, 94 is related to the barrier to hole transport.The smaller 1b, which undergoes the largest changes to the geometric structure on oxidation, has the largest intramolecular reorganization energy (176 meV).The alkyl bond constraints in 3b, interestingly, lead to a considerably larger intramolecular reorganization energy (150 meV) than that found in 2b (112 meV).This difference is qualitatively similar to that between bis(diarylamino)biphenyl and uorene derivatives. 95,96he intramolecular reorganization energy of 4b (90 meV) is the smallest and is comparable with that of the high hole-mobility material pentacene (98 meV). 97All of these intramolecular organization energies are smaller than those estimated for many prototypical hole-transport materials, including TPD (290 meV) 95 and sexithiophene (300 meV). 98

Organic light-emitting devices
To investigate the electroluminescent (EL) properties of compounds 3a, 3b, 4a and 4b, OLEDs were assembled in a standard sandwich geometry: ITO/PEDOT:PSS/[carbazole derivative]/TPBi/Ca/Al; 3a and 4a were deposited by evaporation, while 3b and 4b were spin-cast.1,3,5-Tris(1-phenyl-1H-benzo[d]imidazol-2-yl)benzene (TPBi) is widely used as a hole-blocking/electron-transporting material, 8 and in the current devices was deposited by evaporation to facilitate electron injection into the active layer.All devices give deep blue EL, with maxima in the range 422-435 nm, suggesting that emission occurs primarily from the carbazole-material layer; TPBi lms show a uorescence maximum at 383 nm. 99g. 7 depicts the current density-voltage-luminance (J-V-L) characteristics of devices using 3a and 3b, respectively, as lightemitting layers.The tetrahydropyrene-based OLEDs gave maximum luminance values of 138 cd m À2 at 9 V for 3a and 361 cd m À2 at 10.8 V for 3b.The onset voltages of 5.3 and 5.5 V for 3a and 3b, respectively, are rather high and indicate either imbalanced charge injection or transport within the devices.Consequently the maximum device efficiencies remained low (0.02 and 0.07 cd A À1 for 3a and 3b, respectively).Devices using 3a as the light-emitting layer show an EL peak maximum at 422 nm and a weak shoulder around 375 nm.The spectra correspond to Commission Internationale de l'Eclairage 1931 (CIE1931) coordinates of x ¼ 0.159 and y ¼ 0.046, corresponding to a deep blue emission.For 3b devices, a slightly narrower EL emission peak was observed in a similar region to that seen for 3a devices (EL maximum at 425 nm), but a weak and slightly structured emission is also seen in the red spectral region at around 620 nm; similar EL features in PVK lms have been attributed to electrophosphorescent emission. 100The overall spectrum corresponds to CIE1931 x ¼ 0.193 and y ¼ 0.078, which is slightly red-shied compared to the EL-emission of 3a, but still located in the deep-blue region of the visible spectrum.
Fig. 8 shows the J-V-L characteristics of analogous devices in which 4a and 4b are used as emitters.Maximum luminance values of 1076 cd m À2 were obtained for the 4a device at 7.0 V and 316 cd m À2 at 7.6 V for 4b, respectively.The onset voltages of 4.0 V (4a) and 4.2 V (4b) are somewhat smaller than when tetrahydropyrene-bridged molecules 3a and 3b were used as the active layer, perhaps due to more facile electron injection into the pyrene molecules (see values of EA KT in Table 3).However, the overall device efficiencies of 0.16 cd A À1 for 4a and 0.04 cd A À1 for 4b still remain low and can again be attributed to an unbalanced charge-carrier transport in the active materials.The EL-spectra in the inset of Fig. 8 show a broad and slightly structured EL emission peak for compound 4a in the range 410-570 nm with its maximum at 435 nm and a distinct shoulder around 455 nm.The spectrum corresponds to CIE1931 coordinates x ¼ 0.151 and y ¼ 0.092 (deep blue).For compound 4b a narrow and structureless molecular emission peak between 410 nm and 525 nm, peaking at 435 nm, can be observed, resulting in x ¼ 0.156 and y ¼ 0.044 (CIE1931), at the far blue end of the visible spectrum.None of the reported devices exhibited any sign of excimer emission.
The device work demonstrates that the tetrahydropyrene and pyrene-bridged compounds are in principle suitable emitting materials for deep-blue OLEDs.While the brightnesses and efficiencies are low compared to state-of-the-art multilayer electrophosphorescent devices employing iridium-based emitters, 101,102 some of present devices compare reasonably well to blue electrouorescent devices with comparably simple device architectures, such as devices recently reported based on dendronized or polymerized pyrene derivatives; [15][16][17] for example a single-layer blue-turquoise device based on a polypyrene was reported to exhibit a peak luminance of 300 cd m À2 at 8 V and a maximum efficiency of ca.0.3 cd A À1 .It is anticipated that more efficient OLEDs may be obtained by introduction of additional transport layers on the anode side to ensure a more balanced charge injection. 103

Conclusion
Tetrahydropyrene derivatives 3a,b show similar absorption and emission spectra to their biphenyl analogues, 2a and 2b.The pyrene derivatives 4a,b show qualitatively different behavior: DFT calculations indicate signicant differences in the key frontier orbitals and that the lowest-lying strong absorption is no longer S 0 / S 1 , the emission is considerably red-shied relative to that of the other compounds, and the uorescence lifetimes are generally longer.All of the tert-butyl-substituted compounds studied have reversible electrochemistry, the rst oxidation potential showing only minor variations with the bridging group.DFT calculations indicate signicant variation in the reorganization energy for hole-transfer between biphenyl, tetrahydropyrene, and pyrene derivatives, with the smallest values being found for the pyrene materials.Both tetrahydropyrene and pyrene derivatives have been used as blue uorescent emitters in simple OLED architectures; lower turn-on voltages for the pyrene materials may be related to more facile electron injection from the electron-transporting layer.These molecules may also have applications as hole-transporting materials and perhaps as hosts for green phosphors in OLEDs.

Fig. 1
Fig. 1 Compounds studied in this work.

Fig. 4
Fig. 4 Illustrations of the frontier molecular orbitals and molecular orbital energies of 3b and 4b evaluated at the B3LYP/6-31 G(d,p) level.

Table 1
Absorption and emission data for 1-4 in DMF a a Optical data in other solvents are presented in TablesS5 and S6in the ESI.b Fluorescence quantum yield.c Fluorescence lifetime.d Biexponential t; the relative contribution of the two components is also indicated.

Table 2 Time
-dependent DFT (TDDFT) determination of selected vertical transition energies (E vert , eV), wavelengths (l vert , nm), transition dipole moments (m ge , Debye), and electronic configurations as determined at the B3LYP/6-31G(d,p) level of theory Potentials obtained from the DPV measurements.b Onset of optical absorption.c Estimated solid-state IP obtained according to IP ¼ eE +/0 1/2 + 4.8 eV.d Estimated of the solid-state IP obtained according to EA ¼ IP À E opt g ; see text for caveats.e DSCF values of vertical and adiabatic ionization energies for isolated molecules.f DFT gas-phase values estimated using Koopmans' theorem, i.e.IP KT ¼ ÀE HOMO and EA KT ¼ ÀE LUMO . a