Issue 11, 2013
From the journal:

New Journal of Chemistry

Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes†

Rémy Sylvain,a   Laure Vendier,a   Christian Bijani,a   Antonio Santoro,b   Fausto Puntoriero,b   Sebastiano Campagna,*b   Pierre Sutraa  and  Alain Igau*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, CNRS 205 route de Narbonne, 31077 Toulouse, France
E-mail: alain.igau@lcc-toulouse.fr
Fax: +33 5 61 55 30 03
Tel: +33 5 61 33 31 59

b Dipartimento di Scienze Chimiche, University of Messina, Via F. Stagno d'Alcontres 31, I-98166 Messina, Italy
E-mail: campagna@unime.it
Fax: +39-090-393756
Tel: +39-090-6765737

Abstract

We evidenced the conversion of an unprecedented intermolecular bridged-proton bimetallic P-metallated phosphoryl complex [{[Ru](Ph2P[double bond, length as m-dash]O)}2H][PF6]3 to its corresponding H-bonded water complex [{[Ru](Ph2P[double bond, length as m-dash]O)}2(H2O)][PF6]2, a rare motif. Their synthesis, NMR data, X-ray crystal structures, electrochemical and photophysical properties are reported.

Graphical abstract: Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

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Article information

DOI
https://doi.org/10.1039/C3NJ00522D
Article type
Paper
Submitted
17 May 2013
Accepted
08 Aug 2013
First published
08 Aug 2013

New J. Chem., 2013,37, 3543-3548

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Evidence of the unprecedented conversion of intermolecular proton to water bridging of two phosphoryl ruthenium complexes

R. Sylvain, L. Vendier, C. Bijani, A. Santoro, F. Puntoriero, S. Campagna, P. Sutra and A. Igau, New J. Chem., 2013, 37, 3543 DOI: 10.1039/C3NJ00522D

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