Issue 42, 2024

Flexible intelligent electromagnetic shielding polymer composites with sensitive on/off switching and high absorption

Abstract

The development of absorption-oriented intelligent switchable electromagnetic shielding materials has presented a promising solution for combining data transmission and electromagnetic shielding, and effectively reducing the secondary pollution caused by electromagnetic waves. However, it remains a challenge to achieve high electromagnetic interference shielding effectiveness (EMI SE) and a great absorption coefficient while adapting to certain deformations. Herein, a nickel-plated silicon carbide whisker (Ni@SiCw) is introduced to enhance the absorption properties through electroless plating under dielectric loss and magnetic loss. Ni@SiCw/polyurethane (TPU) is prepared by solution blending and hot pressing. Additionally, silver nanowires (AgNWs)/TPU layers are fabricated by electrospinning and vacuum-assisted filtration. The Ni@SiCw/TPU layer is then bonded with the AgNWs/TPU layer using waterborne polyurethane, fabricating a composite material with an electromagnetic isolation structure. This structure adopts the absorption–reflection–reabsorption shielding mechanism, which allows the composite material to achieve both great EMI SE (49.87 dB) and A (0.72). Furthermore, the material demonstrates the ability to switch the electromagnetic shielding efficiency (15.97–45.92 dB) within a range of 30% strain deformation. Moreover, after 200 tensile cycles, there is no significant decline in its electromagnetic shielding performance, which provides a reference strategy for the development of intelligent electromagnetic shielding materials.

Graphical abstract: Flexible intelligent electromagnetic shielding polymer composites with sensitive on/off switching and high absorption

Supplementary files

Article information

Article type
Paper
Submitted
04 Jul 2024
Accepted
18 Sep 2024
First published
07 Oct 2024

J. Mater. Chem. A, 2024,12, 29211-29221

Flexible intelligent electromagnetic shielding polymer composites with sensitive on/off switching and high absorption

B. Wu, P. Wu, Y. Yu, Y. Wu, X. Song, D. Zhou and Y. Li, J. Mater. Chem. A, 2024, 12, 29211 DOI: 10.1039/D4TA04627G

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