A stable porous Ag(I)-MOF with new topology is constructed from AgSbF6 and 3,6-bis[2-(4-oxide-quinoxaline)-yl]-4,5-diaza-3,5-octadiene (L). This compound can be a highly selective porous MOF material to effectively separate benzene from its six-membered cyclic organic analogues such as cyclohexane, cyclohexene and o-, m-, p-xylene under ambient conditions in both vapor and liquid phases.
J. Cheng, P. Wang, J. Ma, Q. Liu and Y. Dong, Chem. Commun., 2014, 50, 13672 DOI: 10.1039/C4CC03204G
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