Issue 33, 2012

Ti(iii)-Catalyzed, concise synthesis of marine furanospongian diterpenes

Abstract

A bioinspired procedure for the straightforward synthesis of marine furanospongian diterpenes is described. The key step is the titanocene(III)-catalyzed radical cascade cyclization of the suitable epoxy-polyprene.

Graphical abstract: Ti(iii)-Catalyzed, concise synthesis of marine furanospongian diterpenes

Supplementary files

Article information

Article type
Paper
Submitted
25 Sep 2012
Accepted
25 Oct 2012
First published
26 Oct 2012

RSC Adv., 2012,2, 12922-12925

Ti(III)-Catalyzed, concise synthesis of marine furanospongian diterpenes

A. Rosales, J. Muñoz-Bascón, V. Manuel Morales-Alcázar, J. A. Castilla-Alcalá and J. Enrique Oltra, RSC Adv., 2012, 2, 12922 DOI: 10.1039/C2RA22281G

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