Issue 4, 2012
From the journal:

RSC Advances

Dynamic emission quenching of a novel ruthenium(ii) complex by carbon dioxide in solution

Eri Sakuda,*a   Mai Tanaka,b   Akitaka Itoa  and  Noboru Kitamura*ab  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Japan
E-mail: kitamura@sci.hokudai.ac.jp
Fax: +81-11-706-4630
Tel: +81-11-706-2697

b Department of Chemical Sciences and Engineering, Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Japan
E-mail: kitamura@sci.hokudai.ac.jp
Fax: +81-11-706-4630
Tel: +81-11-706-2697

Abstract

Emission from the tris(1,10-phenanthroline)ruthenium(II) complex (Ru(phen)32+) bearing a (dimesityl)boryldurylethynyl (DBDE) charge transfer unit at the 4-position of one of the three phen ligands ([Ru(phen)2(4-DBDE-phen)] = 4BRu2+) was quenched by carbon dioxide in solution with the rate constant of ∼106 M−1 s−1.

Graphical abstract: Dynamic emission quenching of a novel ruthenium(ii) complex by carbon dioxide in solution

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Article information

DOI
https://doi.org/10.1039/C2RA00268J
Article type
Communication
Submitted
03 Jun 2011
Accepted
24 Nov 2011
First published
22 Dec 2011

RSC Adv., 2012,2, 1296-1298

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Dynamic emission quenching of a novel ruthenium(II) complex by carbon dioxide in solution

E. Sakuda, M. Tanaka, A. Ito and N. Kitamura, RSC Adv., 2012, 2, 1296 DOI: 10.1039/C2RA00268J

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