Issue 85, 2012
From the journal:

Chemical Communications

A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct†

Kaustuv Mittra,a   Sudipta Chatterjee,a   Subhra Samanta,a   Kushal Sengupta,a   Hridaynath Bhattacharjeea  and  Abhishek Dey*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, India
E-mail: icad@iacs.res.in
Fax: +91-33-2473 2805
Tel: +91-33-2473 4971

Abstract

A hydrogen bonded heme-FeIII–O2− adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O–O vibrations of this complex are quite different from those reported for other heme-FeIII–O2− adducts.

Graphical abstract: A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

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Article information

DOI
https://doi.org/10.1039/C2CC35162E
Article type
Communication
Submitted
18 Jul 2012
Accepted
30 Aug 2012
First published
31 Aug 2012

Chem. Commun., 2012,48, 10535-10537

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A hydrogen bond scaffold supported synthetic heme FeIII–O2− adduct

K. Mittra, S. Chatterjee, S. Samanta, K. Sengupta, H. Bhattacharjee and A. Dey, Chem. Commun., 2012, 48, 10535 DOI: 10.1039/C2CC35162E

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