Issue 36, 2012
From the journal:

Chemical Communications

Electrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin†‡

Shin-ichi Yamazaki,*a   Masaru Yao,a   Naoko Fujiwara,a   Zyun Siroma,a   Kazuaki Yasudaa  and  Tsutomu Ioroia  

* Corresponding authors

a Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan
E-mail: s-yamazaki@aist.go.jp
Fax: +81-72-751-9629

Abstract

A Rh porphyrin on carbon black was shown to catalyze the electro-oxidation of several aliphatic alcohols (ethanol, 1-propanol, and 2-propanol) and benzyl alcohols. The overpotentials for alcohol oxidation were very low. The reaction mechanism and substrate specificity are discussed.

Graphical abstract: Electrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC30888F
Article type
Communication
Submitted
08 Feb 2012
Accepted
09 Mar 2012
First published
09 Mar 2012

Chem. Commun., 2012,48, 4353-4355

Permissions

Request permissions

Electrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin

S. Yamazaki, M. Yao, N. Fujiwara, Z. Siroma, K. Yasuda and T. Ioroi, Chem. Commun., 2012, 48, 4353 DOI: 10.1039/C2CC30888F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements