Unsupported d8–d8 interactions in cationic PdII and PtII complexes: evidence for a significant metal–metal bonding character

Jia Luo; Julia R. Khusnutdinova; Nigam P. Rath; Liviu M. Mirica

doi:10.1039/C1CC15420F

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Unsupported d⁸–d⁸ interactions in cationic Pd^II and Pt^II complexes: evidence for a significant metal–metal bonding character†‡

Jia Luo,^a Julia R. Khusnutdinova,^a Nigam P. Rath^b and Liviu M. Mirica*^a

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* Corresponding authors

^a Department of Chemistry, Washington University, St. Louis, Missouri, USA
E-mail: mirica@wustl.edu

^b Department of Chemistry and Biochemistry, University of Missouri–St. Louis, St. Louis, Missouri, USA

Abstract

Isostructural dinuclear Pd and Pt complexes that exhibit unique d⁸–d⁸ interactions between dicationic metal centers are reported. These metal–metal interactions are not supported by any bridging ligands and suggest a significant metal–metal bonding character for both Pd and Pt systems.

This article is part of the themed collection: Emerging Investigators 2012

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Article information

DOI: https://doi.org/10.1039/C1CC15420F
Article type: Communication
Submitted: 31 Aug 2011
Accepted: 09 Oct 2011
First published: 25 Oct 2011

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Chem. Commun., 2012,48, 1532-1534

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Unsupported d⁸–d⁸ interactions in cationic Pd^II and Pt^II complexes: evidence for a significant metal–metal bonding character

J. Luo, J. R. Khusnutdinova, N. P. Rath and L. M. Mirica, Chem. Commun., 2012, 48, 1532 DOI: 10.1039/C1CC15420F

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