A vinylene-linked porphyrin covalent organic framework for efficient sunlight-driven photocatalytic organic transformations

Abstract

A vinylene-linked porphyrin-based COF was synthesized via aldol condensation reaction. This COF demonstrates prominent exciton dissociation and charge transfer, exhibiting exceptional photoactivity in the photooxidation of sulfides and oxidative coupling of benzylamines under sunlight irradiation.

Graphical abstract: A vinylene-linked porphyrin covalent organic framework for efficient sunlight-driven photocatalytic organic transformations

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2025
Accepted
23 Nov 2025
First published
27 Nov 2025

Chem. Commun., 2026, Advance Article

A vinylene-linked porphyrin covalent organic framework for efficient sunlight-driven photocatalytic organic transformations

X. Zhang, J. Kan, Y. Dong, F. Yang, Q. Liu and C. Liu, Chem. Commun., 2026, Advance Article , DOI: 10.1039/D5CC05728K

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