Issue 1, 2011
From the journal:

CrystEngComm

Novel quadridentate salen type triple-decker sandwich ytterbium complexes with near infrared luminescence†‡

Peng-Fei Yan,a   Shuo Chen,a   Peng Chen,a   Ju-Wen Zhanga  and  Guang-Ming Li*a  

* Corresponding authors

a Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, No. 74, Xuefu Road, Nangang District, Harbin, P. R. China
E-mail: gmli_2000@163.com

Abstract

Unique quadridentate salen type triple-decker dinuclear sandwich ytterbium complex [Yb2L3(CH3OH)]·0.5H2O (1) and triple-decker trinuclear sandwich ytterbium complex [Yb3L3(CH3OH)2(NO3)3]·CH3OH·5H2O (2) are isolated from the reactions of Yb(OAc)3·4H2O and Yb(NO3)3·6H2O with H2L, respectively (H2L = N,N′-bis(salicylidene)-1,2-(phenylene-diamine)). Complex 2 could be harvested from the addition of complex 1 and Yb(NO3)3·6H2O. Near infrared (NIR) lanthanide luminescence and the lifetime of complexes 1 and 2 are conducted and described.

Graphical abstract: Novel quadridentate salen type triple-decker sandwich ytterbium complexes with near infrared luminescence

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Article information

DOI
https://doi.org/10.1039/C0CE00553C
Article type
Communication
Submitted
20 Aug 2010
Accepted
08 Oct 2010
First published
26 Oct 2010

CrystEngComm, 2011,13, 36-39

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Novel quadridentate salen type triple-decker sandwich ytterbium complexes with near infrared luminescence

P. Yan, S. Chen, P. Chen, J. Zhang and G. Li, CrystEngComm, 2011, 13, 36 DOI: 10.1039/C0CE00553C

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