Issue 45, 2011
From the journal:

Chemical Communications

Synthesis of two-dimensional phenylene–boroxine networks through in vacuo condensation and on-surface radical addition†‡

Stefan Schlögl,ab   Thomas Sirtl,ab   Johanna Eichhorn,ab   Wolfgang M. Hecklabc  and  Markus Lackinger*abc  

* Corresponding authors

a Department of Physics & TUM School of Education, Tech. Univ. Munich, Schellingstrasse 33, 80333 Munich, Germany
E-mail: markus@lackinger.org
Tel: +49 89 2179 605

b Deutsches Museum, Museumsinsel 1, 80538 Munich, Germany

c Center for NanoScience (CeNS), Schellingstrasse 4, 80799 Munich, Germany

Abstract

We report on covalent two-dimensional phenylene–boroxine hybrid-networks that were synthesized under ultra-high vacuum conditions from doubly functionalized monomers through thermally activated condensation prior to deposition and successive heterogeneously catalyzed radical addition on Ag(111). Structural properties were characterized in situ by high resolution Scanning-Tunneling-Microscopy (STM).

Graphical abstract: Synthesis of two-dimensional phenylene–boroxine networks through in vacuo condensation and on-surface radical addition

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Article information

DOI
https://doi.org/10.1039/C1CC13896K
Article type
Communication
Submitted
30 Jun 2011
Accepted
10 Oct 2011
First published
19 Oct 2011

Chem. Commun., 2011,47, 12355-12357

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Synthesis of two-dimensional phenylene–boroxine networks through in vacuo condensation and on-surface radical addition

S. Schlögl, T. Sirtl, J. Eichhorn, W. M. Heckl and M. Lackinger, Chem. Commun., 2011, 47, 12355 DOI: 10.1039/C1CC13896K

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