Issue 37, 2011
From the journal:

Chemical Communications

Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands†‡

Alison N. Campbell,a   Eric B. Meyera  and  Shannon S. Stahl*a  

* Corresponding authors

a Department of Chemistry, University of Wisconsin—Madison, 1101 University Avenue, Madison, Wisconsin 53706, U.S.A
E-mail: stahl@chem.wisc.edu
Fax: 1 608 262 6143
Tel: 1 608 265 6288

Abstract

Palladium-catalyzed aerobic oxidative cross-couplings of indoles and benzene have been achieved by using 4,5-diazafluorene derivatives as ancillary ligands. Proper choice of the neutral and anionic ligands enables control over the reaction regioselectivity.

Graphical abstract: Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands

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Article information

DOI
https://doi.org/10.1039/C1CC13632A
Article type
Communication
Submitted
18 Jun 2011
Accepted
25 Jul 2011
First published
22 Aug 2011

Chem. Commun., 2011,47, 10257-10259

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Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands

A. N. Campbell, E. B. Meyer and S. S. Stahl, Chem. Commun., 2011, 47, 10257 DOI: 10.1039/C1CC13632A

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