Issue 1, 2011
From the journal:

Chemical Communications

Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron†‡

Steven B. Thorpe,a   Xi Guoa  and  Webster L. Santos*a  

* Corresponding authors

a Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, USA
E-mail: santosw@vt.edu
Fax: +1 540 231 3255
Tel: +1 540 231 5041

Abstract

A mild and efficient copper-catalyzed borylation of electron deficient allenoates using an sp2–sp3 mixed hybridized diboron regioselectively installs a boron moiety on the β-position with exclusive (Z)-double bond geometry.

Graphical abstract: Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

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Article information

DOI
https://doi.org/10.1039/C0CC02270E
Article type
Communication
Submitted
30 Jun 2010
Accepted
03 Sep 2010
First published
20 Sep 2010

Chem. Commun., 2011,47, 424-426

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Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron

S. B. Thorpe, X. Guo and W. L. Santos, Chem. Commun., 2011, 47, 424 DOI: 10.1039/C0CC02270E

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