Issue 4, 2010
From the journal:

Chemical Science

Catalytic asymmetric hydrophosphonylation of ynones†

Daisuke Uraguchi,a   Takaki Ito,a   Shinji Nakamuraa  and  Takashi Ooi*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho B2-3(611), Chikusa, Nagoya, Japan
E-mail: tooi@apchem.nagoya-u.ac.jp
Fax: +81-(0)52-789-3338
Tel: +81-(0)52-789-4501

Abstract

Catalytic, highly enantioselective hydrophosphonylation of ynones has been achieved by exploiting the characteristic features of in situ generated chiral tetraaminophosphonium phosphite.

Graphical abstract: Catalytic asymmetric hydrophosphonylation of ynones

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Article information

DOI
https://doi.org/10.1039/C0SC00268B
Article type
Edge Article
Submitted
15 Apr 2010
Accepted
28 May 2010
First published
24 Jun 2010

Chem. Sci., 2010,1, 488-490

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Catalytic asymmetric hydrophosphonylation of ynones

D. Uraguchi, T. Ito, S. Nakamura and T. Ooi, Chem. Sci., 2010, 1, 488 DOI: 10.1039/C0SC00268B

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