Issue 21, 2010
From the journal:

Dalton Transactions

Boron–nitrogen analogues of the fluorenyl anion†‡

Stephen M. Mansell,a   Nicholas C. Norman*a  and  Christopher A. Russell*a  

* Corresponding authors

a University of Bristol, School of Chemistry, Bristol, UK
E-mail: Chris.Russell@bris.ac.uk, n.c.norman@bris.ac.uk
Fax: +44 (0)117 929 0509
Tel: +44 (0)117 928 7599

Abstract

The synthesis and structural characterisation of [BPh(bipy)] and [BCl(bipy)] are described both of which contain a direduced bipy ligand (bipy = 2,2′-bipyridyl) and are analogues of the fluorenyl anion; DFT calculations highlight differences in the electronic structure of both species compared to the fluorenyl anion.

Graphical abstract: Boron–nitrogen analogues of the fluorenyl anion

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Article information

DOI
https://doi.org/10.1039/C0DT00028K
Article type
Communication
Submitted
25 Feb 2010
Accepted
16 Apr 2010
First published
29 Apr 2010

Dalton Trans., 2010,39, 5084-5086

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Boron–nitrogen analogues of the fluorenyl anion

S. M. Mansell, N. C. Norman and C. A. Russell, Dalton Trans., 2010, 39, 5084 DOI: 10.1039/C0DT00028K

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