Issue 44, 2010
From the journal:

Chemical Communications

Photocatalytic hydrogen production from water in self-assembled supramolecular iridium–cobalt systems†‡

Sk. Jasimuddin,a   Tomoko Yamada,a   Kazunori Fukuju,a   Joe Otsuki*a  and  Ken Sakaib  

* Corresponding authors

a The Center for Creative Materials Research, Research Institute of Science and Technology, College of Science and Technology, Nihon University, 1-8-14 Kanda Surugadai, Chiyoda-ku, Tokyo 101-8308, Japan
E-mail: otsuki@chem.cst.nihon-u.ac.jp
Fax: +81 3 3259 0817
Tel: +81 3 3259 0817

b Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan

Abstract

Supramolecular photosynthetic systems made up of the [Ir(ppy)2(bpy)]+ and [Co(bpy)3]2+ cores (ppy = 2-phenylpyridinate, bpy = 2,2′-bipyridine) are in situ self-assembled in aqueous media to generate H2 upon visible light irradiation, where one of them recorded a relatively high turnover number of 20.

Graphical abstract: Photocatalytic hydrogen production from water in self-assembled supramolecular iridium–cobalt systems

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC02486D
Article type
Communication
Submitted
10 Jul 2010
Accepted
15 Sep 2010
First published
05 Oct 2010

Chem. Commun., 2010,46, 8466-8468

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Photocatalytic hydrogen production from water in self-assembled supramolecular iridium–cobalt systems

Sk. Jasimuddin, T. Yamada, K. Fukuju, J. Otsuki and K. Sakai, Chem. Commun., 2010, 46, 8466 DOI: 10.1039/C0CC02486D

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