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Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pdnanoparticles embedded in a supported ionic liquid phase
Kirill V. Kovtunov, Vladimir V. Zhivonitko, Lioubov Kiwi-Minsker and Igor V. Koptyug Chem. Commun., 2010,46, 5764-5766
DOI:
10.1039/C0CC01411G,
Communication
Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd0nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd0/SILP/ACF). The results were markedly different from those obtained with a reference catalyst, Pd0/ACF, demonstrating the important role of the ionic liquid.