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A cationic functional molecule (BNMA) was assembled with a positively-charged LDH monolayer through a polyanion (PVS) as the intermediary. The approach allows fine-tuning and ordered assembly of functional cations with LDH monolayers for designing and achieving novel organic–inorganic ultra-thin films.

Graphical abstract: A strategy to the ordered assembly of functional small cations with layered double hydroxides for luminescent ultra-thin films

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