We demonstrate the application of clamparene-based 3D porous crystals as a purifying agent to effectively remove toluene from the mixture of methylcyclohexane and toluene. We found that clamparene can selectively adsorbs toluene in a mixed of toluene and methylcyclohexane via host–guest interactions up to 99.40% purity.
Z. Li, J. Jiang, X. Jia, K. Wang, W. Shi, W. Qu, Q. Lin, T. Wei and B. Shi, Chem. Commun., 2026, Accepted Manuscript , DOI: 10.1039/D5CC05954B
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