Aqueuous solutions of copper(I) iodide, potassium iodide, and the crown ether from unexpectedly different and novel structure: [Cu4I6][Cu8I13]K7(12-crown-4)6 with two different clusters per asymmetric, unit and polymeric modifications, [Cu4I6]K2(15-crown-5)2, and [Cu3I4]K(dibenzo-24-crown-8) depending upon identity of the crown ether.
N. P. Rath and E. M. Holt, J. Chem. Soc., Chem. Commun., 1985, 665 DOI: 10.1039/C39850000665
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