Lewis acid Mg2+-doped cobalt phosphate nanosheets for enhanced electrocatalytic oxygen evolution reaction

Abstract

Cobalt-based materials are considered to be promising electrocatalysts for the oxygen evolution reaction (OER). However, their catalytic efficiencies are still limited by sluggish surface adsorption and high activation overpotentials. Herein, Lewis acid Mg²⁺-doped Co₃(PO₄)₂ nanosheets were prepared through a simple two-step strategy for enhanced electrocatalytic oxygen evolution reaction. The Lewis acid Mg²⁺ dopants can increase the cobalt–oxygen covalency and thus facilitate the adsorption of oxygenated intermediates, charge transfer and the pre-oxidation of cobalt species during the OER.