Formation, structural characteristics and physicochemical properties of beeswax oleogels prepared with tea polyphenol loaded gelators

Abstract

In this study, a tea polyphenol (TP) loaded beeswax gelator (TP gelator) was constructed and incorporated into soybean oil to improve the oxidative stability of oleogels. The effects of TP on the structure and storage stability of oleogels were investigated. The TP gelator prepared by embedding TP into beeswax improved the dispersity of TP in lipids. The thermal characteristics and X-ray diffraction analysis showed that the components of the TP gelator coexisted homogeneously and TP was well dispersed in beeswax. The Fourier-transform infrared spectra indicated that the phenolic hydroxyl group of TP had intermolecular force with the quaternary ammonium nitrogen in the choline portion of soybean lecithin. The formation of needle-like crystals by beeswax restricted the flow of liquid oil, and TP did not participate in the construction of the internal network structure of the oleogel. In the accelerated storage experiment at 60 °C, the peroxide value of the TP loaded oleogel decreased by 60.6% at the end of the storage period compared with soybean oil. TP was successfully embedded in the oleogel without changing its structure, which not only solved the problem of poor dispersion of TP in oil, but also showed a significant inhibitory effect on lipid oxidation.