Issue 43, 2008
From the journal:

Dalton Transactions

Aerobic oxidation of C(sp3)–H bonds of 4,5-diazafluorene promoted by coordination†

Huiling Jiang,a   Elzbieta Stepowskaa  and  Datong Song*a  

* Corresponding authors

a Davenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: dsong@chem.utoronto.ca
Fax: +1 416 978 7013
Tel: +1 416 978 7014

Abstract

We report a facile oxidation of the CH2group in a coordinated 4,5-diazafluorene (LH) ligand in [RuCl2(LH)(PPh3)2] into a carbonyl group by air at ambient temperature, leaving the two PPh3 ligands intact.

Graphical abstract: Aerobic oxidation of C(sp3)–H bonds of 4,5-diazafluorene promoted by coordination

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Article information

DOI
https://doi.org/10.1039/B812561A
Article type
Communication
Submitted
22 Jul 2008
Accepted
01 Sep 2008
First published
22 Sep 2008

Dalton Trans., 2008, 5879-5881

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Aerobic oxidation of C(sp3)–H bonds of 4,5-diazafluorene promoted by coordination

H. Jiang, E. Stepowska and D. Song, Dalton Trans., 2008, 5879 DOI: 10.1039/B812561A

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