Issue 22, 2002
From the journal:

Chemical Communications

Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands†

Frank Glorius,*a   Gereon Altenhoff,a   Richard Goddarda  and  Christian Lehmanna  

* Corresponding authors

a Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, Mülheim/Ruhr, Germany
E-mail: glorius@mpi-muelheim.mpg.de
Fax: (+49) 208-306-2994
Tel: (+49) 208-306-2428

Abstract

Enantiomerically pure imidazolium triflates can be readily prepared from bioxazolines and oxazolineimines; deprotonation of imidazolium triflate 2 gives a chiral N-heterocyclic carbene that can act as a ligand in a catalytically active palladium complex.

Graphical abstract: Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands

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Article information

DOI
https://doi.org/10.1039/B208045A
Article type
Communication
Submitted
15 Aug 2002
Accepted
03 Oct 2002
First published
18 Oct 2002

Chem. Commun., 2002, 2704-2705

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Oxazolines as chiral building blocks for imidazolium salts and N-heterocyclic carbene ligands

F. Glorius, G. Altenhoff, R. Goddard and C. Lehmann, Chem. Commun., 2002, 2704 DOI: 10.1039/B208045A

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